Patent US3869412A successfully refreshed from Google Patents.
US3869412A
Expired / Lapsed
US
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Surface-active compositions having controlled foaming properties and process for controlling foam therewith
Assignee: Individual
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Filing: 1971-12-20
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Granted: 1975-03-04
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Expires: 1991-12-20
Abstract
Abstract Surface-active compositions are provided having controlled foaming properties comprising an anionic sulphonate or sulphate ester surfactant, a nonionic polyoxyalkylene ether, ester or glycol surfactant, and an anionic polyoxyalkylene phosphate ester surfactant, the polyoxyalkylene phosphate ester and the polyoxyalkylene ether, ester or glycol surfactants serving as low foaming components, and the anionic surfactant increasing the foaming properties of such mixtures in proportion to the amount present. Adjuncts such as builders can also be present. A process for controlling the foaming properties of anionic sulphate or sulphonate ester surfactants and nonionic polyoxyalkylene ether, ester or glycol surfactants is provided, by combining therewith, in selected amounts, an anionic polyoxyalkylene phosphate ester surfactant to give any desired controlled low to high foaming properties.
Inventors
- 👤 Ake Waag
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 22:45
CPC Classifications
C; C11; C11D; C11D11/00; C11D11/02; C11D1/00; C11D1/02; C11D1/34; C11D1/345; C11D1/66; C11D1/72; C11D1/83; C11D3/00; C11D3/0005; C11D3/0026; D; D06; D06M; D06M7/00; D06M2200/00; D06M2200/40; Y; Y10; Y10S; Y10S516/00; Y10S516/905; Y10S516/907; Y10S516/908
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
93 words
A SURFACE-ACTIVE COMPOSITION HAVING CONTROLLED FOAMING PROPERTIES, ANS CONSISTING ESSENTIALLY OF, IN COMBINATION, A SURFACTANT SELECTED FROM THE GROUP CONSISTING OF ANIONIC SULPHONATE AND SULPHATE SURFACTANTS, A NONIONIC SURFACTANT SULLECTED FROM THE GROUP CONSISTING OF POLYOXYALKYLENE ETHER, ESTER AND-GLYCOL SURFACTANTS, AND A POLYOXYALKYLENE PHOSPHATE ESTER SURFACTANT, THE COMBINATION OF THE POLYOXYALKYLENE ETHER, -ESTER OR GLYCOL SURFACTANT AND POLYOXYALKYLENE PHOSPHATE ESTER SURFACTANT HAVING A LOW FOAMING PROPERTY WHICH IS CONTROLLABLY INCREASED BY THE PROPORTION OF ANIONIC SULPHATE OR SULPHONATE SURFACTANT, THE RELATIVE PROPORTIONS OF THE ANIONIC, NONIONIC AND PHOSPHATE SURFACTANTS FALLING WITHIN THE RANGES:
Claim 2
Dependent Claim
93 words
A SURFACE-ACTIVE COMPOSITION HAVING CONTROLLED FOAMING PROPERTIES, ANS CONSISTING ESSENTIALLY OF, IN COMBINATION, A SURFACTANT SELECTED FROM THE GROUP CONSISTING OF ANIONIC SULPHONATE AND SULPHATE SURFACTANTS, A NONIONIC SURFACTANT SULLECTED FROM THE GROUP CONSISTING OF POLYOXYALKYLENE ETHER, ESTER AND-GLYCOL SURFACTANTS, AND A POLYOXYALKYLENE PHOSPHATE ESTER SURFACTANT, THE COMBINATION OF THE POLYOXYALKYLENE ETHER, -ESTER OR GLYCOL SURFACTANT AND POLYOXYALKYLENE PHOSPHATE ESTER SURFACTANT HAVING A LOW FOAMING PROPERTY WHICH IS CONTROLLABLY INCREASED BY THE PROPORTION OF ANIONIC SULPHATE OR SULPHONATE SURFACTANT, THE RELATIVE PROPORTIONS OF THE ANIONIC, NONIONIC AND PHOSPHATE SURFACTANTS FALLING WITHIN THE RANGES:
Claim 3
Dependent Claim
63 words
A composition according to claim 1 including, in addition, a chelating agent selected from the group consisting of inorganic chelating agents and organic chelating agents selected from aminopolycarboxylic acids and polyelectrolytes selected from the group consisting of polyacrylates, polyitaconates, and starch derivatives, in an amount within the range from about 10 to about 80% by weight of the total solids of the composition.
Claim 4
Dependent Claim
33 words
A composition according to claim 1 including, in addition, a soil-suspending agent, in an amount within the range from about 0.05 to about 5% by weight of the total solids of the composition.
Claim 5
Dependent Claim
23 words
A composition according to claim 1, in which the relative proportions of the anionic, nonionic and phosphate surfactants fall within the following ranges:
Claim 6
Dependent Claim
26 words
A composition according to claim 1 in which any one of R4 and R5 in the polyoxyalkylene ether radical is methyl and the other is hydrogen.
Claim 7
Dependent Claim
20 words
A composition according to claim 1 in which the anionic sulphonate surfactant is an alkyl aryl sulfonate having the formula
Claim 8
Dependent Claim
19 words
A composition according to claim 1 in which the anionic sulphonate surfactant is an amidoalkane sulfonate, having the structure:
Claim 9
Dependent Claim
28 words
A composition according to claim 1 in which the anionic surfactant is an ester of sulfuric acid with an aliphatic alcohol of from 10 to 18 carbon atoms.
Claim 10
Dependent Claim
63 words
A composition according to claim 1 in which the anionic surfactant is a sulfonate having the following general formula: R-S03 X where R is a straight or branched, saturated or unsaturated hydrocarbon radical having 12 to 22 carbon atoms, or an alkyl benzene having a straight or branched alkyl containing 12 to 18 carbon atoms, X is an alkali metal, ammonia or alkanolamine-radical.
Claim 11
Dependent Claim
73 words
A composition according to claim 1 in which the anionic surfactant is a sulfated alkoxylate having the following general formula: R-O-(C2H4O)nS03 X where R is a straight or branched, saturated or unsaturated hydrocarbon radical having 8 to 22 carbon atoms, or an alkyl-substituted phenol having 8 to 18 carbon atoms in its alkyl portion, n is a number ranging between 0 and 6, and X is an alkali metal, ammonia or alkanolamine radical.
Claim 12
Dependent Claim
86 words
A composition according to claim 1 in which the nonionic surfactant has the following general formula: R-O-(C2H4O)nY where R is a straight or branched, saturated or unsaturated primary or secondary alkyl radical having, in all, 8 to 26 carbon atoms, or a mono-, di- or trialkyl-substituted phenol having, in all, 6 to 24 carbon atoms in its alkyl portion, n is a number ranging from 1 to 50 and Y is hydrogen or the group -(C3H6O)mH, where m is a number ranging from 1 to 10.
Claim 13
Dependent Claim
42 words
A composition according to claim 1 in which the nonionic surfactant has the following general formula: H(OC2H4)n -(OC3H6)m -OC2-3H4-6O(C3H6O)m -(C2H4O)n where m1 and m2 are numbers ranging from 10 to 50, and n1 and n2 are numbers ranging from 1 to 50.
Claim 14
Dependent Claim
34 words
A composition according to claim 1 including, in addition, an alkali metal polyphosphate in an amount within the range From about 10% to about 80% by weight of the total solids of the composition.
Claim 15
Dependent Claim
45 words
A composition according to claim 1 including, in addition, a soil-suspending agent in an amount of from about 0.05% to about 5%, by weight of the total solids, selected from alkali metal carboxymethyl cellulose, alkali metal cellulose sulphate, and lower alkyl and hydroxyalkyl cellulose ethers.
Claim 16
Dependent Claim
53 words
A composition according to claim 1, consisting essentially of 70 parts by weight of surfactants, 50 parts by weight sodium tripolyphosphate, 50 parts by weight sodium carbonate, 25 parts by weight sodium bicarbonate, 70 parts by weight sodium sulphate, 75 parts by weight sodium silicate, and 10 parts by weight sodium carboxymethyl cellulose.
Claim 17
Dependent Claim
51 words
A composition according to claim 1, including in addition, an amount within the range from about 10% to about 80% by weight of the total solids of the composition of an organic chelating agent selected from aminopolycarboxylic acids and polyelectrolytes selected from the group consisting of polyacrylates, polyitaconates, and starch derivatives.
Claim 18
Dependent Claim
47 words
A composition according to claim 14, in which the surfactants are sulphate ester of tallow fatty alcohol adduct with 2 mols of ethylene oxide, tallow fatty alcohol adduct with 8 mols of ethylene oxide and phosphate ester of stearyl alcohol adduct with 2.0 mols of 1,2-propylene oxide.
Claim 19
Dependent Claim
36 words
A composition according to claim 15, in which the surfactants are dodecylbenzene sulphonate, tallow fatty alcohol adduct with 8 mols of ethylene oxide and phosphate ester of cetyl alcohol adduct with 2 mols of 1,2-propylene oxide.
Claim 20
Dependent Claim
38 words
A composition according to claim 15, in which the surfactants are C15-C18 -olefin sulphonate, tallow fatty alcohol adduct with 8 mols of ethylene oxide and phosphate ester of tallow fatty alcohol adduct with 1.2 mols of ethylene oxide.
Claim 21
Dependent Claim
45 words
A composition according to claim 15, in which the surfactants are sulphate ester of n-primary C12-C18 fatty alcohol and C8-C18 alcohol sulphosuccinate (1:1); tridecyl alcohol adduct with 8 mols of ethylene oxide and phosphate ester of lauryl alcohol adduct with 2 mols of ethylene oxide.
Claim 22
Dependent Claim
60 words
A composition according to claim 1, consisting essentially of 70 parts by weight of surfactants, 50 parts by weight sodium tripolyphosphate, 100 parts by weight trisodium nitrilotriacetic acid, 50 parts by weight sodium carbonate, 25 parts by weight sodium bicarbonate, 70 parts by weight sodium sulphate, 75 parts by weight sodium silicate, and 10 parts by weight sodium carboxymethyl cellulose.
Claim 23
Dependent Claim
47 words
A composition according to claim 21, in which the surfactants are sulphate ester of tallow fatty alcohol adduct with 2 mols of ethylene oxide, tallow fatty alcohol adduct with 8 mols of ethylene oxide and phosphate ester of stearyl alcohol adduct with 2 mols of 1,2-propylene oxide.
Claim 24
Dependent Claim
38 words
A composition according to claim 21, in which the surfactants are sodium dodecyl benzene sulphonate, tallow fatty alcohol adduct with 8 mols of ethylene oxide, and phosphate ester of cetyl alcohol adduct with 2 mols of 1,2-propylene oxide.
Claim 25
Dependent Claim
38 words
A composition according to claim 21, in which the surfactants are C15-C18 -olefin sulphonate, tallow fatty alcohol adduct with 8 mols of ethylene oxide and phosphate ester of tallow fatty alcohol adduct with 1.2 mols of ethylene oxide.
Claim 26
Dependent Claim
41 words
A composition according to claim 1, consisting essentially of 70 parts by weight of surfactants, 300 parts by weight sodium tripolyphosphate, 30 parts by weight sodium carbonate (calcined), 5 parts by weight trisodium phosphate, and 30 parts by weight sodium metasilicate.
Claim 27
Dependent Claim
38 words
A composition according to claim 25 in which the surfactants arE sodium dodecyl benzene sulfonate, nonyl phenol adduct with 10 mols of ethylene oxide and phosphate ester of stearyl alcohol adduct with 8.5 mols of 1,2- propylene oxide.
Claim 28
Dependent Claim
17 words
A composition according to claim 1 consisting essentially of, in addition to the surfactant, sodium carbonate (calcined).
Claim 29
Dependent Claim
50 words
A composition according to claim 27, in which the surfactants are sulphate ester of n-primary C16-C20 fatty alcohol adduct with 3 mols of ethylene oxide, n-primary C16-C20 fatty alcohol adduct with 30 mols of ethylene oxide, and phosphate ester of n-primary C20-C22 alcohol adduct with 3 mols of ethylene oxide.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-03-03 | 1978-09-02 | 1979-03-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-03-03 | 1982-09-02 | 1983-03-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-03-03 | 1986-09-02 | 1987-03-04 | $7700.00 | Window Closed / Lapsed |