← Back to Patent Explorer
US3868431A Expired / Lapsed US ⏱️ 0.0 years remaining

Elastomer production

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1973-04-19
•
Granted: 1975-02-25
•
Expires: 1993-04-19
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A process for the production of an elastomeric material from a homogeneous composition comprising from 50% to 95% by weight of the precursors of a cross-linked elastomeric polyurethane and from 50% to 5% by weight of a polymerisable ethylenically unsaturated material, in which the reaction of the polyurethane precursors is substantially completed before polymerisation of the ethylenically unsaturated material is allowed to proceed to the extent that the polymer so produced forms a separate phase, polymerisation of the ethylenically unsaturated material thereafter being completed, and in which the ethylenically unsaturated material contains at least one polyfunctional ethylenically unsaturated material and is selected so as to produce, after polymerisation, a cross-linked polymer having on average a molecular weight between cross-links of not greater than 2500.

Inventors

  • 👤 Francis Gowland Hutchinson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 06:21
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/63; C08G18/637; C08L; C08L75/00; C08L75/04

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 163 words
IN A PROCESS FOR THE PRODUCTION OF AN ELASTOMERIC MATERIAL FROM A HOMOGENEOUS COMPOSITION COMPRISING FROM 50% TO 95% BY WEIGHT OF THE PRECURSORS OF A CROSS-LINKED POLYURETHANE WHICH, WHEN REACTED ALONE IN THE ABSENCE OF ETHYLENICALLY UNSATURATED MATERIAL, ARE CAPABLE OF FORMING AN ELASTOMERIC POLYURETHANE HAVING A GLASS-RUBBER TRANSITION TEMPERATURE OF 25*C OR LESS, AND FROM 50% TO 5% BY WEIGHT OF AT LEAST ONE POLYMERISABLE ETHYLENICALLY UNSATURATED MATERIAL, IN WHICH PROCESS THE REACTION OF THE POLYURETHANE PRECURSORS IS SUBSTANTIALLY COMPLETED BEFORE POLYMERISATION OF THE ETHYLENICALLY UNSATURATED MATERIAL IS ALLOWED TO PROCEED TO THE EXTENT THAT THE POLYMER SO PRODUCED FORMS A SEPARATE PHASE AND IN WHICH POLYMERISATION OF THE ETHYLENICALLY UNSATURATED MATERIAL IS THEREAFTER COMPLETED, THE IMPROVEMENT WHICH COMPRISES USING IN THE PROCESS AN ETHYLENICALLY UNSATURATED MATERIAL WHICH CONTAINS AT LEAST ONE POLYFUNCTIONAL ETHYLENICALLY UNSATURATED MATERIAL AND IS SELECTED SO AS TO PRODUCE, AFTER POLYMERISATION, A CROSS-LINKED POLYMER HAVING ON AVERAGE A MOLECULAR WEIGHT BETWEEN CROSS-LINKS OF NOT GREATER THAN 2,500.
Claim 2
Dependent Claim 163 words
IN A PROCESS FOR THE PRODUCTION OF AN ELASTOMERIC MATERIAL FROM A HOMOGENEOUS COMPOSITION COMPRISING FROM 50% TO 95% BY WEIGHT OF THE PRECURSORS OF A CROSS-LINKED POLYURETHANE WHICH, WHEN REACTED ALONE IN THE ABSENCE OF ETHYLENICALLY UNSATURATED MATERIAL, ARE CAPABLE OF FORMING AN ELASTOMERIC POLYURETHANE HAVING A GLASS-RUBBER TRANSITION TEMPERATURE OF 25*C OR LESS, AND FROM 50% TO 5% BY WEIGHT OF AT LEAST ONE POLYMERISABLE ETHYLENICALLY UNSATURATED MATERIAL, IN WHICH PROCESS THE REACTION OF THE POLYURETHANE PRECURSORS IS SUBSTANTIALLY COMPLETED BEFORE POLYMERISATION OF THE ETHYLENICALLY UNSATURATED MATERIAL IS ALLOWED TO PROCEED TO THE EXTENT THAT THE POLYMER SO PRODUCED FORMS A SEPARATE PHASE AND IN WHICH POLYMERISATION OF THE ETHYLENICALLY UNSATURATED MATERIAL IS THEREAFTER COMPLETED, THE IMPROVEMENT WHICH COMPRISES USING IN THE PROCESS AN ETHYLENICALLY UNSATURATED MATERIAL WHICH CONTAINS AT LEAST ONE POLYFUNCTIONAL ETHYLENICALLY UNSATURATED MATERIAL AND IS SELECTED SO AS TO PRODUCE, AFTER POLYMERISATION, A CROSS-LINKED POLYMER HAVING ON AVERAGE A MOLECULAR WEIGHT BETWEEN CROSS-LINKS OF NOT GREATER THAN 2,500.
Claim 3
Dependent Claim 25 words
A process as claimed in claim 1 in which the precursors of the cross-linked polyurethane are free of groups reactive with the ethylenically unsaturated material.
Claim 4
Dependent Claim 21 words
A process as claimed in claim 1 in which the ethylenically unsaturated material comprises at least one polyfunctional ethylenically unsaturated monomer.
Claim 5
Dependent Claim 32 words
A process as claimed in claim 3 in which the ethylenically unsaturated material comprises a mixture of at least one monofunctional ethylenically unsaturated monomer and at least one polyfunctional ethylenically unsaturated monomer.
Claim 6
Dependent Claim 28 words
A process as claimed in claim 1 in which the composition comprises greater than 70% and less than 90% by weight of the precursors of a cross-linked polyurethane.
Claim 7
Dependent Claim 32 words
A process as claimed in claim 1 in which the precursors of the cross-linked polyurethane are capable of forming an elastomeric polyurethane having a glass-rubber transition temperature of 0* C or less.
Claim 8
Dependent Claim 38 words
A process as claimed in claim 1 in which the ethylenically unsaturated material is selected so as to produce, after polymerisation, a cross-linked polymer having on average a molecular weight between cross-links in the range 100 to 2,000.
Claim 9
Dependent Claim 36 words
A process as claimed in claim 7 in which the ethylenically unsaturated material is selected so as to produce, after polymerisation, a cross-linked polymer having a molecular weight between cross-links in the range 100 to 1,000.
Claim 10
Dependent Claim 29 words
A process as claimed in claim 1 in which the polyfunctional ethylenically unsaturated material comprises at least one monomer which is an acrylate or methacrylate bis-ester of a diol.
Claim 11
Dependent Claim 21 words
A process as claimed in claim 9 in which the acrylate or methacrylate bis-ester of a diol is ethylene glycol dimethacrylate.

References Cited (Backward Citations)

US2806836A Cited
US2879248A Cited
US3047530A Cited
US3008917A Cited
US3509234A Cited
US3700752A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-02-24 1978-08-26 1979-02-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-02-24 1982-08-26 1983-02-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-02-24 1986-08-26 1987-02-25 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag