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US3864169A Expired / Lapsed US ⏱️ 0.0 years remaining

A method for making laminated electrodes

Assignee: NL Industries Inc
•
Filing: 1974-03-25
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Granted: 1975-02-04
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Expires: 1994-03-25
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Abstract

Abstract A light-weight lead-acid battery has been prepared which contains a novel light weight electrode having at least three plies, the center ply being a conductive sheet and the outer two plies being sheets of porous, compressed and sintered homogeneous composite of synthetic fibers and lead oxide powder material. This application is also directed toward a method for preparing laminated electrodes and the light-weight battery which uses these electrodes.

Inventors

  • 👤 John P Cestaro
  • 👤 Uriel Sokolov

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 03:00
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/04; H01M4/0402; H01M4/0404; H01M4/043; H01M4/0435; H01M4/0471; H01M4/14; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24273; Y10T428/24322; Y10T428/24331; Y10T428/30

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 97 words
A METHOD FOR MAKING A COMPOSITE SHEET OF A LOOSE HOMOGENEOUS MAT OF SYNTHETIC FIBERS COATED WITH A POWDERED ACTIVE MATERIAL SAID COMPOSITE SHEET USEFUL FOR FORMING A LAMINATED ELECTRODE WHICH COMPRISES DISPERSING SYNTHETIC FIBERS IN WATER WITH AGITATION TO FORM A SLURRY, ADDING POWDERED ACTIVE MATERIAL TO SAID SLURRY AND AFTER THROUGHLY MIXING, FLOCCULATING THE DISPERSED SLURRY BY LOWERING THE PH UNTIL A LARGE FLOCCULATED MASS OF FIBERS AND ACTIVE MATERIAL IS FORMED, FILTERING AND DRYING SAID FLOCCULATED MASS TO FORM A COMPOSITE SHEET OF A LOOSE HOMOGENEOUS MAT OF FIBERS COATED WITH SAID ACTIVE MATERIAL.
Claim 2
Independent Claim 97 words
A METHOD FOR MAKING A COMPOSITE SHEET OF A LOOSE HOMOGENEOUS MAT OF SYNTHETIC FIBERS COATED WITH A POWDERED ACTIVE MATERIAL SAID COMPOSITE SHEET USEFUL FOR FORMING A LAMINATED ELECTRODE WHICH COMPRISES DISPERSING SYNTHETIC FIBERS IN WATER WITH AGITATION TO FORM A SLURRY, ADDING POWDERED ACTIVE MATERIAL TO SAID SLURRY AND AFTER THROUGHLY MIXING, FLOCCULATING THE DISPERSED SLURRY BY LOWERING THE PH UNTIL A LARGE FLOCCULATED MASS OF FIBERS AND ACTIVE MATERIAL IS FORMED, FILTERING AND DRYING SAID FLOCCULATED MASS TO FORM A COMPOSITE SHEET OF A LOOSE HOMOGENEOUS MAT OF FIBERS COATED WITH SAID ACTIVE MATERIAL.
Claim 3
Dependent Claim 20 words
Method according to claim 1 in which the fibers used are selected from the group consisting of polyethylene and polypropylene.
Claim 4
Dependent Claim 23 words
Method according to claim 1 in which 90 percent to 100 percent of the fibers used are synthetic, the remainder being natural fibers.
Claim 5
Dependent Claim 35 words
Method according to claim 1 in which the fibers used are of size such that the numerical product of the length of the fibers in millimeters multiplied by the denier is no greater than 25.
Claim 6
Dependent Claim 30 words
Method according to claim 1 in which the powdered active material used is selected from the group consisting of PbO, Pb, tribasic lead sulfate, tetrabasic lead sulfate, and mixtures thereof.
Claim 7
Dependent Claim 30 words
Method according to claim 1 in which the amount of active material used in the composite sheet is from 50 to 90 parts by weight for each part of fiber.
Claim 8
Independent Claim 128 words
A method for forming a laminated electrode which comprises dispersing synthetic fibers in water with agitation to form a slurry, adding powdered active material to said slurry and after thoroughtly mixing, flocculating the dispersed slurry by lowering the pH until a large flocculated mass of fibers and active material is formed, filtering and drying said flocculated mass to form a composite sheet of a loose homogeneous mat of fibers coated with said active material, placing a composite sheet of said homogeneous mat of fibers coated with said active material on each side of a conductive sheet to form a sandwich and heating and compressing said sandwich at a temperature from 120* to 200 *C under pressure from atmospheric to 13,000 psi to form a three-ply laminated electrode structure.
Claim 9
Independent Claim 128 words
A method for forming a laminated electrode which comprises dispersing synthetic fibers in water with agitation to form a slurry, adding powdered active material to said slurry and after thoroughtly mixing, flocculating the dispersed slurry by lowering the pH until a large flocculated mass of fibers and active material is formed, filtering and drying said flocculated mass to form a composite sheet of a loose homogeneous mat of fibers coated with said active material, placing a composite sheet of said homogeneous mat of fibers coated with said active material on each side of a conductive sheet to form a sandwich and heating and compressing said sandwich at a temperature from 120* to 200 *C under pressure from atmospheric to 13,000 psi to form a three-ply laminated electrode structure.
Claim 10
Dependent Claim 38 words
Method according to claim 7 in which the conductive sheet in said laminated electrode is selected from the group consisting of lead foil, thin perforated lead sheet, paper sheet containing graphite and paper sheet containing lead metal powder.

References Cited (Backward Citations)

US2681375A Cited
US2834825A Cited
US3530001A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-02-03 1978-08-05 1979-02-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-02-03 1982-08-05 1983-02-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-02-03 1986-08-05 1987-02-04 $7700.00 Window Closed / Lapsed

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