Patent US3864087A successfully refreshed from Google Patents.
US3864087A
Expired / Lapsed
US
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Titrating system
Assignee: Bio Rad Laboratories Inc
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Filing: 1973-05-14
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Granted: 1975-02-04
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Expires: 1993-05-14
Abstract
Abstract A chemical measuring system of the titration type comprises an elongated, hollow conduit, the walls of which are formed of a porous membrane. The conduit is suspended in a body of titrant. In operation a sample fluid is passed through the conduit. Titrant permeates the walls of the conduit and reacts with the sample. An end point is observed by an observable change at some position along the conduit, that position being proportional to the concentration of the sample.
Inventors
- 👤 Tomas Hirschfeld
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 14:20
CPC Classifications
G; G01; G01N; G01N31/00; G01N31/16; G01N31/166; Y; Y10; Y10T; Y10T436/00; Y10T436/25; Y10T436/25375; Y10T436/255
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
95 words
A CHEMICAL MEASURING SYSTEM FOR TITRATING A SAMPLE SOLUTION WITH A TITRANT CAPABLE OF REACTING WITH SAID SOLUTION TO PRODUCE AN OBSERVABLE END-POINT CHANGE, AND COMPRISING, IN COMBINATION: MEANS FOR CONTAINING A BODY OF SAID TITRANT; A HOLLOW, ELONGATED CONDUIT DISPOSED WITHIN SAID MEANS FOR CONTAINING, THE WALL OF SAID CONDUIT BEING POROUS SO THAT A NET FLOW THROUGH SAID WALL CAN OCCUR BETWEEN SAID BODY OF TITRANT AND A STREAM OF SAMPLE SOLUTION FLOWING THROUGH SAID CONDUIT; AND MEANS FOR DETERMINING THE RELATIVE POSITION ALONG SAID CONDUIT AT WHICH SAID END-POINT CHANGE IS OBSERVABLE.
Claim 2
Dependent Claim
95 words
A CHEMICAL MEASURING SYSTEM FOR TITRATING A SAMPLE SOLUTION WITH A TITRANT CAPABLE OF REACTING WITH SAID SOLUTION TO PRODUCE AN OBSERVABLE END-POINT CHANGE, AND COMPRISING, IN COMBINATION: MEANS FOR CONTAINING A BODY OF SAID TITRANT; A HOLLOW, ELONGATED CONDUIT DISPOSED WITHIN SAID MEANS FOR CONTAINING, THE WALL OF SAID CONDUIT BEING POROUS SO THAT A NET FLOW THROUGH SAID WALL CAN OCCUR BETWEEN SAID BODY OF TITRANT AND A STREAM OF SAMPLE SOLUTION FLOWING THROUGH SAID CONDUIT; AND MEANS FOR DETERMINING THE RELATIVE POSITION ALONG SAID CONDUIT AT WHICH SAID END-POINT CHANGE IS OBSERVABLE.
Claim 3
Dependent Claim
15 words
A system as defined in claim 1 wherein said wall of said conduit is semi-permeable.
Claim 4
Dependent Claim
16 words
A system as defined in claim 2 wherein said wall is formed of a dialyzing membrane.
Claim 5
Dependent Claim
13 words
A system as defined in claim 1 wherein said conduit is substantially transparent.
Claim 6
Dependent Claim
13 words
A system as defined in claim 1 wherein said conduit is substantially translucent.
Claim 7
Dependent Claim
19 words
A system as defined in claim 1 including a color indicator material admixed with said titrant of said sample.
Claim 8
Dependent Claim
19 words
A system as defined in claim 1 wherein said means for determining comprises a scale extending along said conduit.
Claim 9
Dependent Claim
16 words
A system as defined in claim 1 wherein said conduit has a substantially uniform cross-sectioned area.
Claim 10
Dependent Claim
18 words
A system as defined in claim 1 wherein the wall of said conduit has a substantially uniform thickness.
Claim 11
Dependent Claim
22 words
A system as defined in claim 1 including means disposed in said conduit for providing turbulence to said stream in said conduit.
Claim 12
Dependent Claim
24 words
A system as defined in claim 1 including means defined in said conduit for mixing said stream with any titrant flow through said wall.
Claim 13
Dependent Claim
20 words
A system as defined in claim 1 including means for applying a substantially constant pressure head on said sample solution.
Claim 14
Dependent Claim
122 words
A chemical measuring system for continuously titrating a sample solution flow through a pipe with a titrant capable of reacting with said solution to produce an observable end-point change, and comprising, in combination: means for containing a body of said titrant; a hollow, elongated conduit disposed within said means for containing, the wall of said conduit being porous so that a net flow through said wall can occur between said body of titrant and a stream of sample solution flowing through said conduit; an internal constriction in said pipe; the ends of said conduit being connected to said pipe on opposite sides of said constriction; and means for determining the relative position along said conduit at which said end-point change is observable.
Claim 15
Dependent Claim
122 words
A chemical measuring system for continuously titrating a sample solution flow through a pipe with a titrant capable of reacting with said solution to produce an observable end-point change, and comprising, in combination: means for containing a body of said titrant; a hollow, elongated conduit disposed within said means for containing, the wall of said conduit being porous so that a net flow through said wall can occur between said body of titrant and a stream of sample solution flowing through said conduit; an internal constriction in said pipe; the ends of said conduit being connected to said pipe on opposite sides of said constriction; and means for determining the relative position along said conduit at which said end-point change is observable.
Claim 16
Dependent Claim
136 words
A chemical measuring system for titrating a sample fluid with a titrant capable of reacting with said fluid to produce an observable end-point change and, comprising in combination: first means for containing a body of said titrant fluid; second means for containing a body of said sample; at least one of the said first and second means constituting a conduit for the flow of the corresponding body of fluid therethrough; a common wall disposed between said conduit and the other of said first or second means, said wall being porous so that a net flow through said wall can occur between the body of fluid flowing through said conduit and the other body of fluid in said other means; and means for determining the relative position along said conduit at which said end-point change is observable.
Claim 17
Dependent Claim
136 words
A chemical measuring system for titrating a sample fluid with a titrant capable of reacting with said fluid to produce an observable end-point change and, comprising in combination: first means for containing a body of said titrant fluid; second means for containing a body of said sample; at least one of the said first and second means constituting a conduit for the flow of the corresponding body of fluid therethrough; a common wall disposed between said conduit and the other of said first or second means, said wall being porous so that a net flow through said wall can occur between the body of fluid flowing through said conduit and the other body of fluid in said other means; and means for determining the relative position along said conduit at which said end-point change is observable.
Claim 18
Dependent Claim
115 words
A chemical measuring system for titrating a sample solution with a titrant capable of reacting with said fluid to produce an observable end-point change, and comprising in combination; means for containing a first body of liquid; a hollow elongated conduit having a porous wall in common with said means so that a net flow through said wall can occur between said first body of liquid and a flow stream of liquid flowing through said conduit, said first body being one of said solution of said titrant, said second body being the other of said solution or said titrant; and means for determining the relative position along said conduit at which said end-point change is observable.
Claim 19
Dependent Claim
115 words
A chemical measuring system for titrating a sample solution with a titrant capable of reacting with said fluid to produce an observable end-point change, and comprising in combination; means for containing a first body of liquid; a hollow elongated conduit having a porous wall in common with said means so that a net flow through said wall can occur between said first body of liquid and a flow stream of liquid flowing through said conduit, said first body being one of said solution of said titrant, said second body being the other of said solution or said titrant; and means for determining the relative position along said conduit at which said end-point change is observable.
References Cited (Backward Citations)
US3404962A
Cited
US3723062A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-02-03 | 1978-08-05 | 1979-02-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-02-03 | 1982-08-05 | 1983-02-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-02-03 | 1986-08-05 | 1987-02-04 | $7700.00 | Window Closed / Lapsed |