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US3862914A Expired / Lapsed US ⏱️ 0.0 years remaining

Water-based coatings from polyepoxides and polycarboxylic acid monoanhydrides

Assignee: Valspar Corp
•
Filing: 1972-11-01
•
Granted: 1975-01-28
•
Expires: 1992-11-01
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Abstract

Abstract Water-based coating compositions are provided by reacting an hydroxy functional polyepoxide with a polycarboxylic acid monoanhydride, preferably trimellitic anhydride, in organic solvent medium at critical concentration, and at critical temperature to produce a non-gelled acidic resin which is dispersible in water with the aid of a base.

Inventors

  • 👤 Ronald W Anderson
  • 👤 Richard C Mcafee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:24
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/42

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 14 words
A method as recited in claim 1 in which said anhydride is trimellitic anhydride.
Claim 2
Dependent Claim 18 words
A method as recited in claim 2 in which the resin solids content is from 55 to 80%.
Claim 3
Dependent Claim 31 words
A method as recited in claim 1 in which said polyepoxide and said monoanhydride are used in amounts providing an epoxy to carboxy ratio in the range of 2:1 to 2:16.
Claim 4
Dependent Claim 14 words
A method as recited in claim 1 in which said solvent is a ketone.
Claim 5
Dependent Claim 56 words
A solution of acidic resin dispersible in water with the aid of a base, said Acidic resin being the non-gelled reaction product produced by the method of claim 1, said acidic resin being substantially free of unreacted anhydride groups and having an acid number of at least about 10 and being dissolved in water-miscible organic solvent.
Claim 6
Dependent Claim 21 words
A solution as recited in claim 6 in which said acidic resin has an acid number in the range of 50-150.
Claim 7
Dependent Claim 14 words
A solution as recited in claim 6 in which said anhydride is trimellitic anhydride.
Claim 8
Dependent Claim 31 words
A solution as recited in claim 6 in which said polyepoxide is a polyglycidyl ether of a bisphenol having a molecular weight in the range of 300 up to about 10,000.
Claim 9
Dependent Claim 20 words
A solution as recited in claim 9 in which said polyepoxide has a molecular weight in the range of 350-4,000.
Claim 10
Dependent Claim 15 words
A solution as recited in claim 6 in which said solvent comprises an ether alcohol.
Claim 11
Dependent Claim 23 words
A solution as recited in claim 6 in which water soluble or water dispersible heat-hardening formaldehyde condensation product is present in said solution.
Claim 12
Dependent Claim 31 words
A solution as recited in claim 12 in which said heat-hardening formaldehyde condensate is an aminoplast resin present in an amount of from 0.5-50%, based on the weight of total resin.
Claim 13
Dependent Claim 32 words
A water dispersion comprising the solution of claim 6 dispersed in water with the aid of a base, said dispersion having a pH of from about pH 6 to about pH 10.
Claim 14
Dependent Claim 16 words
A water dispersion as recited in claim 14 in which said base is a nitrogenous base.
Claim 15
Dependent Claim 31 words
A water dispersion comprising the solution of claim 12 dispersed in water with the aid of a nitrogenous base, said dispersion having a pH of from pH 7 to pH 9.5.
Claim 16
Dependent Claim 28 words
A method as recited in claim 1 in which said polyepoxide is a polyglycidyl ether having a molecular weight in the range of 300 up to about 10,000.

References Cited (Backward Citations)

US3355401A Cited
US3397159A Cited
US3370969A Cited
US3730926A Cited
US3563929A Cited
US3624013A Cited
US3627720A Cited
US3634326A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-01-27 1978-07-29 1979-01-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-01-27 1982-07-29 1983-01-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-01-27 1986-07-29 1987-01-28 $7700.00 Window Closed / Lapsed

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