Patent US3861876A successfully refreshed from Google Patents.
US3861876A
Expired / Lapsed
US
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Constant temperature cold-end corrosion probe
Assignee: ChampionX LLC
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Filing: 1973-07-30
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Granted: 1975-01-21
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Expires: 1993-07-30
Abstract
Abstract Method and apparatus for determining the corrosion or acid deposition rate in the cold end of a boiler system, including a probe loop having an organic solvent circulating through the loop with a predetermined boiling temperature wherein the loop includes a removable specimen that can be tested for acid deposition or corrosion rate. Recirculation of the organic solvent maintains the surface temperature of the specimen within close limits approximating the maximum corrosion temperature.
Inventors
- 👤 Reed S Robertson
- 👤 William R Watson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 01:25
CPC Classifications
G; G01; G01N; G01N17/00
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
149 words
A CONSTANT TEMPERATURE COLD-END CORROSION PROBE FOR DETERMINING THE CORROSION RATE OF THE FLUE GAS STREAM IN THE COLD END OF A BOILER, SAID PROBE COMPRISING A PIPE LOOP HAVING AN UPPER RUN AND A LOWER RUN, SAID RUNS BEING ARRANGED IN A VERTICAL PLANE AND SAID LOOP ADAPTED FOR INSTALLATION IN THE FLUE GAS STREAM HAVING A TUBULAR CORROSION SPECIMEN, A TANK MOUNTED OUTSIDE THE FLUE GAS STREAM AND CONNECTED TO BOTH ENDS OF SAID PIPE LOOP COOLANT IN THE TANK HAVING A BOILING POINT ORGANIC SOLVENT TYPE COOLANT IN THE TANK HAVING A BOILING POINT ABOUT THE SAME AS THAT WHERE MAXIMUN CORROSION WOULD OCCUR FOR THE SPECIMEN, AND COOLING MEANS IN THE TANK MAINTAINING THE COOLANT AT A TEMPERATURE BELOW THE BOILING P0INT THEREBY PRODUCING CIRCULATION THROUGH THE PIPE LOOP AND MAINTINING THE TEMPERATURE OF THE SPECIMEN CONSTANT AT ABOOUT THE BOILING POINT OF THE COOLANT.
Claim 2
Dependent Claim
149 words
A CONSTANT TEMPERATURE COLD-END CORROSION PROBE FOR DETERMINING THE CORROSION RATE OF THE FLUE GAS STREAM IN THE COLD END OF A BOILER, SAID PROBE COMPRISING A PIPE LOOP HAVING AN UPPER RUN AND A LOWER RUN, SAID RUNS BEING ARRANGED IN A VERTICAL PLANE AND SAID LOOP ADAPTED FOR INSTALLATION IN THE FLUE GAS STREAM HAVING A TUBULAR CORROSION SPECIMEN, A TANK MOUNTED OUTSIDE THE FLUE GAS STREAM AND CONNECTED TO BOTH ENDS OF SAID PIPE LOOP COOLANT IN THE TANK HAVING A BOILING POINT ORGANIC SOLVENT TYPE COOLANT IN THE TANK HAVING A BOILING POINT ABOUT THE SAME AS THAT WHERE MAXIMUN CORROSION WOULD OCCUR FOR THE SPECIMEN, AND COOLING MEANS IN THE TANK MAINTAINING THE COOLANT AT A TEMPERATURE BELOW THE BOILING P0INT THEREBY PRODUCING CIRCULATION THROUGH THE PIPE LOOP AND MAINTINING THE TEMPERATURE OF THE SPECIMEN CONSTANT AT ABOOUT THE BOILING POINT OF THE COOLANT.
Claim 3
Dependent Claim
41 words
The combination as defined in claim 1, wherein the organic solvent level is above said ports, and said cooling means includes a condensing coil in the tank spaced above the solvent level, and means forcing a cooling media through the coil.
Claim 4
Dependent Claim
33 words
The combination as defined in claim 2, wherein said cooling means further includes a cooling coil in the tank positioned within the coolant, and means forcing a cooling media through the cooling coil.
Claim 5
Dependent Claim
17 words
The combination as defined in claim 3, and means removably connecting the specimen in the pipe loop.
Claim 6
Dependent Claim
195 words
A constant temperature cold-end corrosion probe for determining the rate of sulphuric acid corrosion caused by flue gases in the cold end of a sulphur-containing fuel fired boiler, said probe comprising a corrosion specimen in the form of a metal pipe section adapted to be exposed to the flue gases of a temperature above the maximum corrosion temperature, a fitting in the breeching wall of the boiler, pipe sections connected to the specimen and extending from the fitting defining a pipe loop having an upper run and a lower run in which the specimen is located, said runs arranged in a vertical plane, a coolant tank outside the breeching wall having upper and lower coolant ports connected to the pipe loop, coolant in the tank at a level above said ports and having a bOiling temperature of about the temperature desired for probe operation, and coolant cooling means including a condensing coil in the coolant tank above the coolant level connected to a source of circulating water of a temperature lower than the coolant boiling point to condense the coolant in a gaseous phase and cool the coolant to a temperature below its boiling point.
Claim 7
Dependent Claim
195 words
A constant temperature cold-end corrosion probe for determining the rate of sulphuric acid corrosion caused by flue gases in the cold end of a sulphur-containing fuel fired boiler, said probe comprising a corrosion specimen in the form of a metal pipe section adapted to be exposed to the flue gases of a temperature above the maximum corrosion temperature, a fitting in the breeching wall of the boiler, pipe sections connected to the specimen and extending from the fitting defining a pipe loop having an upper run and a lower run in which the specimen is located, said runs arranged in a vertical plane, a coolant tank outside the breeching wall having upper and lower coolant ports connected to the pipe loop, coolant in the tank at a level above said ports and having a bOiling temperature of about the temperature desired for probe operation, and coolant cooling means including a condensing coil in the coolant tank above the coolant level connected to a source of circulating water of a temperature lower than the coolant boiling point to condense the coolant in a gaseous phase and cool the coolant to a temperature below its boiling point.
Claim 8
Dependent Claim
20 words
The combination as defined in claim 5, wherein the specimen is mounted in the upper run of the pipe loop.
Claim 9
Dependent Claim
33 words
The combination as defined in claim 6, wherein said coolant cooling means further includes a cooling coil positioned within the coolant and connected to said source of circulating water to temper the coolant.
Claim 10
Dependent Claim
214 words
Apparatus for determining the sulphuric acid deposition rate of a boiler flue gas stream produced by a sulphur-containing fuel fired boiler comprising a probe pipe loop having upper and lower runs extending horizontally and arranged in a vertical plane and having a removable specimen therein, a fitting in the breeching wall of the boiler, a pair of pipe sections extending through the fitting and at each side thereof the portions of which extend into the flue gas stream constitute part of said upper and lower runs, said specimen being a straight pipe section and defining a part of the upper run, a coupling connecting one end of the specimen to the upper run pipe section extending through said fitting, an interconnecting pipe section between the lower run pipe section extending through the fitting and the specimen including a straight portion extending from said lower run pipe section and defining a part of the lower run and a loop portion extending from said specimen, couplings connecting the loop portion of the interconnecting pipe section to the specimen and the straight portion thereof to the lower run pipe section, and means connected to the upper and lower run pipe sections outside the breeching wall for cooling the loop by forcing a cooling media through the loop.
Claim 11
Dependent Claim
214 words
Apparatus for determining the sulphuric acid deposition rate of a boiler flue gas stream produced by a sulphur-containing fuel fired boiler comprising a probe pipe loop having upper and lower runs extending horizontally and arranged in a vertical plane and having a removable specimen therein, a fitting in the breeching wall of the boiler, a pair of pipe sections extending through the fitting and at each side thereof the portions of which extend into the flue gas stream constitute part of said upper and lower runs, said specimen being a straight pipe section and defining a part of the upper run, a coupling connecting one end of the specimen to the upper run pipe section extending through said fitting, an interconnecting pipe section between the lower run pipe section extending through the fitting and the specimen including a straight portion extending from said lower run pipe section and defining a part of the lower run and a loop portion extending from said specimen, couplings connecting the loop portion of the interconnecting pipe section to the specimen and the straight portion thereof to the lower run pipe section, and means connected to the upper and lower run pipe sections outside the breeching wall for cooling the loop by forcing a cooling media through the loop.
Claim 12
Independent Claim
162 words
A method of determining the corrosivity caused by the flue gas stream in the cold end of a boiler in terms of a corrosion rate, which method comprises the steps of weighing a tubular corrosion specimen, connecting the specimen in the upper run of a probe loop having an upper run and a lower run arranged in a vertical plane, positioning the probe loop within the flue gas stream of the boiler at a point where the temperature is above that where maximum corrosion occurs, connecting the probe loop to a coolant tank positioned outside the flue gas stream, filling the coolant tank with an organic solvent having a boiling point temperature where maximum corrosion occurs in the gas stream, cooling the solvent in the tank to a temperature below the boiling point temperature thereby causing recirculation of coolant in the probe loop, operating the cooling cycle for a test period, and removing and weighing the specimen to calculate the corrosion rate.
Claim 13
Independent Claim
162 words
A method of determining the corrosivity caused by the flue gas stream in the cold end of a boiler in terms of a corrosion rate, which method comprises the steps of weighing a tubular corrosion specimen, connecting the specimen in the upper run of a probe loop having an upper run and a lower run arranged in a vertical plane, positioning the probe loop within the flue gas stream of the boiler at a point where the temperature is above that where maximum corrosion occurs, connecting the probe loop to a coolant tank positioned outside the flue gas stream, filling the coolant tank with an organic solvent having a boiling point temperature where maximum corrosion occurs in the gas stream, cooling the solvent in the tank to a temperature below the boiling point temperature thereby causing recirculation of coolant in the probe loop, operating the cooling cycle for a test period, and removing and weighing the specimen to calculate the corrosion rate.
Claim 14
Dependent Claim
31 words
The method as defined in claim 9, wherein the step of positioning the probe loop within the gas stream includes positioning where the gas stream temperature is at least 300* F.
Claim 15
Dependent Claim
31 words
The method as defined in claim 9, wherein the step of cooling the solvent in the tank includes positioning a condensing coil above the liquid phase to condense the gaseous phase.
Claim 16
Independent Claim
197 words
The method of determining the sulphuric acid corrosion rate of metal caused by a flue gas stream flowing through the cold end of a boiler fired by a sulphur-containing fuel, said method comprising weighing a corrosion specimen in the form of a tube of a metal for which the corrosion rate is desired, connecting the tube to pipe in the form of a loop defining a probe section having an upper run and a lower run arranged in a vertical plane, positioning the probe section in the boiler flue gas stream at a point where the temperature is above the temperature where maximum corrosion occurs to be wiped by the flue gas stream, connecting the probe section to a coolant tank having a condensing coil mounTed therein, filling the coolant tank with an organic solvent having a boiling point about the same as where maximum corrosion exists to a level slightly below the condensing coil and subjecting the condensing coil to the cooling action of a cooling media, wherein boiling of the coolant in the probe causes constant recirculation between the tank and probe thereby continually cooling the probe and maintaining it at a constant corroding temperature.
Claim 17
Independent Claim
197 words
The method of determining the sulphuric acid corrosion rate of metal caused by a flue gas stream flowing through the cold end of a boiler fired by a sulphur-containing fuel, said method comprising weighing a corrosion specimen in the form of a tube of a metal for which the corrosion rate is desired, connecting the tube to pipe in the form of a loop defining a probe section having an upper run and a lower run arranged in a vertical plane, positioning the probe section in the boiler flue gas stream at a point where the temperature is above the temperature where maximum corrosion occurs to be wiped by the flue gas stream, connecting the probe section to a coolant tank having a condensing coil mounTed therein, filling the coolant tank with an organic solvent having a boiling point about the same as where maximum corrosion exists to a level slightly below the condensing coil and subjecting the condensing coil to the cooling action of a cooling media, wherein boiling of the coolant in the probe causes constant recirculation between the tank and probe thereby continually cooling the probe and maintaining it at a constant corroding temperature.
Claim 18
Dependent Claim
56 words
The method as defined in claim 12, wherein the step of positioning the probe section in the flue gas stream includes subjecting the probe to a temperature of at least 300* F., and wherein the step of filling the tank with an organic solvent includes choosing a solvent having a boiling point of about 250* F.
Claim 19
Independent Claim
92 words
The method of determining the sulphuric acid deposition rate of a boiler flue gas stream comprising the step of connecting a specimen to pipe in the form of a loop defining a probe section and having an upper run and a lower run arranged in a vertical plane, positioning the probe section in a flue gas stream having a temperature above that where acid deposition takes place, cooling the probe section to a temperature where maximum acid deposition takes place, removing the specimen following a test period, and measuring the acid deposition.
Claim 20
Independent Claim
92 words
The method of determining the sulphuric acid deposition rate of a boiler flue gas stream comprising the step of connecting a specimen to pipe in the form of a loop defining a probe section and having an upper run and a lower run arranged in a vertical plane, positioning the probe section in a flue gas stream having a temperature above that where acid deposition takes place, cooling the probe section to a temperature where maximum acid deposition takes place, removing the specimen following a test period, and measuring the acid deposition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-01-20 | 1978-07-22 | 1979-01-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-01-20 | 1982-07-22 | 1983-01-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-01-20 | 1986-07-22 | 1987-01-21 | $7700.00 | Window Closed / Lapsed |