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US3859261A
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Azides
Assignee: Hercules LLC
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Filing: 1972-12-20
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Granted: 1975-01-07
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Expires: 1992-12-20
Abstract
Abstract Disclosed are azides of the formula WHEREIN R is a polyvalent organic radical, and n and m are each 1-10. They are useful for bonding receptive polymers to ethylenically unsaturated hydrocarbon silane treated glass and, particularly when m 1, for linking together the polymer chains of receptive polymers. Because in the reaction of these compounds with receptive polymers the azidoformate radicals react substantially faster than the azidosulfonyl radicals, linking of receptive polymers with these compounds can be effected in two steps. (1) After forming a blend of receptive polymer and azide of the formula, establishing and maintaining the blend in a temperature range for a period of time selected to permit at least a substantial portion of the azidoformate radicals to react with the polymer with a minimum of the azidosulfonyl radicals having reacted with the polymer, whereby a substantially nonlinked, but reacted, polymer (ankylomeric polymer) is formed, and (2) establishing and maintaining the ankylomeric polymer in a temperature range for a period of time selected to permit at least a substantial portion of the azidosulfonyl radicals to react with the ankylomeric polymer, whereby linking of the polymer chains takes place.
Inventors
- 👤 David S Breslow
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 17:52
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C08J5/08; C08G; C08G81/00; C08K; C08K5/00; C08K5/36; C08K5/43
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
33 words
A process according to cLaim 1, wherein said blend is established and maintained in a temperature range for a period of time selected to effect combination reaction of a substantial portion of the
Claim 2
Dependent Claim
146 words
A process for making an ankylomeric polymer product, which comprises: forming a blend of (1) at least one polymer selected from the group consisting of saturated, unsaturated, linear, non-linear, crystalline and amorphous hydrocarbon homopolymers, copolymers and terpolymers; cellulose esters; cellulose ethers; polyesters; poly(alkylene oxide) polymers; polyamides; condensation products of triallyl pentaerythritol and diallylidene pentaerythritol; esters of triallyl pentaerythritol and drying oil fatty acids; poly(vinyl alkyl ethers); poly(vinyl acetals); vinyl chloride polymers having a vinyl chloride content of at least ten mol percent; nitrocellulose; chlorinated natural rubber; sulfochlorinated polyethylene; polysulfide rubber; polyurethane rubber; poly(vinyl acetate); ethylene-vinyl acetate copolymer; poly(vinylidene chloride); vinylidene chloride-acrylonitrile copolymers; ethyl acrylate-2-chloroethyl vinyl ether copolymers; poly(ethyl acrylate); poly(ethyl methacrylate); poly(3,3-bis(chloromethyl)oxetane); vinyl modified poly(dimethyl siloxane); polychloroprene; and butadiene-acrylonitrile copolymers; and (2) from about 0.01 to about 50% by weight based on the weight of the polymer of at least one azide compound having the formula
Claim 3
Dependent Claim
31 words
A process which comprises: establishing and maintaining an ankylomeric polymer product at an elevated temperature range for a period of time selected to effect reaction of a substantial portion of the
Claim 4
Dependent Claim
122 words
An ankylomeric polymer comprising a polymer selected from the group consisting of saturated, unsaturated, linear, non-linear, crystalline and amorphous hydrocarbon homopolymers, copolymers and terpolymers; cellulose esters; cellulose ethers; polyesters; poly(alkylene oxide) polymers; polyamides; condensation products of triallyl pentaerythritol and diallylidene pentaerythritol; esters of triallyl pentaerythritol and drying oil fatty acids; poly(vinyl alkyl ethers); poly(vinyl acetals); vinyl chloride polymers having a vinyl chloride content of at least ten mol percent; nitrocellulose; chlorinated natural rubber; sulfochlorinated polyethylene; polysulfide rubber; polyurethane rubber; poly(vinyl acetate); ethylene-vinyl acetate copolymer; poly(vinylidene chloride); vinylidene chlorideacrylonitrile copolymers; ethyl acrylate-2-chloroethyl vinyl ether copolymers; poly(ethyl acrylate); poly(ethyl methacrylate); poly(3,3-bis(chloromethyl)oxetane); vinyl modified poly(dimethyl siloxane); polychloroprene; and butadiene-acrylonitrile copolymers, which has been modified by reaction with at least one azide compound having the formula
Claim 5
Dependent Claim
115 words
A polymer selected from the group consisting of saturated, unsaturated, linear, non-linear, crystalline and amorphous hydrocarbon homopolymers, copolymers and terpolymers; cellulose esters; cellulose ethers; polyesters; poly(alkylene oxide) polymers; polyamides; condensation products of triallyl pentaerythritol and diallylidene pentaerythritol; esters of triallyl pentearythritol and drying oil fatty acids; poly(vinyl alkyl ethers); poly(vinyl acetals); vinyl chloride polymers having a vinyl chloride content of at least ten mol percent; nitrocellulose; chlorinated natural rubber; sulfochlorinated polyethylene; polysulfide rubber; polyurethane rubber; poly(vinyl acetate); ethylene-vinyl acetate copolymer; poly(vinylidene chloride); vinylidene chloride-acrylonitrile copolymers; ethyl acrylate-2-chloroethyl vinyl ether copolymers; poly(ethyl acrylate); poly(ethyl methacrylate); poly(3,3-bis(chloromethyl)oxetane); vinyl modified poly(dimethyl siloxane); polychloroprene; and butadiene-acrylonitrile copolymers cross-linked by reaction with at least one azide compound having the formula
Claim 6
Dependent Claim
139 words
A CROSS-LINKABLE COMPOSITION COMPRISING A BLEND OF (1) AT LEAST ONE POLYMER SELECTED FROM THE GROUP CONSISTING OF SATURATED, UNSATURATED, LINEAR, NON-LINEAR, CRYSTALLINE AND AMORPHOUS HYDROCARBON HOMOPOLYMERS, COPOLYMERS AND TERPOLYMERS; CELLULOSE ESTERS; CELLULOSE ESTHERS; POLYESTERS; POLY(ALKYLENE OXIDE) POLYMERS; POLYAMIDES; CONDENSATION PRODUCTS OF TRIALLYL PENTAERYTHRITOL AND DIALLYLIDENE PENTAERYTHRITOL; ESTERS OF TRIALLYL PENTAERYTHRITOL AND DRYING OIL FATTY ACIDS; POLY(VINYL ALKYL ETHERS); POLY(VINYL ACETALS); VINYL CHLORIDE POLYMERS HAVING A VINYL CHLORIDE CONTENT OF AT LEAST TEN MOL PERCENT; NITROCELLULOSE; CHLORINATED NATURAL RUBBER; SULFOCHLORINATED POLYETHYLENE; POLYSULFIDE RUBBER; POLYURETHANE RUBBER; POLY(VINYL ACETATE); ETHYLENE-VINYL ACETATE COPOLYMER; POLY(VINYLIDENE CHLORIDE); VINYLIDENE CHLORIDE-ACRYLONITRILE COPOLYMERS; ETHYL ACRYLATE-2-CHLOROETHYL VINYL ETHER COPOLYMERS; POLY(ETHYL ACRYLATE); POLY(ETHYL METHACRYLATE); POLY(3,3-BIS(CHLOROMETHYL)OXETANE); VINYL MODIFIED POLY(DIMETHYL SILOXANE); POLYCHLOROPRENE; AND BUTADIENEACRYLONITRILE COPOLYMERS; AND (2) FROM ABOUT 0.01 TO ABOUT 50% BY WEIGHT BASED ON THE WEIGHT OF THE POLYMER OF AT LEAST ONE AZIDE COMPOUND HAVING THE FORMULA
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-01-06 | 1978-07-08 | 1979-01-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-01-06 | 1982-07-08 | 1983-01-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-01-06 | 1986-07-08 | 1987-01-07 | $7700.00 | Window Closed / Lapsed |