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US3859252A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyamido polysulfone thermoplastics and intermediates thereof

Assignee: Uniroyal Chemical Co Inc
•
Filing: 1972-04-28
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Granted: 1975-01-07
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Expires: 1992-04-28
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Abstract

Abstract Thermoplastic copolymers having both bis-amide moieties and polyarylene bis-sulfone moieties in the recurring structural units of the chains are formed by the interaction of (1) polyarylene bis-sulfone monomers having two terminal amideforming groups and (2) difunctional compounds having two terminal amide-forming groups complementary to those of the polysulfone monomers. Thus, a diamino polyarylene polysulfone monomer is condensed with a di-acid chloride or anhydride; or, a polyarylene di-sulfone di(carboacid chloride) monomer is condensed with an aromatic diamine.

Inventors

  • 👤 Iwhan Cho

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 09:40
CPC Classifications
C; C07; C07C; C07C317/00; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/32; C08G69/42; C08G75/00; C08G75/20

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 48 words
THERMOPLASTIC CONDENSATION INTERPOLYMERS IN WHICH THE RECURRING UNIT HAS THE STRUCTURE (-AR'' -SO2-X-SO2-AR'' - (BIS-AMIDE STRUCTURE))-, WHEREIN X IS ARYLENE OR OXYDIARYLENE, AR'' IS PHENYLENE, "BISAMIDE STRUCTURE" IS -NH-CO-R-CO-NH-, -CO-NH-R'' -NH-CO- OR -NH-SO2-R" -SO2-NH-, R IS ALKYLENE OR PHENYLENE, R'' IS PHENYLENE OR P,P''-DIPHENYLENE, AND R" IS P,P''-OXYDIPHENYLENE.
Claim 2
Dependent Claim 48 words
THERMOPLASTIC CONDENSATION INTERPOLYMERS IN WHICH THE RECURRING UNIT HAS THE STRUCTURE (-AR'' -SO2-X-SO2-AR'' - (BIS-AMIDE STRUCTURE))-, WHEREIN X IS ARYLENE OR OXYDIARYLENE, AR'' IS PHENYLENE, "BISAMIDE STRUCTURE" IS -NH-CO-R-CO-NH-, -CO-NH-R'' -NH-CO- OR -NH-SO2-R" -SO2-NH-, R IS ALKYLENE OR PHENYLENE, R'' IS PHENYLENE OR P,P''-DIPHENYLENE, AND R" IS P,P''-OXYDIPHENYLENE.
Claim 3
Dependent Claim 35 words
Interpolymers according to claim 1 wherein the -Ar''-SO2-X-SO2-Ar''- component is provided by a bis(aminophenylsulfonyl) arylene monomer and the -(bis-amide structure)- is -NH-CO-R-CO-NH-, the -CO-R-CO- portion thereof being provided by an organic di-acid chloride or anhydride.
Claim 4
Dependent Claim 16 words
Interpolymers according to claim 2 wherein said -CO-R-CO-portion is provided by an aromatic dicarboxylic acid chloride.
Claim 5
Dependent Claim 13 words
Interpolymers according to claim 2 wherein said -CO-R-CO-portion is provided by isophthaloyl chloride.
Claim 6
Dependent Claim 15 words
Interpolymers according to claim 2 wherein said -CO-R-CO-portion is provided by an alkanedioic acid chloride.
Claim 7
Dependent Claim 13 words
Interpolymers according to claim 2 wherein said -CO-R-CO-portion is provided by sebacoyl chloride.
Claim 8
Dependent Claim 33 words
Interpolymers according to claim 1 wherein the -Ar''-SO2-X-SO2-Ar''- component is provided by a bis(aminophenylsulfonyl)arylene monomer and the -(bis-amide structure)- is -NH-SO2-R''''-SO2-NH-, the -SO2-R''''-SO2- portion thereof being provided by an oxy aromatic disulfonyl chloride.
Claim 9
Dependent Claim 13 words
Interpolymers according to claim 7 wherein the -Ar''-SO2-X-SO2-Ar''- component is provided by 4,4''-oxybis(4-(phenylsulfonyl)aniline).
Claim 10
Dependent Claim 14 words
Interpolymers according to claim 7 wherein said -SO2-R''''-SO2-portion is provided by oxydiphenylene disulfonyl chloride.
Claim 11
Dependent Claim 13 words
Interpolymers according to claim 2 wherein the -Ar''-SO2-X-SO2-Ar''- component is provided by 4,4''-biphenylenebis-(4-sulfonylaniline).
Claim 12
Dependent Claim 30 words
Interpolymers according to claim 1 wherein the -Ar''-SO2-X-SO2-Ar''- component is provided by an oxybis(p-phenylsulfonylbenzoylchloride) and the -(bis-amide structure)- is -CO-NH-R''-NH-CO-, the -NH-R''-NH- portion thereof being provided by an aromatic diamine.
Claim 13
Dependent Claim 13 words
Interpolymers according to claim 11 wherein the -Ar''-SO2-X-SO2-Ar''- component is provided by 4,4''-oxybis(p-phenylsulfonylbenzoylchloride).
Claim 14
Dependent Claim 12 words
Interpolymers according to claim 11 wherein said -NH-R''-NH-portion is provided by m-phenylenediamine.
Claim 15
Dependent Claim 14 words
Interpolymers according to claim 11 wherein the said -NH-R''-NH- portion is provided by p,p-biphenylenediamine.
Claim 16
Dependent Claim 10 words
A shaped article composed of the interpolymers of claim 1.

References Cited (Backward Citations)

US3505288A Cited
US3503931A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-01-06 1978-07-08 1979-01-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-01-06 1982-07-08 1983-01-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-01-06 1986-07-08 1987-01-07 $7700.00 Window Closed / Lapsed

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