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US3857915A Expired / Lapsed US ⏱️ 0.0 years remaining

Embossed plastic surface covering and method of preparing same

Assignee: Individual
•
Filing: 1972-02-22
•
Granted: 1974-12-31
•
Expires: 1992-02-22
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Abstract

Abstract A chemically embossed vinyl chloride resin sheet material is prepared by treating the gelled surface of a vinyl chloride resin plastisol containing a blowing agent with a liquid which contains a monomer subject to polymerization and a polymerization catalyst for said monomer, whereby on subsequent heating of the treated gelled vinyl chloride resin sheet material and decomposition of the blowing agent, full expansion of the sheet material is prevented by the polymerization of the monomer in the treated areas, thereby producing a chemically embossed product.

Inventors

  • 👤 R Crowley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 22:28
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/04; C08J9/06; Y; Y10; Y10S; Y10S264/00; Y10S264/82

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 107 words
A METHOD OF CHEMICALLY EMBOSSING A GAS-EXPANDABLE VINYL-CHLORIDE RESIN SHEET MATERIAL, WHICH METHOD COMPRISES: A. APPLYING TO SURFACE PORTIONS OF SAID SHEET MATERIAL IN A PREDETERMINED PATTERN AN ESTER OF ACRYLIC ACID AND A PEROXIDE CROSS LINKING AGENT WHICH WILL CROSS-LINK SAID ESTER ON HEATING; AND B. HEATING THE TREATED SHEET MATERIAL TO A TEMPERATURE SUFFICIENT TO POLYMERIZE THE ESTER BY THE CROSS-LINING AGENT AND TO CAUSE THE SHEET TO EXPAND, WHEREBY THE SURFACE OF THE PORTION OF THE SHEET MATERIAL TO WHICH THE UNSATURATED COMPOUND HAS NOT BEEN APPLIED RISES ABOVE THE LEVEL OF THE SURFACE OF THE APPLIED PORTIONS TO FORM A CHEMICALLY EMBOSSED PRODUCT.
Claim 2
Independent Claim 107 words
A METHOD OF CHEMICALLY EMBOSSING A GAS-EXPANDABLE VINYL-CHLORIDE RESIN SHEET MATERIAL, WHICH METHOD COMPRISES: A. APPLYING TO SURFACE PORTIONS OF SAID SHEET MATERIAL IN A PREDETERMINED PATTERN AN ESTER OF ACRYLIC ACID AND A PEROXIDE CROSS LINKING AGENT WHICH WILL CROSS-LINK SAID ESTER ON HEATING; AND B. HEATING THE TREATED SHEET MATERIAL TO A TEMPERATURE SUFFICIENT TO POLYMERIZE THE ESTER BY THE CROSS-LINING AGENT AND TO CAUSE THE SHEET TO EXPAND, WHEREBY THE SURFACE OF THE PORTION OF THE SHEET MATERIAL TO WHICH THE UNSATURATED COMPOUND HAS NOT BEEN APPLIED RISES ABOVE THE LEVEL OF THE SURFACE OF THE APPLIED PORTIONS TO FORM A CHEMICALLY EMBOSSED PRODUCT.
Claim 3
Dependent Claim 14 words
The method of claim 1 wherein the ester of acrylic acid is allyl acrylate.
Claim 4
Dependent Claim 13 words
The method of claim 1 wherein the peroxide cross-linking agent is benzoyl peroxide.
Claim 5
Dependent Claim 22 words
The method of claim 1 wherein said sheet material, prior to the applying step, is essentially free of any polymerizable materials therein.
Claim 6
Dependent Claim 23 words
The method of claim 1 wherein the ester is applied to the selected portions of the sheet material in a liquid printing ink.
Claim 7
Dependent Claim 14 words
The method of claim 5 wherein the printing ink contains the peroxide cross-linking agent.
Claim 8
Dependent Claim 28 words
The method of claim 5 wherein the printing ink contains from about 5 to 50 percent of the ester and about 2 to 25 percent of the peroxide.

References Cited (Backward Citations)

US3098831A Cited
US3098832A Cited
US3365353A Cited
US3538204A Cited
US3453171A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-30 1978-07-01 1978-12-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-30 1982-07-01 1982-12-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-30 1986-07-01 1986-12-31 $7700.00 Window Closed / Lapsed

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