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US3857773A Expired / Lapsed US ⏱️ 0.0 years remaining

Suppression of crevice corrosion in gasketed titanium crevices by the use of rubber compound gaskets substantially free of calcium

Assignee: PPG Industries Inc
•
Filing: 1973-04-05
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Granted: 1974-12-31
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Expires: 1993-04-05
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Abstract

Abstract Disclosed herein is a method of reducing crevice corrosion in titanium structures having gasketed joints, by the use of rubber gaskets characterized by the substantial absence of calcium. Also disclosed is a method of electrolysis in a titanium vessel having gasketed titanium joints with rubber gaskets substantially free of calcium in the joints and crevices.

Inventors

  • 👤 Bois D Du
  • 👤 W Darlington

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 05:41
CPC Classifications
C; C25; C25B; C25B9/00; F; F16; F16J; F16J15/00; F16J15/02; F16J15/06; F16J15/10; F16J15/102

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 72 words
A METHOD OF PREVENTING CERVICE CORROSION WHICH IS ENCOUNTERED BETWEEN A PAIR OF CLOSELY SPACED SURFACES DURING ELCTROLYSIS UNDER ACIDIC CONDITIONS IN AN ELECTROLYTIC CELL WHEREIN AT LEAST ONE OF SAID SURFACES IS TITANIUM WHICH METHOD COMPRISES PROVIDING A RUBBER GASKET BETWEEN SAID SURFACES IN CONTACT WITH THE TITANIUM WHICH RUBBER GASKET CONTAINS LESS THAN 0.07 WEIGHT PERCENT CALCIUM, DETERMINED BY ATOMIC ABSORPTION SPECTROSCOPY, WHEREBY SAID GASKET IS SUBSTANTIALLY FREE OF CALCIUM.
Claim 2
Independent Claim 72 words
A METHOD OF PREVENTING CERVICE CORROSION WHICH IS ENCOUNTERED BETWEEN A PAIR OF CLOSELY SPACED SURFACES DURING ELCTROLYSIS UNDER ACIDIC CONDITIONS IN AN ELECTROLYTIC CELL WHEREIN AT LEAST ONE OF SAID SURFACES IS TITANIUM WHICH METHOD COMPRISES PROVIDING A RUBBER GASKET BETWEEN SAID SURFACES IN CONTACT WITH THE TITANIUM WHICH RUBBER GASKET CONTAINS LESS THAN 0.07 WEIGHT PERCENT CALCIUM, DETERMINED BY ATOMIC ABSORPTION SPECTROSCOPY, WHEREBY SAID GASKET IS SUBSTANTIALLY FREE OF CALCIUM.
Claim 3
Dependent Claim 22 words
The method of claim 1 wherein the rubber is chosen from the group consisting of ethylene-propylene-diene rubber, neoprene rubber, and isoprene rubber.
Claim 4
Dependent Claim 29 words
The method of claim 1 wherein said rubber compound contains a filler chosen from the group consisting of carbon black, silica fibers, amorphous silica, sodium silicate, and magnesium silicate.
Claim 5
Dependent Claim 22 words
The method of claim 1 wherein said rubber compound contains less than 10 percent calcium in the ash determined by emission spectroscopy.
Claim 6
Dependent Claim 71 words
In an electrolytic cell having an anode and a cathode in a vessel, wherein said vessel comprises at least one titanium member separated from another member by a gasket with a crevice therebetween subject to crevice corrosion, the improvement wherein said gasket in contact with said titanium comprises a rubber compound containing less than 0.07 weight percent calcium, determined by atomic absorption spectroscopy, where said gasket is substantially free of calcium.
Claim 7
Dependent Claim 71 words
In an electrolytic cell having an anode and a cathode in a vessel, wherein said vessel comprises at least one titanium member separated from another member by a gasket with a crevice therebetween subject to crevice corrosion, the improvement wherein said gasket in contact with said titanium comprises a rubber compound containing less than 0.07 weight percent calcium, determined by atomic absorption spectroscopy, where said gasket is substantially free of calcium.
Claim 8
Dependent Claim 21 words
The electrolytic cell of claim 5 wherein the rubber is chosen from the group consisting of ethylene-propylene-diene rubber, and neoprene rubber.
Claim 9
Dependent Claim 30 words
The electrolytic cell of claim 5 wherein said rubber compound comprises a filler chosen from the group consisting of carbon black, silica fibers, amorphous silica, sodium silicate, and magnesium silicate.
Claim 10
Dependent Claim 24 words
The electrolytic cell of claim 5 wherein said rubber compound comprises less than 10 weight percent calcium in the ash determined by emission spectroscopy.

References Cited (Backward Citations)

US3436324A Cited
US3591483A Cited
US3576726A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-30 1978-07-01 1978-12-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-30 1982-07-01 1982-12-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-30 1986-07-01 1986-12-31 $7700.00 Window Closed / Lapsed

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