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US3856530A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic polyester film material comprising antistatic layer

Assignee: Agfa Gevaert NV
•
Filing: 1973-07-30
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Granted: 1974-12-24
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Expires: 1993-07-30
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Abstract

Abstract A photographic film material comprising a polyester film support and at least one silver halide emulsion layer is provided with an antistatic coating comprising a homogeneous mixture of (A) a chlorine-containing polymer consisting of at least 70% by weight of at least one monomer taken from vinyl chloride and vinylidene chloride, and (B) a polymeric material having electroconductive properties, the ratio of chlorine-containing polymer to electroconductive polymeric material varying between 2:1 and 1:2 parts by weight.

Inventors

  • 👤 Paesschen A Van
  • 👤 J Herbots
  • 👤 D Timmerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 14:33
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/85; G03C1/89; C; C08; C08L; C08L27/00; C08L27/02; C08L27/04; C08L35/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 131 words
PHOTOGRAPHIC FILM MATERIAL COMPRISING A POLYESTER FILM SUPPORT, AT LEAST ONE LIGHT-SENSITIVE HALIDE EMULSION LAYER ON ONE SIDE OF THE POLYESTER SUPPORT, AND ON THE OTHER SIDE A LAYER OF AN ANTISTATIC COATING COMPOSITION FOR A POLYESTER FILM SUPPORT, COMPRISING AN HOMOGENUOS MIXTURE OF (A) A CHLORINE-CONTAINING POLYMER CONSISTING OF AT LEAST 70% BY WEIGHT OF AT LEAST ONE MONOMER TAKEN FROM VINYL CHLORIDE AND VINYLIDENE CHLORIDE, (B) A POLYMERIC MATERIAL HAVING ELECTROCONDUCTIVE PROPERTIES, AND (C) ABOUT 10 TO 20% BY WEIGHT OF A WZXY MATERIAL, THE RATIO OF CHLORINE-CONTAINING POLYMER TO ELECTROCONDUCTIVE POLYMERIC MATERIAL IN SAID HOMOGENEOUS MIXTURE VARYING BETWEEN 2:1 AND 1:2 PARTS BY WEIGHT, SAID COMPOSITION HAVING A SURFACE RESISTANCE OF 30% RH OF LESS THAN 1.10**10 OHM/10 SQ.CM AND AT 60% RH LESS THAN 1.10**9 OHM/10 SQ.CM.
Claim 2
Dependent Claim 131 words
PHOTOGRAPHIC FILM MATERIAL COMPRISING A POLYESTER FILM SUPPORT, AT LEAST ONE LIGHT-SENSITIVE HALIDE EMULSION LAYER ON ONE SIDE OF THE POLYESTER SUPPORT, AND ON THE OTHER SIDE A LAYER OF AN ANTISTATIC COATING COMPOSITION FOR A POLYESTER FILM SUPPORT, COMPRISING AN HOMOGENUOS MIXTURE OF (A) A CHLORINE-CONTAINING POLYMER CONSISTING OF AT LEAST 70% BY WEIGHT OF AT LEAST ONE MONOMER TAKEN FROM VINYL CHLORIDE AND VINYLIDENE CHLORIDE, (B) A POLYMERIC MATERIAL HAVING ELECTROCONDUCTIVE PROPERTIES, AND (C) ABOUT 10 TO 20% BY WEIGHT OF A WZXY MATERIAL, THE RATIO OF CHLORINE-CONTAINING POLYMER TO ELECTROCONDUCTIVE POLYMERIC MATERIAL IN SAID HOMOGENEOUS MIXTURE VARYING BETWEEN 2:1 AND 1:2 PARTS BY WEIGHT, SAID COMPOSITION HAVING A SURFACE RESISTANCE OF 30% RH OF LESS THAN 1.10**10 OHM/10 SQ.CM AND AT 60% RH LESS THAN 1.10**9 OHM/10 SQ.CM.
Claim 3
Dependent Claim 13 words
A material according to claim 1 wherein the waxy material is N, N-ethylene-bis-oleylamide.
Claim 4
Dependent Claim 133 words
Photographic film material comprising a polyester film support, at least one light-sensitive silver halide emulsion layer on one side of the polyester support, and on the other side a layer of an antistatic coating composition for a polyester film support, comprising an homogeneous mixture of (A) a chlorine-containing polymer consisting of at least 70% by weight of at least one monomer taken from vinyl chloride and vinylidene chloride, and (B) a polymeric material having electroconductive properties, the ratio of chlorine-containing polymer to electroconductive polymeric material in said homogeneous mixture varying between 2:1 and 1:2 parts by weight, said composition having a surface resistance at 30% RH of less than 1.1010 ohm/10 sq.cm. and at 60% RH less than 1.109 ohm/10 sq.cm., said antistatic layer having a thickness not greater than about 1 micron.
Claim 5
Dependent Claim 133 words
Photographic film material comprising a polyester film support, at least one light-sensitive silver halide emulsion layer on one side of the polyester support, and on the other side a layer of an antistatic coating composition for a polyester film support, comprising an homogeneous mixture of (A) a chlorine-containing polymer consisting of at least 70% by weight of at least one monomer taken from vinyl chloride and vinylidene chloride, and (B) a polymeric material having electroconductive properties, the ratio of chlorine-containing polymer to electroconductive polymeric material in said homogeneous mixture varying between 2:1 and 1:2 parts by weight, said composition having a surface resistance at 30% RH of less than 1.1010 ohm/10 sq.cm. and at 60% RH less than 1.109 ohm/10 sq.cm., said antistatic layer having a thickness not greater than about 1 micron.
Claim 6
Dependent Claim 23 words
A material according to claim 3 wherein said antistatic layer has a thickness in the range between about 0.4 and about 1 micron.
Claim 7
Dependent Claim 26 words
A material according to claim 3 wherein the chlorine-containing polymer is a copolymer of vinyl chloride and vinyl acetate containing 87% by weight of vinyl chloride.
Claim 8
Dependent Claim 26 words
A material according to claim 3 wherein the chlorine-containing polymer is the copolymer of vinylidene chloride, N-tert-butylacrylamine, n-butyl acrylate and itaconic acid (70:23: 3:4% by weight).
Claim 9
Dependent Claim 28 words
A material according to claim 3 wherein the polymeric material having electroconductive properties is the sodium salt of the copolymer of styrene and maleic acid (50:50 mole %).
Claim 10
Dependent Claim 33 words
A material according to claim 3 wherein the polymeric material having electroconductive properties is the sodium salt of the copolymer of N-(methacryloyloxyethyl)-trimethylammonium methylsulphate, Beta -chloroethyl acrylate and acrylic acid (60: 25:15 mole %).

References Cited (Backward Citations)

US2627088A Cited
US3514291A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-23 1978-06-24 1978-12-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-23 1982-06-24 1982-12-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-23 1986-06-24 1986-12-24 $7700.00 Window Closed / Lapsed

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