Patent US3856512A successfully refreshed from Google Patents.
US3856512A
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Processing titaniferous iron ores for the recovery of aluminum, chromium, iron, titanium and vanadium
Assignee: Centre de Recherche Industrielle du Quebec CRIQ
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Filing: 1973-04-27
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Granted: 1974-12-24
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Expires: 1993-04-27
Abstract
Abstract An improved process is provided for to separate iron from titaniferous iron ores by roasting the latter in the presence of a roasting agent made up of a mixture of sodium oxide producing compound and calcium or magnesium oxides or a calcium oxide or magnesium oxide producing compound whereby chromium, vanadium and aluminum oxides can be readily leached out from the ore.
Inventors
- 👤 J Palmer
- 👤 G Handfield
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 23:00
CPC Classifications
C; C22; C22B; C22B1/00; C22B1/02; C22B34/00; C22B34/10; C22B34/12; C22B34/1204
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
217 words
A PROCESS FOR TREATING TITANIFEROUS IRON ORE OR CONCENTRATE HAVING A TOTAL IRON CONTENT OF AT LEAST 40% AND A TITANIUM DIOXIDE CONTENT OF LESS THAN 25% WHICH COMPRISES A. ROASTING THE FINELY DIVIDED TITANIFEROUS IRON ORE OR CONCENTRATE IN ANN OXIDIZING ATMOSPHERE AND IN THE PRESENCE OF A ROASTING AGENT MADE UP OF A MIXTURE OF (1) A SODIUM OXIDE FORMING COMPOUND AND (2) AN ALKALINE EARTH METAL OXIDE COMPOUND SELECTED FROM CALCIUM OXIDE, MAGNESIUM OXIDE, A CALCIUM OXIDE FORMING COMPOUND, A MAGNESIUM OXIDE FORMING COMPOUND AND MIXTURE THEREOF, THE AMOUNT OF SODIUM OXIDE OR SODIUM OXIDE FORMING COMPOUND BEING AT LEAST THE STOICHIOMETRIC AMOUNT EXPRESSED AS SODIUM OXIDE AND CALCULATED IN ACCORDANCE WITH THE FORMULA: NA2O(MOLES) =2 $ CR2O3(MOLES) + 3 $ V2O5(MOLES) + AL2O3(MOLES) AND THE AMOUNT OF THE SECOND OXIDE FORMING COMPOUND OF THE ROASTING AGENT BEING AT LEAST THE STOICHIOMETRIC AMOUNT EXPRESSED AS CALCIUM OXIDE OR MAGNESIUM OXIDE CALCULATED IN ACCORDANCE WITH THE FORMULA: CAO OR MGO(MOLES) =2 $ SIO2(MOLES) + TIO2(MOLES) - (CAO + MGO) (MOLES IN THE ORE OR CONCENTRATE) B. LEACHING THE ROAST WITH AN AQUEOUS SOLUTION OF 5 TO 75 GR/L OF SODIUM CARBONATE AND 2 TO 10 GR/L OF SODIUM HYDROXIDE; C. AND SEPARATING THE SOLID CONTAINING THE RESIDUE FROM THE CHROMATE, ALUMINATE AND VANADATE CONTAINING SOLUTION.
Claim 2
Dependent Claim
217 words
A PROCESS FOR TREATING TITANIFEROUS IRON ORE OR CONCENTRATE HAVING A TOTAL IRON CONTENT OF AT LEAST 40% AND A TITANIUM DIOXIDE CONTENT OF LESS THAN 25% WHICH COMPRISES A. ROASTING THE FINELY DIVIDED TITANIFEROUS IRON ORE OR CONCENTRATE IN ANN OXIDIZING ATMOSPHERE AND IN THE PRESENCE OF A ROASTING AGENT MADE UP OF A MIXTURE OF (1) A SODIUM OXIDE FORMING COMPOUND AND (2) AN ALKALINE EARTH METAL OXIDE COMPOUND SELECTED FROM CALCIUM OXIDE, MAGNESIUM OXIDE, A CALCIUM OXIDE FORMING COMPOUND, A MAGNESIUM OXIDE FORMING COMPOUND AND MIXTURE THEREOF, THE AMOUNT OF SODIUM OXIDE OR SODIUM OXIDE FORMING COMPOUND BEING AT LEAST THE STOICHIOMETRIC AMOUNT EXPRESSED AS SODIUM OXIDE AND CALCULATED IN ACCORDANCE WITH THE FORMULA: NA2O(MOLES) =2 $ CR2O3(MOLES) + 3 $ V2O5(MOLES) + AL2O3(MOLES) AND THE AMOUNT OF THE SECOND OXIDE FORMING COMPOUND OF THE ROASTING AGENT BEING AT LEAST THE STOICHIOMETRIC AMOUNT EXPRESSED AS CALCIUM OXIDE OR MAGNESIUM OXIDE CALCULATED IN ACCORDANCE WITH THE FORMULA: CAO OR MGO(MOLES) =2 $ SIO2(MOLES) + TIO2(MOLES) - (CAO + MGO) (MOLES IN THE ORE OR CONCENTRATE) B. LEACHING THE ROAST WITH AN AQUEOUS SOLUTION OF 5 TO 75 GR/L OF SODIUM CARBONATE AND 2 TO 10 GR/L OF SODIUM HYDROXIDE; C. AND SEPARATING THE SOLID CONTAINING THE RESIDUE FROM THE CHROMATE, ALUMINATE AND VANADATE CONTAINING SOLUTION.
Claim 3
Dependent Claim
29 words
A process according to claim 1 including the further steps of reducing the solid residue obtained to reduce the iron oxide to metallic iron and recovering said metallic iron.
Claim 4
Dependent Claim
34 words
A process according to claim 2 wherein the roasting is carried out at 800* to 1,300*C, and the reducing is carried out using as a reducing agent hydrogen, carbon monoxide, coal, coke or oil.
Claim 5
Dependent Claim
13 words
The process of claim 2 wherein the titaniferous iron ore is titaniferous magnetite.
Claim 6
Dependent Claim
23 words
The process of claim 4 wherein the roasting is carried out in the presence of a mixture of sodium oxide and calcium oxide.
Claim 7
Dependent Claim
16 words
A process according to claim 3 wherein the reducing is carried out at 700* to 1,300*C.
Claim 8
Dependent Claim
16 words
A process according to claim 1 wherein the roasting is carried out at 800* to 1,300*C.
Claim 9
Dependent Claim
33 words
A process according to claim 7 wherein per 100 grams of ore there are employed 9.36 to 15 grams of sodium carbonate and 7.7 to 19.5 grams of calcium carbonate or magnesium carbonate.
Claim 10
Dependent Claim
32 words
A process according to claim 7 wherein the amount of (1) is 5 to 50% over the stoichiometric amount and the amount of (2) is 5 to 30% over the stoichiometric amount.
Claim 11
Dependent Claim
197 words
In a process for treating titaniferous iron ore or concentrate having a total iron content of at least 40% and a titanium dioxide content of less than 25% by roasting said ore or concentrate, leaching the roast, reducing the solid residue obtained in the leach and recovering a metallic iron concentrate, the improvement which comprises carrying out the roasting step of the finely divided titaniferous iron ore in an oxidizing atmosphere and in the presence of a roasting agent made up of (1) a sodium oxide forming compound and (2) an alkaline earth oxide compound selected from calcium oxide, magnesium oxide, a calcium oxide forming compound, a magnesium oxide forming compound and mixtures thereof, the amount of sodium oxide forming compound being at least the stoichiometric amount expressed as sodium oxide calculated in accordance with the formula: Na2O(moles) 2 X Cr2O3(moles) + 3 X V2O5(moles) + Al2O3(moles) and the amount of the second oxide forming compound of the roasting agent being at least the stoichiometric amount expressed as calcium oxide or magnesium oxide calculated in accordance with the formula: CaO or MgO(moles) 2 X SiO2(moles) + TiO2(moles) - (CaO + MgO) (moles present in ore or concentrate).
Claim 12
Dependent Claim
197 words
In a process for treating titaniferous iron ore or concentrate having a total iron content of at least 40% and a titanium dioxide content of less than 25% by roasting said ore or concentrate, leaching the roast, reducing the solid residue obtained in the leach and recovering a metallic iron concentrate, the improvement which comprises carrying out the roasting step of the finely divided titaniferous iron ore in an oxidizing atmosphere and in the presence of a roasting agent made up of (1) a sodium oxide forming compound and (2) an alkaline earth oxide compound selected from calcium oxide, magnesium oxide, a calcium oxide forming compound, a magnesium oxide forming compound and mixtures thereof, the amount of sodium oxide forming compound being at least the stoichiometric amount expressed as sodium oxide calculated in accordance with the formula: Na2O(moles) 2 X Cr2O3(moles) + 3 X V2O5(moles) + Al2O3(moles) and the amount of the second oxide forming compound of the roasting agent being at least the stoichiometric amount expressed as calcium oxide or magnesium oxide calculated in accordance with the formula: CaO or MgO(moles) 2 X SiO2(moles) + TiO2(moles) - (CaO + MgO) (moles present in ore or concentrate).
Claim 13
Dependent Claim
21 words
A process according to claim 10 wherein the roasting is carried out at 800* to 1,300*C for 1/2 to 3 hours.
Claim 14
Dependent Claim
32 words
A process according to claim 11 wherein the amount of (1) is 5 to 50% over the stoichiometric amount and the amount of (2) is 5 to 30% over the stoichiometric amount.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1977-12-23 | 1978-06-24 | 1978-12-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1981-12-23 | 1982-06-24 | 1982-12-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1985-12-23 | 1986-06-24 | 1986-12-24 | $7700.00 | Window Closed / Lapsed |