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US3852065A Expired / Lapsed US ⏱️ 0.0 years remaining

Photoconductive bisphenyl thiocompounds linked by bridging organic group

Assignee: Canon Production Printing Holding BV
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Filing: 1971-05-14
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Granted: 1974-12-03
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Expires: 1991-05-14
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Abstract

Abstract A photoconductive composition useful in electrophotographic processes is provided by utilizing in admixture with an electrically insulating polymeric organic binder a monomeric organic photoconductor which is a bisphenylthio compound wherein at least one of the phenylthio residues carries a para-tertiary amino group and the two thio atoms are linked together by a bridging organic group which may be an aliphatic, atomatic or heterocyclic residue. Preferably, the two phenylthio residues carry similar paratertiary amino groups. The composition is used in the form of a photoconductive layer, either self-supported or carried on a support which may be paper or the like or a conductive surface, depending upon the manner of utilization. A fine powder of the composition containing a sensitizing dysestuff is useful in phototoner processes.

Inventors

  • 👤 A Hectors

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:43
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0601; G03G5/062

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 24 words
A PHOTOCONDUCTIVE COMPOSITION COMPRISING IN ADMIXTURE WITH AN ELECTRICALLY INSULATING POLYMERIC ORGANIC BINDER A MONOMERIC ORGANIC PHOTOCONDUCTOR WHICH IS A COMPOUND HAVING THE FORMULA:
Claim 2
Dependent Claim 24 words
A PHOTOCONDUCTIVE COMPOSITION COMPRISING IN ADMIXTURE WITH AN ELECTRICALLY INSULATING POLYMERIC ORGANIC BINDER A MONOMERIC ORGANIC PHOTOCONDUCTOR WHICH IS A COMPOUND HAVING THE FORMULA:
Claim 3
Dependent Claim 26 words
A photoconductive composition according to claim 1, wherein x is an aliphatic residue selected from the group consisting of alkylene, alkenylene, aliphatic dicarboxylic and cycoaliphatic residues.
Claim 4
Dependent Claim 32 words
A photoconductive composition according to claim 1, wherein X is an aromatic residue selecteD from the group consisting of anthryl, phenylene polyphenylene, naphthylene, dicarboxylic phenyl, pyridine, furane, pyrrol, thiophene and triazine residues.
Claim 5
Dependent Claim 13 words
A photoconductive composition according to claim 3 wherein Z is said amino group
Claim 6
Dependent Claim 13 words
A photoconductive composition according to claim 4 wherein Z is said amino group
Claim 7
Dependent Claim 37 words
A photoconductive composition according to claim 1 wherein said photoconductor is selected from the group consisting of 1,2-bis(4-N,N-diethyl-amino-phenylthio)-ethene, 1,2-bis(4-N,N-dibenzylamino-phenylthio) ethene, 1,2-bis(4-N-methyl-N-cyclopentylamino-phenylthio)ethene, 1,2-bis(4-N,N-diethylamino-phenylthio)-dichloroethene, 1,4-bis (4''-N,N-diethylamino-phenylthio)-butane, 1,2-bis(4-N-butyl-N-benzyl-amino-phenylthio)-ethene, 1,2-bis(4-N(H)cyclohexyl aminophenylthio)-ethene, 1,2-bis(4-morpholinophenylthio)-ethene, 1,4-bis(4''-N,N-diethylamino-phenylthio) phenylene, 2,6-bis(4''-N,N-diethylamino-phenylthio)-aniline, bis (4-N,N-diethyl-amino-phenylthio)-thion, bis(4-N,N-diethylamino-phenylthio)-thiolsuccinate, 1,2-bis(4-N,N-dimethylamino-2-methyl-phenylthio)-ethene and 1,2-bis(4-N,N-diethylamino-phenylthio)ethane.
Claim 8
Dependent Claim 14 words
An electrophotographic material comprising a layer of a photoconductive composition according to claim 1.
Claim 9
Dependent Claim 23 words
An electrophotographic material comprising a support having substantial electrical conductivity and carrying thereon a layer of a photoconductive composition according to claim 1.
Claim 10
Dependent Claim 19 words
An electrophotographic material comprising a paper support carrying thereon a layer of a photoconductive composition according to claim 1.
Claim 11
Dependent Claim 23 words
An electrophotographic material comprising a photoconductive composition according to claim 1 in the form of a fine powder useful as a photoconductive toner.
Claim 12
Dependent Claim 21 words
An electrophotographic material according to claim 10, said powder having an average particle size of the order of approximately 20 microns.
Claim 13
Dependent Claim 48 words
The process of producing an electrophotographic copy which comprises electrostatically charging a layer of a photoconductive composition according to claim 1, imagewise exposing the charged layer to light, and thereafter applying oppositely charged toner particles to said layer and fixing said particles to the unexposed image areas thereof.
Claim 14
Dependent Claim 84 words
The process of producing an electrophotographic copy which comprises applying to an electrically conductive surface a layer of a fine powder the particles of which contain a photoconductive composition according to claim 1 with a sensitizing dyestuff, electrostatically charging said layer, then imagewise exposing it to light, removing from said surface the powder in the exposed image areas of said layer, and transferring from said surface to and fixing on a receiving support the powder remaining in the unexposed image areas of said layer.
Claim 15
Dependent Claim 20 words
A photoconductive composition comprising in admixture with an electrically insulating polymeric organic binder a monomeric organic photoconductor having the formula:
Claim 16
Dependent Claim 20 words
A photoconductive composition comprising in admixture with an electrically insulating polymeric organic binder a monomeric organic photoconductor having the formula:
Claim 17
Dependent Claim 13 words
A photoconductive composition according to claim 1, wherein Z is an amino group

References Cited (Backward Citations)

US2351657A Cited
US2384577A Cited
US2435508A Cited
US2983726A Cited
US3261825A Cited
US3299040A Cited
US3388126A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-02 1978-06-03 1978-12-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-02 1982-06-03 1982-12-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-02 1986-06-03 1986-12-03 $7700.00 Window Closed / Lapsed

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