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US3847796A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrocracking process for the production of lpg

Assignee: Universal Oil Products Co
•
Filing: 1973-03-15
•
Granted: 1974-11-12
•
Expires: 1993-03-15
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Abstract

Abstract Hydrocarbons are converted with a catalyst comprising a Group VIII metal component combined with a support containing alumina and finely divided crystalline mordenite particles. Key feature of the process involves the critical quantity of mordenite present in the composition, thereby effecting and maximizing some basic enhancement of the ability of the resultant catalyst to accelerate hydrocarbon conversion reactions that depend on carbonium ion intermediates: that is, the activity level of the resultant composite is markedly increased.

Inventors

  • 👤 L Hilfman
  • 👤 E Pollitzer
  • 👤 E Michalko

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:58
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/18; B01J29/20

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 128 words
A HYDROGEN-CONSUMING PROCESS FOR SELECTIVELY PRODUCING LPG FROM A HYDROCARBON CHARGE STOCK BOILING BELOW ABOUT 600*F., WHICH COMPRISES CONTACTING SAID CHARGE STOCK AND HYDROGEN WITH A CATALYST COMPRISING A GROUP VIII METAL COMPONENT COMBINED WITH AN ALUMINA CARRIER MATERIAL CONTAINING A UNIFORM DISTRIBUTION OF ABOUT 20 TO ABOUT 30 WEIGHT PERCENT A FINELY DIVIDED MORDENITE PARTICLES AT HYDROCRACKING CONDITIONS INCLUDING A PRESSURE OF ABOUT 300 TO ABOUT 1800 PSIG., A TEMPERATURE OF ABOUT 600*F. TO ABOUT 950*F., A LHSV OF ABOUT 1 TO ABOUT 10 HR.-1 AND A HYDROGEN CIRCULATION RATE OF ABOUT 5000 SCFB TO ABOUT 15,000 SCFB BASED ON FRESH CHARGE STOCK, SAID CATALYST HAVING BEEN PREPARED BY COMMINGLING SAID MORDENITE WITH AN ALUMINUM HALIDE SLO, GELLING THE RESULTANT MIXTURE AND THEN CALCINING THE GELLED MIXTURE.
Claim 2
Dependent Claim 128 words
A HYDROGEN-CONSUMING PROCESS FOR SELECTIVELY PRODUCING LPG FROM A HYDROCARBON CHARGE STOCK BOILING BELOW ABOUT 600*F., WHICH COMPRISES CONTACTING SAID CHARGE STOCK AND HYDROGEN WITH A CATALYST COMPRISING A GROUP VIII METAL COMPONENT COMBINED WITH AN ALUMINA CARRIER MATERIAL CONTAINING A UNIFORM DISTRIBUTION OF ABOUT 20 TO ABOUT 30 WEIGHT PERCENT A FINELY DIVIDED MORDENITE PARTICLES AT HYDROCRACKING CONDITIONS INCLUDING A PRESSURE OF ABOUT 300 TO ABOUT 1800 PSIG., A TEMPERATURE OF ABOUT 600*F. TO ABOUT 950*F., A LHSV OF ABOUT 1 TO ABOUT 10 HR.-1 AND A HYDROGEN CIRCULATION RATE OF ABOUT 5000 SCFB TO ABOUT 15,000 SCFB BASED ON FRESH CHARGE STOCK, SAID CATALYST HAVING BEEN PREPARED BY COMMINGLING SAID MORDENITE WITH AN ALUMINUM HALIDE SLO, GELLING THE RESULTANT MIXTURE AND THEN CALCINING THE GELLED MIXTURE.
Claim 3
Dependent Claim 20 words
The process of claim 1 further characterized in that said Group VIII metal component is platinum or a platinum compound.
Claim 4
Dependent Claim 20 words
The process of claim 1 further characterized in that said Group VIII metal component is palladium or a palladium compound.
Claim 5
Dependent Claim 27 words
The process of claim 1 further characterized in that said Group VIII metal component is present in an amount from about 0.05 to about 1.5 weight percent.
Claim 6
Dependent Claim 20 words
The process of claim 1 further characterized in that said catalyst contains about 0.05 to about 1.5 weight percent halogen.
Claim 7
Dependent Claim 17 words
The process of claim 1 wherein said catalyst contains about 0.1 to about 1.5 weight percent sulfur.

References Cited (Backward Citations)

US3546102A Cited
US3547807A Cited
US3619412A Cited
US3617507A Cited
US3617483A Cited
US3511773A Cited
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US3775298A Cited
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US3620963A Cited
US3707460A Cited
US3769235A Cited
US3718575A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-11-11 1978-05-13 1978-11-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-11-11 1982-05-13 1982-11-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-11-11 1986-05-13 1986-11-12 $7700.00 Window Closed / Lapsed

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