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Method for the treatment of cyanide-containing wastes

Assignee: Mitsubishi Chemical Corp
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Filing: 1973-12-04
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Granted: 1974-11-12
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Expires: 1993-12-04
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Abstract

Abstract This invention relates to a method for the treatment of cyanidecontaining wastes, which method comprises passing a part of cyanide-containing waste from a cyanide-containing waste storage tank in series through a cathode compartment composed of a cathode and cation exchange membrane and an anode compartment composed of an anode and anion exchange membrane and then recirculating to the cyanide-containing waste storage tank, simultaneously passing the other part of cyanide-containing waste in parallel through a plurality of concentration compartments partitioned by a plurality of anion exchange membranes and cation exchange membranes arranged alternately and then recirculating to the cyanide-containing waste storage tank, and simultaneously passing a solution of an alkali metal chloride or alkaline earth metal chloride from an alkali metal chloride or alkaline earth metal chloride solution storage tank in parallel through a plurality of dilution compartments partitioned by a plurality of anion exchange membranes and cation exchange membranes arranged alternately and then recirculating to the alkali metal chloride or alkaline earth metal chloride solution storage tank.

Inventors

  • 👤 T Uno
  • 👤 K Uosaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 09:10
CPC Classifications
B; B01; B01D; B01D61/00; B01D61/42; B01D61/44; B01J; B01J47/00; B01J47/12; C; C02; C02F; C02F1/00; C02F1/46; C02F1/461; C02F1/467; C02F1/4672; C02F1/4674; C02F1/469; C02F1/4693; C02F2101/00; C02F2101/10; C02F2101/16; C02F2101/18; C02F2201/00; C02F2201/46; C02F2201/461; C02F2201/46105; C02F2201/46115; C02F2201/4618; C02F2201/46185

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 162 words
A METHOD FOR THE TREATMENT OF CYANIDE-CONTAINING WASTES, WHICH COMPRISES PASSING A PART OF CYANIDE-CONTAINING WASTE FROM A CYANIDE-CONTAINING WASTE STORAGE TANK IN SERIES THROUGH A CATHODE COMPARTMENT COMPOSED OF A CATHODE AND CATION EXCHANGE MEMBRANE AND AN ANODE COMPARTMENT COMPOSED OF AN ANODE AND ANION EXCHANGE MEMBRANE AND THEN RECIRCULATING TO THE CYANIDE-CONTAINING WASTE STORAGE TANK, SIMULTANEOUSLY PASSING THE OTHER PART OF CYANIDE-CONTAINING WASTE IN PARALLEL THROUGH A PLURALITY OF CONCENTRATION COMPARTMENTS PARTIONED BY A PLURALITY OF ANION EXCHANGE MEMBRANES AND CATION EXCHANGE MEMBRANES ARRANGED ALTERNATELY AND THEN RECIRCULATING TO THE CYANIDE-CONTAINING WASTE STORAGE TANK, AND SIMULTANEOUSLY PASSING A SOLUTION OF AN ALKALI METAL CHLORIDE OR ALKALINE EARTH METAL CHLORIDE FROM AN ALKALI METAL CHLORIDE OR ALKALINE EARTH METAL CHLORIDE SOLUTION STORAGE TANK IN PARALLEL THROUGH A PLURALITY OF DILUTION COMPARTMENTS PARTITIONED BY A PLURALITY OF ANION EXCHANGE MEMBRANES AND CATION EXCHANGE MEMBRANES ARRANGED ALTERNATELY AND THEN RECIRCULATING TO THE ALKALI METAL CHLORIDE OR ALKALINE EARTH METAL CHLORIDE SOLUTION STORAGE TANK.
Claim 2
Independent Claim 162 words
A METHOD FOR THE TREATMENT OF CYANIDE-CONTAINING WASTES, WHICH COMPRISES PASSING A PART OF CYANIDE-CONTAINING WASTE FROM A CYANIDE-CONTAINING WASTE STORAGE TANK IN SERIES THROUGH A CATHODE COMPARTMENT COMPOSED OF A CATHODE AND CATION EXCHANGE MEMBRANE AND AN ANODE COMPARTMENT COMPOSED OF AN ANODE AND ANION EXCHANGE MEMBRANE AND THEN RECIRCULATING TO THE CYANIDE-CONTAINING WASTE STORAGE TANK, SIMULTANEOUSLY PASSING THE OTHER PART OF CYANIDE-CONTAINING WASTE IN PARALLEL THROUGH A PLURALITY OF CONCENTRATION COMPARTMENTS PARTIONED BY A PLURALITY OF ANION EXCHANGE MEMBRANES AND CATION EXCHANGE MEMBRANES ARRANGED ALTERNATELY AND THEN RECIRCULATING TO THE CYANIDE-CONTAINING WASTE STORAGE TANK, AND SIMULTANEOUSLY PASSING A SOLUTION OF AN ALKALI METAL CHLORIDE OR ALKALINE EARTH METAL CHLORIDE FROM AN ALKALI METAL CHLORIDE OR ALKALINE EARTH METAL CHLORIDE SOLUTION STORAGE TANK IN PARALLEL THROUGH A PLURALITY OF DILUTION COMPARTMENTS PARTITIONED BY A PLURALITY OF ANION EXCHANGE MEMBRANES AND CATION EXCHANGE MEMBRANES ARRANGED ALTERNATELY AND THEN RECIRCULATING TO THE ALKALI METAL CHLORIDE OR ALKALINE EARTH METAL CHLORIDE SOLUTION STORAGE TANK.
Claim 3
Independent Claim 184 words
A method for the treatment of cyanide-containing wastes, which comprises passing a part of cyanide-containing waste from a cyanidE-containing waste storage tank in series through a cathode compartment composed of a cathode and cation exchange membrane and an anode compartment composed of an anode and anion exchange membrane, said cathode compartment and anode compartment being situated in one electrodialysis cell, and then recirculating to the cyanide-containing waste storage tank, simultaneously passing the other part of cyanide-containing waste in parallel through a plurality of concentration compartments partitioned by a plurality of anion exchange membranes and cation exchange membranes arranged alternately between said cathode and anode and then recirculating to the cyanide-containing waste storage tank, and simultaneously passing a solution of an alkali metal chloride or alkaline earth metal chloride from an alkali metal chloride or alkaline earth metal chloride solution storage tank in parallel through a plurality of dilution compartments partitioned by a plurality of anion exchange membranes and cation exchange membranes arranged alternately between said cathode and anode and then recirculating to the alkali metal chloride or alkaline earth metal chloride solution storage tank.
Claim 4
Independent Claim 184 words
A method for the treatment of cyanide-containing wastes, which comprises passing a part of cyanide-containing waste from a cyanidE-containing waste storage tank in series through a cathode compartment composed of a cathode and cation exchange membrane and an anode compartment composed of an anode and anion exchange membrane, said cathode compartment and anode compartment being situated in one electrodialysis cell, and then recirculating to the cyanide-containing waste storage tank, simultaneously passing the other part of cyanide-containing waste in parallel through a plurality of concentration compartments partitioned by a plurality of anion exchange membranes and cation exchange membranes arranged alternately between said cathode and anode and then recirculating to the cyanide-containing waste storage tank, and simultaneously passing a solution of an alkali metal chloride or alkaline earth metal chloride from an alkali metal chloride or alkaline earth metal chloride solution storage tank in parallel through a plurality of dilution compartments partitioned by a plurality of anion exchange membranes and cation exchange membranes arranged alternately between said cathode and anode and then recirculating to the alkali metal chloride or alkaline earth metal chloride solution storage tank.
Claim 5
Independent Claim 212 words
A method for the treatment of cyanide-containing wastes, which comprises passing a part of cyanide-containing waste from a cyanide-containing waste storage tank in series through a cathode compartment of a first electrodialysis unit and an anode compartment of a second electrodialysis unit and then recirculating to the cyanide-containing waste storage tank, simultaneously passing the other part of cyanide-containing waste in parallel through concentration compartments of the first electrodialysis unit and then in parallel through concentration compartments of the second electrodalysis unit and then recirculating to the cyanide-containing waste storage tank, and simultaneously passing a solution of an alkali metal chloride or alkaline earth metal chloride from an alkali metal chloride or alkaline earth metal chloride solution storage tank in parallel through dilution compartments of the first electrodialysis unit and then in parallel through dilution compartments of the second electrodialysis unit and then recirculating to the alkali metal chloride or alkaline earth metal chloride solution storage tank, each of said electrodialysis units having a cathode compartment composed of a cathode and cation exchange membrane, anode compartment composed of an anode and anion exchange membrane, and dilution compartments and concentration compartments arranged alternately between the cathode compartment and anode compartment and partitioned alternately by a plurality of anion exchange membranes and cation exchange membranes.
Claim 6
Independent Claim 212 words
A method for the treatment of cyanide-containing wastes, which comprises passing a part of cyanide-containing waste from a cyanide-containing waste storage tank in series through a cathode compartment of a first electrodialysis unit and an anode compartment of a second electrodialysis unit and then recirculating to the cyanide-containing waste storage tank, simultaneously passing the other part of cyanide-containing waste in parallel through concentration compartments of the first electrodialysis unit and then in parallel through concentration compartments of the second electrodalysis unit and then recirculating to the cyanide-containing waste storage tank, and simultaneously passing a solution of an alkali metal chloride or alkaline earth metal chloride from an alkali metal chloride or alkaline earth metal chloride solution storage tank in parallel through dilution compartments of the first electrodialysis unit and then in parallel through dilution compartments of the second electrodialysis unit and then recirculating to the alkali metal chloride or alkaline earth metal chloride solution storage tank, each of said electrodialysis units having a cathode compartment composed of a cathode and cation exchange membrane, anode compartment composed of an anode and anion exchange membrane, and dilution compartments and concentration compartments arranged alternately between the cathode compartment and anode compartment and partitioned alternately by a plurality of anion exchange membranes and cation exchange membranes.
Claim 7
Dependent Claim 29 words
The method of claim 2, wherein the cyanide-containing waste treated in the former operation is reused as the solution of an alkali metal chloride or alkaline earth metal chloride.
Claim 8
Dependent Claim 29 words
The method of claim 3, wherein the cyanide-containing waste treated in the former operation is reused as the solution of an alkali metal chloride or alkaline earth metal chloride.
Claim 9
Dependent Claim 20 words
The method of claim 1, wherein said cyanide-containing waste contains at least one of K4(Fe(CN))6), K2(Ni(CN)4), K2(Cu(CN)3), NaCN and Na4(Fe(CN)6).
Claim 10
Dependent Claim 13 words
The method of claim 1, wherein said alkali metal chloride is sodium chloride.

References Cited (Backward Citations)

US2520703A Cited
US2737298A Cited
US3457152A Cited
US3682796A Cited
US3645867A Cited
US3719570A Cited
US3756932A Cited
US3764497A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-11-11 1978-05-13 1978-11-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-11-11 1982-05-13 1982-11-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-11-11 1986-05-13 1986-11-12 $7700.00 Window Closed / Lapsed

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