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US3844838A Expired / Lapsed US ⏱️ 0.0 years remaining

Alkaline cells with anodes made from zinc fibers and needles

Assignee: Edgewell Personal Care Brands LLC
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Filing: 1972-03-13
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Granted: 1974-10-29
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Expires: 1992-03-13
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Abstract

Abstract Stable, high surface area, virtually pure zinc filaments and in particular zinc fibers and needles having a unique crystal structure consisting essentially of one or more single crystals preferentially orientated with an a axis parallel to the axis of the filament. The zinc fibers and needles are prepared by the electrolysis of a soluble zinc salt-containing electrolyte solution under conditions of extremely high cathode current density. Galvanic cell anodes are fabricated using the zinc fibers or needles by compression molding techniques.

Inventors

  • 👤 D Louzos

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 21:24
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M10/00; H01M10/24; H01M10/26; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 102 words
AN ALKALINE GALVANIC CELL HAVING AN ANODE, A CATHODE AND AN ALKALINE ELECTROLYTE IN CONTACT THEREWITH, SAID ANODE COMPRISING A POROUS, ELECTROLYTE ABSORBENT, COHESIVE, SELFSUPPORTING BODY OF INTERMINING AND INTERLOCKED ZINC FILAMENTS CHARACTERIZED BY HAVING A THIN ELONGATED CEBTRAL SPINE PORTION WITH AT LEAST A FEW POLYDIRECTIONAL SIDE GROWTHS OF GRANULAR DENDRITIC OR PLATELET FORM, THE THIN ELONGATED CENTRAL SPINE PORTION CONSISTING ESSENTIALLY OF ONE OR MORE SINGLE CRYSTALS PERFERNIALLY ORIENTED WITH AN A AXIS PARALLEL TO THE AXIS OF THE FILAMENT, SAID FILAMENTS HAVING A LENGTH OF FROM ABOUT 1 8 TO ABOUT 4 INCHES, AN AVERAGE DIAMETER OF ABOUT 0.006
Claim 2
Dependent Claim 102 words
AN ALKALINE GALVANIC CELL HAVING AN ANODE, A CATHODE AND AN ALKALINE ELECTROLYTE IN CONTACT THEREWITH, SAID ANODE COMPRISING A POROUS, ELECTROLYTE ABSORBENT, COHESIVE, SELFSUPPORTING BODY OF INTERMINING AND INTERLOCKED ZINC FILAMENTS CHARACTERIZED BY HAVING A THIN ELONGATED CEBTRAL SPINE PORTION WITH AT LEAST A FEW POLYDIRECTIONAL SIDE GROWTHS OF GRANULAR DENDRITIC OR PLATELET FORM, THE THIN ELONGATED CENTRAL SPINE PORTION CONSISTING ESSENTIALLY OF ONE OR MORE SINGLE CRYSTALS PERFERNIALLY ORIENTED WITH AN A AXIS PARALLEL TO THE AXIS OF THE FILAMENT, SAID FILAMENTS HAVING A LENGTH OF FROM ABOUT 1 8 TO ABOUT 4 INCHES, AN AVERAGE DIAMETER OF ABOUT 0.006
Claim 3
Dependent Claim 41 words
The alkaline galvanic cell in accordance with claim 1 wherein the filaments are zinc fibers having a thin elongated central spine portion with a number of poly-directional side growths and having a length of from about 1/8 to about 2 inches.
Claim 4
Dependent Claim 42 words
The alkaline galvanic cell in accordance with claim 1 wherein the filaments are zinc needles having a thin smooth elongated central spine portion with only a few poly-directional side growths and having a length of from about 1/8 to about 4 inches.
Claim 5
Dependent Claim 22 words
The alkaline galvanic cell in accordance with claim 1 wherein the filaments contain less thAn about 1.5 parts per million of iron.
Claim 6
Dependent Claim 25 words
The alkaline galvanic cell in accordance with claim 1 wherein the filaments are amalgamated with at least about 3 per cent by weight of mercury.
Claim 7
Dependent Claim 29 words
The alkaline galvanic cell in accordance with claim 1 wherein the cathode is an oxidic compound selected from the group consisting of manganese dioxide, nickel oxide and silver oxide.
Claim 8
Dependent Claim 20 words
The alkaline galvanic cell in accordance with claim 1 wherein the alkaline electrolyte is a concentrated solution of potassium hydroxide.
Claim 9
Dependent Claim 35 words
The alkaline galvanic cell in accordance with claim 1 wherein the alkaline electrolyte comprises an aqueous solution of from about 40 to 45 per cent potassium hydroxide and 12.5 to 15 per cent zinc oxide.
Claim 10
Dependent Claim 35 words
The alkaline galvanic cell in accordance with claim 1 wherein the alkaline electrolyte contains at least about 20 parts per million of an additive selected from the group consisting of plumbites, arsenates, molybdates and tungstates.

References Cited (Backward Citations)

US2655472A Cited
US2820077A Cited
US3071638A Cited
US3291707A Cited
US3226260A Cited
US3326783A Cited
US3672996A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-10-28 1978-04-29 1978-10-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-10-28 1982-04-29 1982-10-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-10-28 1986-04-29 1986-10-29 $7700.00 Window Closed / Lapsed

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