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US3842909A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of polymer flooding

Assignee: Marathon Oil Co
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Filing: 1972-11-27
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Granted: 1974-10-22
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Expires: 1992-11-27
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Abstract

Abstract Improved production of formation fluids from a subterranean, oil-bearing reservoir of low permeability using a polymer of a specified average molecular weight and wherein at least 5% by weight of the polymer has an average molecular weight at least 1.2 times greater than the specified average molecular weight is obtained by mechanically or physically degrading the at least 5 percent portion of the polymer solution. This substantially decreases the tendency of the polymer solution to ''''plug'''' the formation, while only slightly decreasing its viscosity.

Inventors

  • 👤 J Rhudy
  • 👤 G Haws

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 22:15
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/588; E; E21; E21B; E21B43/00; E21B43/16

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 208 words
IN A PROCESS FOR RECOVERING CRUDE OIL FROM A SUBTERRANEAN OIL-BEARING RESERVOUR HAVING AT LEAST ONE INJECTION MEANS IN FLUID COMMUNICATION WITH AT LEAST ONE PRODUCTION MEANS AND WHEREIN AN AQUEOUS SOLUTION OF A HIGH MOLECULAR WEIGHT COPOLYMER OF AN ETHYLENICALLY UNSATURATED CARBOXYLIC ACID OR SALT THEREOF AND AN ETHYLENICALLY UNSATURATED NON-CARBOXYLIC COMPOUND IS INJECTED INTO THE FORMATION TO DISPLACE CRUDE OIL TOWARD THE AT LEAST ONE PRODUCTION MEANS AND WHEREIN THE COPOLYMER HAS A PREDETERMINED AVERAGE MOLECULAR WEIGHT WITH AT LEAST 5 PERCENT BY WEIGHT OF THE COPOLYMER HAVING AN AVERAGE MOLECULAR WEIGHT AT LEAST ABOUT 1.2 TIMES GREATER THAN THE AVERAGE MOLECULAR WEIGHT AT LEAST ABOUT 1.2 TIMES GREATER THA THE AQUEOUS SOLUTION AND WHEREIN THE AT LEAST 5 PERCENT PORTION CONRIBUTES SIGNIFICANTLY TO REDUCING THE PERMEABLILITY OF THE SUBTERTANEAN OIL-BEARING FORMATION, THE IMPROVEMENT COMPRISING SUBJECTING THE COPOLYMER SOLUTION TO SUFFICIENT SHEAR FORCE TO SUBSTANTIALLY SHEAR ALL OF THE LEAST 5 PERCENT PORTION OF THE COPOLYMER, THEREBY REDUCING THE AVERAGE MOLECULAR WEIGHT OF THE AT LEAST 5 PERCENT PORTION OF THE COPOLYMER AND THEREAFTER INJECTING THE COPOLYMER, INTO THE RESERVOIR AND DISPLACING IT TOWARD THE PRODUCTION MEANS, THE OVERALL EFFECT BEING TO INHIBIT THE TENDENCY OF THE COPOLYMER TO SUBSTANTIALLY REDUCE THE PERMEABILITY OF THE RESERVOIR.
Claim 2
Dependent Claim 208 words
IN A PROCESS FOR RECOVERING CRUDE OIL FROM A SUBTERRANEAN OIL-BEARING RESERVOUR HAVING AT LEAST ONE INJECTION MEANS IN FLUID COMMUNICATION WITH AT LEAST ONE PRODUCTION MEANS AND WHEREIN AN AQUEOUS SOLUTION OF A HIGH MOLECULAR WEIGHT COPOLYMER OF AN ETHYLENICALLY UNSATURATED CARBOXYLIC ACID OR SALT THEREOF AND AN ETHYLENICALLY UNSATURATED NON-CARBOXYLIC COMPOUND IS INJECTED INTO THE FORMATION TO DISPLACE CRUDE OIL TOWARD THE AT LEAST ONE PRODUCTION MEANS AND WHEREIN THE COPOLYMER HAS A PREDETERMINED AVERAGE MOLECULAR WEIGHT WITH AT LEAST 5 PERCENT BY WEIGHT OF THE COPOLYMER HAVING AN AVERAGE MOLECULAR WEIGHT AT LEAST ABOUT 1.2 TIMES GREATER THAN THE AVERAGE MOLECULAR WEIGHT AT LEAST ABOUT 1.2 TIMES GREATER THA THE AQUEOUS SOLUTION AND WHEREIN THE AT LEAST 5 PERCENT PORTION CONRIBUTES SIGNIFICANTLY TO REDUCING THE PERMEABLILITY OF THE SUBTERTANEAN OIL-BEARING FORMATION, THE IMPROVEMENT COMPRISING SUBJECTING THE COPOLYMER SOLUTION TO SUFFICIENT SHEAR FORCE TO SUBSTANTIALLY SHEAR ALL OF THE LEAST 5 PERCENT PORTION OF THE COPOLYMER, THEREBY REDUCING THE AVERAGE MOLECULAR WEIGHT OF THE AT LEAST 5 PERCENT PORTION OF THE COPOLYMER AND THEREAFTER INJECTING THE COPOLYMER, INTO THE RESERVOIR AND DISPLACING IT TOWARD THE PRODUCTION MEANS, THE OVERALL EFFECT BEING TO INHIBIT THE TENDENCY OF THE COPOLYMER TO SUBSTANTIALLY REDUCE THE PERMEABILITY OF THE RESERVOIR.
Claim 3
Dependent Claim 22 words
The process of claim 1 wherein the high molecular weight copolymer has an average molecular weight of about 500,000 to about 50,000,000.
Claim 4
Dependent Claim 23 words
The process of claim 1 wherein the subterranean oil-bearing reservoir is characterized as having an average permeability of about 5 to 200 millidarcies.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein the high molecular weight copolymer is characterized as being viscoelastic.
Claim 6
Dependent Claim 16 words
The process of claim 1 wherein the copolymer is obtained by copolymerizing acrylamide and acrylic acid.
Claim 7
Dependent Claim 21 words
The process of claim 1 wherein the copolymer is obtained by copolymerizing acrylamide and an alkali metal salt of acrylic acid.
Claim 8
Dependent Claim 18 words
The process of claim 1 wherein the copolymer is sheared prior to its introduction into the injection means.
Claim 9
Dependent Claim 190 words
In a process for recovering crude oil from a subterrean oil-bearing reservoir having at least one injection means in fluid communication with at least one production means and wherein an aqueous solution of a high molecular weight copolymer of acrylamide and acrylic acid or sodium acrylate is injected into the formation to displace the crude oil toward the at least one production means and wherein the copolymer has a predetermined average molecular weight with at least 5 percent by weight of the copolymer having an average molecular weight at least about 1.2 times greater than the average molecular weight of the total polymer within the aqueous solution and wherein the at least 5 percent portion contributes significantly to reducing the permeability of the subterranean oil-bearing reservoir, the improvement comprising subjecting the copolymer solution to sufficient shear force to substantially reduce the screen factor of the copolymer while only slightly reducing the average molecular weight of the copolymer, and thereafter injecting the copolymer into the reservoir and displacing it toward the production means, the overall effect being to reduce the tendency of the copolymer to reduce the permeability of the reservoir.
Claim 10
Dependent Claim 190 words
In a process for recovering crude oil from a subterrean oil-bearing reservoir having at least one injection means in fluid communication with at least one production means and wherein an aqueous solution of a high molecular weight copolymer of acrylamide and acrylic acid or sodium acrylate is injected into the formation to displace the crude oil toward the at least one production means and wherein the copolymer has a predetermined average molecular weight with at least 5 percent by weight of the copolymer having an average molecular weight at least about 1.2 times greater than the average molecular weight of the total polymer within the aqueous solution and wherein the at least 5 percent portion contributes significantly to reducing the permeability of the subterranean oil-bearing reservoir, the improvement comprising subjecting the copolymer solution to sufficient shear force to substantially reduce the screen factor of the copolymer while only slightly reducing the average molecular weight of the copolymer, and thereafter injecting the copolymer into the reservoir and displacing it toward the production means, the overall effect being to reduce the tendency of the copolymer to reduce the permeability of the reservoir.
Claim 11
Dependent Claim 22 words
The process of claim 8 wherein the high molecular weight copolymer has an average molecular weight of about 500,000 to about 50,000,000.
Claim 12
Dependent Claim 24 words
The process of claim 8 wherein the subterranean oil-bearing reservoir is characterized as having an average permeability of about 5 to about 200 millidarcies.
Claim 13
Dependent Claim 16 words
The process of claim 8 wherein the high molecular weight copolymer is characterized as being viscoelastic.
Claim 14
Dependent Claim 16 words
The process of claim 8 wherein the copolymer is obtained by copolymerizing acrylic acid and acrylamide.
Claim 15
Dependent Claim 18 words
The process of claim 8 wherein the copolymer is sheared prior to its introduction into the injection means.
Claim 16
Dependent Claim 16 words
The process of claim 8 wherein the copolymer is obtained by copolymerizing acrylamide and sodium acrylate.
Claim 17
Dependent Claim 25 words
The process of claim 8 wherein the acrylic acid or sodium acrylate content of the copolymer is about 15 to about 40 percent by mole.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-10-21 1978-04-22 1978-10-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-10-21 1982-04-22 1982-10-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-10-21 1986-04-22 1986-10-22 $7700.00 Window Closed / Lapsed

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