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Amorphous polyamide from bis(4-aminocyclohexyl)methane, bis(carboxyphenyl)methane and alkylene dicarboxylic acid

Assignee: Phillips Petroleum Co
•
Filing: 1972-11-27
•
Granted: 1974-10-01
•
Expires: 1992-11-27
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Abstract

Abstract Substantially amorphous, optically clear polyamides are produced from a bis(4-aminocyclohexyl)methane or methyl derivative thereof and a bis(carboxyphenyl)methane or methyl derivative thereof. Copolyamides having desirable processing properties are produced by polymerizing the above monomers and at least one straight chain dicarboxylic acid as an additional monomer. The resulting polymers are useful as fibers as well as molding resins.

Inventors

  • 👤 R Campbell
  • 👤 P Stapp
  • 👤 H Holtz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 19:43
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 29 words
A FIBER-FORMING, SUBSTANTIALLY AMORPHOUS, OPTICALLY CLEAR SOLID POLYAMIDE CONSISTING ESSENTIALLY OF THE POLYMERIC REACTION PRODUCT OF A. AT LEAST ONE BIS(4-AMINOCYCLOHEXYL)METHANE OR A METHYL DERIVATIVE THEREOF OF THE FORMULA
Claim 2
Dependent Claim 29 words
A FIBER-FORMING, SUBSTANTIALLY AMORPHOUS, OPTICALLY CLEAR SOLID POLYAMIDE CONSISTING ESSENTIALLY OF THE POLYMERIC REACTION PRODUCT OF A. AT LEAST ONE BIS(4-AMINOCYCLOHEXYL)METHANE OR A METHYL DERIVATIVE THEREOF OF THE FORMULA
Claim 3
Dependent Claim 29 words
A copolyamide according to claim 1 wherein (a) is bis(4-aminocyclohexyl)methane, (b) is 2,2-bis(p-carboxyphenyl)propane, and (c) is suberic acid, and said product has a glass transition temperature of about 175*C.
Claim 4
Dependent Claim 32 words
The copolyamide of claim 1 wherein (a) is bis(4-aminocyclohexyl)methane, (b) is 2,2-bis(p-carboxyphenyl)propane and (c) is suberic acid, and (c) constitutes about 75 mole percent of the total amount of (b) and (c).
Claim 5
Dependent Claim 23 words
The composition of claim 1 in which at least 40 mole percent of reactant (a) is in the form of a trans,trans isomer.

References Cited (Backward Citations)

US2516585A Cited
US2696482A Cited
US2836579A Cited
US3475387A Cited
US3393210A Cited
US3416302A Cited
US3597400A Cited
US3481133A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-09-30 1978-04-01 1978-10-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-09-30 1982-04-01 1982-10-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-09-30 1986-04-01 1986-10-01 $7700.00 Window Closed / Lapsed

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