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US3818993A Expired / Lapsed US ⏱️ 0.0 years remaining

Lpg micellar solutions as fracturing fluids

Assignee: Marathon Oil Co
•
Filing: 1972-01-03
•
Granted: 1974-06-25
•
Expires: 1992-01-03
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Abstract

Abstract A fracturing fluid successfully useful for stimulating gas producing wells is obtained by mixing 60-95 percent by volume of a hydrocarbon containing an average of C-3 to about C-10 carbon atoms, up to 20 percent by volume of water, 2.5 to about 25 percent of a surfactant obtained by condensing about 1 mole of an alcohol containing about 4 to about 20 carbon atoms with about 1 to about 20 moles of an alkene oxide to obtain a surfactant having a HLB (hydrophil-lipophil balance) of about 3 to about 15, and optionally containing 0.1 to about 10 percent by volume of a cosurfactant which can be an alcohol containing 1 to about 10 carbon atoms and/or about 0.001 to about 5 percent by weight (based on aqueous medium) of an electrolyte. In addition, the fracturing fluid can contain propping agents, fluid loss control agents, corrosion inhibitors, diverting agents, and other additives desired for a particular fracturing process.

Inventors

  • 👤 W Gogarty
  • 👤 G Haws

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 09:31
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/62; C09K8/64; Y; Y10; Y10S; Y10S507/00; Y10S507/922

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 25 words
The process of claim 1 wherein the hydrocarbon of the fracturing fluid contains an average of about 4 to about 7 carbon atoms per molecule.
Claim 2
Dependent Claim 10 words
up to about 20 percent by volume of water, and
Claim 3
Dependent Claim 59 words
about 2.5 to about 25 percent by volume of a surfactant obtained by condensing an alcohol containing an average of about 4 to about 20 carbon atoms per molecule with about 1 to about 20 moles of an alkene oxide, and thereafter injecting the fracturing fluid into the reservoir at a sufficient rate to effect fracturing of the reservoir.
Claim 4
Dependent Claim 18 words
The process of claim 1 wherein the fracturing fluid contains less than 10 percent by volume of water.
Claim 5
Dependent Claim 38 words
The process of claim 1 wherein the fracturing fluid contains a surfactant obtained by condensing an alcohol containing an average of about 10 to about 14 carbon atoms with about 1 to about 20 moles of ethylene oxide.
Claim 6
Dependent Claim 17 words
The process of claim 1 wherein the alkene oxide contains about 2 to about 4 carbon atoms.
Claim 7
Dependent Claim 45 words
The process of claim 1 wherein the fracturing fluid contains about 0.01 to about 10 percent by volume of a cosurfactant which is selected from the group consisting of alcohols, ketones, aldehydes, esters, amines, which contain about 1 to about 10 carbon atoms per molecule.
Claim 8
Dependent Claim 24 words
The process of claim 1 wherein the water phase of the fracturing fluid contains about 0.001 to about 5 percent by weight of electrolyte.
Claim 9
Dependent Claim 25 words
The process of claim 1 wherein the fracturing fluid contains about 0.1 to about 5 lbs of a propping agent per gallon of fracturing fluid.
Claim 10
Dependent Claim 21 words
The process of claim 5 wherein the propping agent is sand having a mesh size of about 20 to about 40.
Claim 11
Dependent Claim 14 words
The process of claim 1 wherein the fracturing fluid contains a fluid loss agent.
Claim 12
Dependent Claim 23 words
The process of claim 10 wherein the fracturing fluid contains about 0.001 to about 6 lb of silica flour per gallon of fluid.
Claim 13
Dependent Claim 16 words
The process of claim 10 wherein the fracturing fluid contains an oil-soluble, high molecular weight polymer.
Claim 14
Dependent Claim 15 words
The process of claim 12 wherein the high molecular weight oil-soluble polymer is a polyisobutylene.

References Cited (Backward Citations)

US2828265A Cited
US3335794A Cited
US3500932A Cited
US3545546A Cited
US3557874A Cited
US3603400A Cited
US3747681A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-06-24 1977-12-24 1978-06-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-06-24 1981-12-24 1982-06-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-06-24 1985-12-24 1986-06-25 $7700.00 Window Closed / Lapsed

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