Patent US3817592A successfully refreshed from Google Patents.
← Back to Patent Explorer
US3817592A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for reproducibly fabricating and using stable thermal-field emission cathodes

Assignee: Linfield Research Institute
•
Filing: 1972-09-29
•
Granted: 1974-06-18
•
Expires: 1992-09-29
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Methods are disclosed for reproducibly fabricating and using <100> thermal-field built-up field emission cathodes through the selective thermal elimination of contaminants and preservation of specific surface oxides in conjunction with the application of an E-field to promote faceting of certain planes while discouraging faceting of the (100) planes. An example in which <100> oriented tungsten wire is used as a starting material is treated comprehensively.

Inventors

  • 👤 L Swanson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 23:53
CPC Classifications
H; H01; H01J; H01J37/00; H01J37/02; H01J37/04; H01J37/06; H01J37/073; H01J9/00; H01J9/02; H01J9/022; H01J9/025; H01J2237/00; H01J2237/06; H01J2237/063; H01J2237/06308; H01J2237/06316

Claims Analysis

Total Claims: 44
Claim 1
Independent Claim 28 words
The method of claim 1 in which magnitude of the field is not allowed to exceed a value at which arcing occurs between the tip and the electrode.
Claim 2
Dependent Claim 17 words
The method of claim 2 in which steps c and d are initiated in reverse sequential order.
Claim 3
Dependent Claim 16 words
The method of claim 2 in which steps c and d are carried out substantially simultaneously.
Claim 4
Dependent Claim 109 words
A process for fabricating a field electron cathode, disposed near an electrode in a partially evacuated, environmentally controllable chamber, from <100> oriented wire having an end thereof brought to a terminal radius less than approximately 3000A, said process comprising the sequentially interchangeable and overlapping steps of: a. heating the wire sufficiently to diffuse contaminants to the wire surface; and b. applying sufficient voltage between the wire and the electrode to draw a predetermined minimum total current; said process further comprising the subsequent step of: c. maintaining the total current flow between the wire and the electrode at a value less than a predetermined maximum until total current stabilization occurs.
Claim 5
Dependent Claim 20 words
The process of claim 5 in which the <100> oriented wire is selected from the group including tungsten and molybdenum.
Claim 6
Dependent Claim 58 words
The process of claim 5 in which the <100> oriented wire is tungsten and step a is carried out by heating the tungsten wire to a temperature sufficient to diffuse any bulk carbon to the wire surface such that the carbon combines with oxygen to form volatile oxides of carbon, which volatile oxides of carbon are thermally desorbed.
Claim 7
Dependent Claim 36 words
The process of claim 7 in which the temperature of the tungsten wire is always kept below a temperature at which a surface layer of tungsten oxide on the end of the wire would be removed.
Claim 8
Dependent Claim 19 words
The process of claim 7 in which the temperature of the tungsten wire is not allowed to exceed 1,900*K.
Claim 9
Dependent Claim 19 words
The process of claim 7 in which the tungsten wire is heated to a temperature of at least 1,200*K.
Claim 10
Dependent Claim 46 words
The process of claim 7 including an additional step in which supplementary oxygen is introduced into the chamber after steps a and b have been carried out whereby substantially all bulk carbon in said wire is thermally desorbed as a constituent the volatile oxides of carbon.
Claim 11
Independent Claim 225 words
A method for fabricating a stable thermal field emission cathode for long-term usage under conditions of high current density emission in a relatively relaxed vacuum environment, the method including the steps of: a. forming a generally conical tip at one end of a Miller indices <100> oriented metal wire composed of a material having a body centered cubic crystalline structure; b. heating the metal wire in a partially evacuated enclosure to a first temperature, which first temperature is sufficiently high to cause the desorption of surface contaminants, including compounds of carbon, while not exceeding a second temperature at which the generally conical tip would undergo substantial geometric deformation; c. heating the metal wire in the partially evacuated enclosure without exceeding a second temperature at which substantially all residual surface oxide of the metal would be desorbed; and d. imposing an electrical potential between the wire tip and an adjacent electrode, the imposed potential being adequate to develop a field of sufficient magnitude at the wire tip to initiate build-up of the (100) planes and to initiate faceting of at least the (110) and (211) planes; steps c and d being performed in overlapping sequence, whereby a stable thermal field emission cathode is formed having an axially disposed, generally tetrahedral, endform, the apex of said endform being characterized by a relatively small effective radius of curvature.
Claim 12
Dependent Claim 29 words
The method of claim 12 in which the magnitude of the field is not allowed to exceed a value at which arcing occurs between the tip and the electrode.
Claim 13
Dependent Claim 17 words
The method of claim 13 in which steps c and d are initiated in reverse sequential order.
Claim 14
Dependent Claim 16 words
The method of claim 13 in which steps c and d are carried out substantially simultaneously.
Claim 15
Dependent Claim 22 words
The method of claim 13 in which step c is executed after introducing a small partial pressure of oxygen into the enclosure.
Claim 16
Dependent Claim 22 words
The method of claim 13 in which step d is executed after introducing a small partial pressure of oxygen into the enclosure.
Claim 17
Independent Claim 253 words
A method for reproducibly fabricating a stable thermal field emission cathode for long-term usage under conditions of high current density emission in a relatively relaxed vacuum environment, the method including the steps of: a. forming a generally conical tip at one end of a Miller indices <100> oriented metal wire composed of a material having a body centered cubic crystalline structure; b. heating said metal wire in a partially evacuated enclosure, to a first temperature sufficiently high to cause the desorption of surface contaminants, including carbon as a volatile oxide thereof, while not exceeding a second temperature at which substantially all residual surface oxide would be desorbed from the wire tip; c. maintaining said metal wire in said partially evacuated enclosure at a third temperature, the third temperature being less than the second temperature but sufficiently high to assure surface mobility at the wire tip responsive to surface tension; and d. imposing an electrical potential between the tip of the metal wire and an adjacent electrode, said potential being of sufficient magnitude to initiate build-up of the (100) planes and to initiate faceting of at least the (110) and (211) planes, said potential being less than that potential at which geometrically destructive vacuum arcing occurs; said imposing step being sequentially interchangeable with said maintaining step; whereby a stable thermal field emission cathode is formed having an axially disposed, generally tetrahedral, endform, the apex of the endform being characterized by a relatively small effective radius of curvature and a correspondingly small effective emission area.
Claim 18
Dependent Claim 17 words
The method of claim 18 in which steps c and d are initiated in reverse sequential order.
Claim 19
Dependent Claim 24 words
The method of claim 18 wherein the metal wire is of a material selected from the group of metals consisting of tungsten and molybdenum.
Claim 20
Dependent Claim 13 words
The method of claim 18 wherein the metal wire is composed of tungsten.
Claim 21
Dependent Claim 38 words
The method of claim 21 wherein the forming step is carried out in the presence of a partial pressure of oxygen sufficient to cause the surface formation of tungsten oxide layer at the tip of the metal wire.
Claim 22
Dependent Claim 19 words
The method of claim 22 wherein the first temperature is in the range of temperatures between 1,700* and 1,900*K.
Claim 23
Dependent Claim 19 words
The method of claim 23 wherein the second temperature is in the range of temPeratures between 1,900* and 2,100*K.
Claim 24
Dependent Claim 19 words
The method of claim 24 wherein the third temperature is in the range of temperatures between 1,300* and 1,800*K.
Claim 25
Dependent Claim 26 words
The method of claim 18 wherein the pressure in the partially evacuated enclosure is in the range of pressures between 10 7 and 10 9 torr.
Claim 26
Independent Claim 284 words
A method for reproducibly fabricating a stable thermal field emission cathode for long-term usage under conditions of high current density emission in a relatively relaxed vacuum environment, the method including the steps of: a. forming a generally conical tip at one end of a Miller indices <100> oriented metal wire composed of a material having a body centered cubic crystalline strucuture; b. heating the metal wire in a partially evacuated enclosure to a first temperature, which first temperature is sufficiently high to bring about the desorption of substantially all surface contaminants, including carbon as a volatile oxide thereof, while not exceeding a second temperature at which the generally conical tip would undergo substantial geometric deformation; c. heating the metal wire in the partially evacuated enclosure to a third temperature, which third temperature is lower than a temperature at which substantially all residual surface oxide of the metal would be desorbed, said metal wire being exposed to a limited partial pressure of oxygen sufficient to assure the presence of oxides on the surface of the metal wire; and d. imposing an electrical potential between the tip of the metal wire and an adjacent electrode, the potential being adequate to develop a field of sufficient magnitude to initiate build-up of the (100) planes and to initiate faceting of at least the (110) and (112) planes, the potential being lower than a potential at which geometrically destructive vacuum arcing occurs; steps c and d being performed in overlapping sequence, whereby a stable thermal field emission cathode is formed having an axially disposed, generally tetrahedral, endform, the apex of which endform is characterized by a relatively small effective radius of curvature and a correspondingly small effective emission area.
Claim 27
Dependent Claim 17 words
The method of claim 27 in which steps c and d are initiated in reverse sequential order.
Claim 28
Dependent Claim 16 words
The method of claim 27 in which steps c and d are carried out substantially simultaneously.
Claim 29
Independent Claim 254 words
A method for reproducibly fabricating a stable thermal field emission cathode for long-term usage under conditions of high current density emission in a relatively relaxed vacuum environment, the method including the steps of: a. forming a generally conical tip at one end of a Miller indices <100> oriented metal wire composed of a material having a body centered cubic crystalline structure; b. heating the metal wire in a partially evacuated enclosure to a first temperature, which first temperature is sufficiently high to bring about the desorption of substantially all surface contaminants, including carbon as a volatile oxide thereof, while not exceeding a second temperature at which the generally conical tip would undergo substantial geometric deformation; c. maintaining the metal wire in the partially evacuated enclosure at a third temperature, which third temperature is lower than a fourth temperature at which substantially all residual surface oxide would be desorbed; d. forming oxides of the metal comprising the wire on the tip surface thereof; and e. imposing an electrical potential between the tip of the metallic wire and an adjacent electrode, the potential being adequate to develop a field of sufficient magnitude to initiate build-up of the (100) planes and to initiate faceting of at least the (110) and (112) planes, said potential being lower than a potential at which geometrically destructive Vacuum arcing occurs; whereby a stable thermal field emission cathode is formed having an axially disposed, generally tetrahedral, endform, the apex of which endform is characterized by a relatively small effective radius of curvature.
Claim 30
Dependent Claim 17 words
The method of claim 30 in which steps c and e are initiated in reverse sequential order.
Claim 31
Dependent Claim 15 words
The method of claim 30 in which steps c and e are carried out concurrently.
Claim 32
Independent Claim 207 words
A method for reproducibly fabricating a stable thermal field emission cathode for long-term usage under conditions of high current density emission in a relatively relaxed vacuum environment, the method including the steps of: a. forming a conical tip with a generally hemispherical endform at one end of a Miller indices <100> oriented tungsten wire having a diameter in the range of values between 0.005 and 0.010 inches; b. heating the tungsten wire in a partially evacuated enclosure to a first temperature falling in the range of temperatures between 1,400* and 1,900*K, the enclosure having an internal pressure in the range of pressures between 10 7 and 10 9 torr; c. maintaining the tungsten wire in the enclosure at a second temperature falling in the range of temperatures between 1, 200* and 1,900*K; and d. imposing an electrical potential between the tungsten wire and an adjacent electrode, the potential being of sufficient magnitude to cause an initial electrical current flow between the tungsten wire and the electrode in the range of currents between 10 and 20 microamperes; whereby a stable thermal field emission cathode is formed having an axially disposed, generally tetrahedral, endform, the apex of which endform is characterized by a relatively small effective radius of curvature.
Claim 33
Dependent Claim 17 words
The method of claim 33 in which steps c and d are initiated in reverse sequential order.
Claim 34
Dependent Claim 16 words
The method of claim 33 in which steps c and d are carried out substantially simultaneously.
Claim 35
Independent Claim 260 words
A method for reproducibly fabricating a stable thermal field emission cathode for long-term usage under conditions of high current density emission in a relatively relaxed vacuum environment, the method including the steps of: a. forming a conical tip with a generally hemispherical endform at one end of a Miller indices <100> oriented tungsten wire having a diameter in the range of values between 0.005 and 0.010 inches; b. heating the tungsten wire in a partially evacuated enclosure to a first temperature in the range of temperatures between 1, 400*K and 1,900*K, the enclosure having an internal pressure in the range of pressures between 10 7 and 10 9 torr; c. maintaining the tungsten wire in the enclosure at a second temperature falling in the range of temperatures between 1, 200*K and 1,900*K; d. imposing an electrical potential between the tungsten wire and an adjacent electrode, the potential being of sufficient magnitude to cause initial electrical current flow between the tungsten wire and the electrode in the range of currents between 5 and 25 microamperes; e. detecting substantially increased current flow between the tungsten wire and the electrode, the increased current flow being an indicia of (100) plane build-up and the associated facetings of at least the (110) and (112) planes; and f. adjusting the imposed potential to achieve a predetermined current flow rate between the wire and the electrode; whereby a stable thermal field emission cathode is formed having an axially disposed, generally tetrahedral, endform, the apex of which endform is characterized by a relatively small effective radius of curvature.
Claim 36
Dependent Claim 17 words
The method of claim 36 in which steps c and d are initiateD in reverse sequential order.
Claim 37
Dependent Claim 16 words
The method of claim 36 in which steps c and d are carried out substantially simultaneously.
Claim 38
Independent Claim 127 words
A method for refabricating during operation a thermal field emission cathode fabricated from <100> oriented starting material, said method including the sequentially interchangeable and overlapping steps of: a. heating the cathode in a partially evacuated enclosure to at least a first temperature, said first temperature being sufficiently high to assure surface mobility at the emission tip of said cathode, while not exceeding a second temperature at which substantially all residual surface oxide would be desorbed; and b. imposing an electrical potential between the cathode and an adjacent electrode, said potential being of sufficient magnitude to initiate build-up of the (100) planes and to initiate faceting of at least the (110) and (112) planes, the potential being lower than a potential at which geometrically destructive vacuum arcing occurs.
Claim 39
Dependent Claim 19 words
The method of claim 39 wherein said first temperature is within the range of temperatures between 1,500* and 1,800*K.
Claim 40
Dependent Claim 15 words
The method of claim 39 wherein said steps a and b are performed substantially simultaneously.
Claim 41
Dependent Claim 26 words
The method of claim 39 wherein said first temperature is sufficiently high to cause the disorption of surface contaminants including carbon as a volatile oxide thereof.
Claim 42
Dependent Claim 136 words
A method for refabrication during operation of a thermal field emission cathode of the type fabricated by the method set forth in claim 27, said refabrication method including the additional sequentially interchangeable and overlapping steps of: a. heating the cathode in a partially evacuated enclosure to at least a first temperature, said first temperature being sufficiently high to assure surface mobility at the emission tip of said cathode, while not exceeding a second temperature at which substantially all residual surface oxide would be desorbed; and b. imposing an electrical potential between the cathode and an adjacent electrode, said potential being of sufficient magnitude to initiate build-up of the (100) planes and to initiate faceting of at least the (110) and (112) planes, the potential being lower than a potential at which geometrically destructive vacuum arcing occurs.
Claim 43
Dependent Claim 12 words
A thermal field emission cathode fabricated by the method of claim 43.
Claim 44
Dependent Claim 12 words
A thermal field emission cathode fabricated by the method of claim 1.

References Cited (Backward Citations)

US3374386A Cited
US3356887A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-06-17 1977-12-17 1978-06-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-06-17 1981-12-17 1982-06-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-06-17 1985-12-17 1986-06-18 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag