← Back to Patent Explorer
US3813762A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of producing schottky contacts

Assignee: Siemens AG
•
Filing: 1971-11-24
•
Granted: 1974-06-04
•
Expires: 1991-11-24
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Method of producing metal-semiconductor contacts (Schottky contacts) with precisely defined and relatively small surface areas comprising: applying a layer of an insulating material (aluminum oxide or silicon dioxide) onto a semiconductor surface; etching only areas of the insulating material layer corresponding to the desired contact; coating a layer of chromium onto the exposed semiconductor surface areas and on the non-etched insulating material areas and etching only the areas comprised of a top layer of chromium and a bottom layer of insulating material to produce discrete areas of chromium directly on the semiconductor surface. In one embodiment, the so-formed semiconductor having discrete areas of chromium thereon is further treated by coating another layer of an insulating material over the chromium areas and the semiconductor surface areas, etching only the areas of the insulating material layer generally corresponding to the chromium layer areas and applying a layer of aluminum onto the exposed chromium areas for attachment of feed-line or the like directly onto said aluminum layer.

Inventors

  • 👤 H Kniepkamp

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 22:46
CPC Classifications
H; H10; H10P; H10P95/00; H10W; H10W20/00; H10W20/40

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 14 words
A method as defined in claim 1 wherein the insulating material is aluminum oxide.
Claim 2
Dependent Claim 24 words
A method as defined in claim 2 wherein the aluminum oxide layer is etched at steps (2) and (4) with a buffered hydrofluoric acid.
Claim 3
Dependent Claim 19 words
A method as defined in claim 3 wherein the buffered hydrofluoric acid includes ammonium fluoride as a buffering agent.
Claim 4
Dependent Claim 43 words
A method as defined in claim 4 wherein the buffered hydrofluoric acid is comprised of a mixture having an approximate weight ratio of about one part of 48 percent hydrofluoric acid, about five parts of ammonium fluoride and about seven parts of water.
Claim 5
Dependent Claim 30 words
A method as defined in claim 2 wherein the aluminum oxide layer is etched at steps (2) and (4) with phosphoric acid having a concentration of at least 30 percent.
Claim 6
Dependent Claim 18 words
A method as defined in claim 6 wherein the phosphoric acid has a concentration of about 85 percent.
Claim 7
Dependent Claim 14 words
A method as defined in claim 1 wherein the insulating material is silicon dioxide.
Claim 8
Dependent Claim 33 words
A method as defined in claim 8 wherein the silicon dioxide layer is etched at steps (2) and (4) with an etch-solution comprised of a mixture of hydrofluoric acid, ammonium fluoride and water.
Claim 9
Dependent Claim 102 words
A method as defined in claim 1 wherein the formed semiconductor surface having discrete areas of chromium thereon after step (4) is further treated by steps; (5) substantially uniformly coating a layer of a photo-lithographically etchable-insulating material selected from the group consisting of aluminum oxide and silicon dioxide on The exposed semiconductor surfaces areas and the discrete chromium areas; (6) etching areas of the insulating material layer that generally correspond to the discrete chromium areas to expose at least parts of said chromium areas; and (7) coating a layer of aluminum at least onto the exposed parts of the discrete chromium areas.
Claim 10
Dependent Claim 30 words
A method as defined in claim 10 wherein the insulating material in steps (1) and (5) is silicon dioxide applied in a layer thickness of about 100 to 500 nm.
Claim 11
Dependent Claim 20 words
A method as defined in claim 10 wherein the aluminum layer has a thickness of about 50 to 150 nm.
Claim 12
Dependent Claim 30 words
A method as defined in claim 1 wherein the insulating material is applied by sputtering said material onto the semiconductor surface and then tempering the resulting layer of said material.
Claim 13
Dependent Claim 15 words
A method as defined in claim 1 wherein the chromium layer is applied by evaporation.
Claim 14
Dependent Claim 34 words
A method as defined in claim 1 wherein the insulating material layer has a thickness of about 100 to 500 nm and the chromium layer has a thickness of about 20 to 100 nm.
Claim 15
Dependent Claim 39 words
A method as defined in claim 1 wherein the chromium layer has a thickness of about 50 nm and the insulating material layer has a thickness that is at least a multiple of three of said chromium layer thickness.
Claim 16
Independent Claim 201 words
A method of producing metal-semiconductor contacts with precisely defined relatively small surface areas that include chromium on a semiconductor member, comprising the sequential steps of; (1) applying a layer of an insulating material selected from the group of aluminum oxide and silicon dioxide onto a semiconductor surface in a thickness of about 100 to 500 nm; (2) applying a layer of a photo-sensitive resist material onto the insulating material layer, selectively exposing areas of said resist material layer to light so that unexposed areas thereof correspond to desired contact areas, and removing the unexposed areas to expose corresponding insulating material areas; (3) etching the exposed insulating material areas with an etch-solution for said insulating material until corresponding areas of the semiconductor surface are exposed, and removing the exposed areas of the resist material layer to uncover corresponding insulating material areas; (4) evaporating a layer of chromium onto the exposed semiconductor surfaces and onto uncovered insulating material layer areas in a thickness of about 20 to 100 nm; and (5) removing the remained areas of insulating material with an etch-solution for said insulating material until corresponding areas of semiconductor surface are exposed and discrete areas of chromium remain on said semiconductor surface.
Claim 17
Dependent Claim 34 words
A method as defined in claim 17 including (6) dividing the formed semiconductor sample having chromium-semiconductor contacts thereon into component elements, each comprised of a semiconductor sample having at least one chromium-semiconductor contact thereon.
Claim 18
Independent Claim 307 words
A method of producing metal-semiconductor contacts with precisely defined relatively small surface areas that include chromium on a semiconductor substrate; comprise the sequential steps of; (1) applying a layer of silicon dioxide onto a semiconductor surface in a thickness of about 100 to 500 nm; (2) applying a layer of a photo-sensitive resist material onto the silicon dioxide layer, selectively exposing areas of said resist material layer to light so that unexposed areas thereof correspond to desired contact areas and removing the unexposed areas to expose corresponding silicon dioxide areas; (3) etching the exposed silicon dioxide layer areas with an etch-solution comprised of a mixture of hydrofluoric acid, ammonium fluoride and water until corresponding areas of the semiconductor surface are exposed and removing the exposed areas of the resist material layer to uncover corresponding silicon dioxide layer areas; (4) evaporatIng a layer of chromium onto the exposed semiconductor surface areas and onto uncovered silicon dioxide layer areas in a thickness of about 20 to 100 nm; (5) removing the areas of insulating material with said etch-solution until corresponding areas of semiconductor surface are exposed and discrete areas of chromium remain on said semiconductor surface; (6) applying a coating of silicon dioxide over the exposed semiconductor surface areas and the discrete chromium areas; (7) applying a layer of a photo-sensitive resist material onto said silicon dioxide layer, selectively exposing areas of said resist material layer to light so that unexposed areas thereof generally correspond to the discrete chromium areas, and removing said unexposed areas to expose corresponding areas of the silicon dioxide layer; (8) etching the exposed silicon dioxide layer areas with said etch-solution to expose at least portions of the discrete chromium areas; and (9) evaporating a layer of aluminum onto at least said exposed chromium area portions in a thickness of about 50 to 100 nm.
Claim 19
Dependent Claim 18 words
A method as defined in claim 19 wherein a connection element is attached directly to the aluminum layer.

References Cited (Backward Citations)

US3012920A Cited
US3642528A Cited
US3599323A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-06-03 1977-12-03 1978-06-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-06-03 1981-12-03 1982-06-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-06-03 1985-12-03 1986-06-04 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag