US3798081A
Expired / Lapsed
US
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Method for diffusing as into silicon from a solid phase
Assignee: International Business Machines Corp
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Filing: 1972-02-14
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Granted: 1974-03-19
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Expires: 1992-02-14
Abstract
Abstract A process for diffusing As into a silicon substrate forming diffused regions having a surface impurity concentration in excess of 1019 atoms/cc by forming a composite layer of an upper As doped glassy layer and an underlying SiO2 layer at the interface of the substrate and glassy layer, and heating the substrate and layers in an inert atmosphere to diffuse the As from the solid phase glassy layer through the SiO2 layer and into the substrate to the desired depth.
Inventors
- 👤 K Beyer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 05:46
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6921; H10P14/6922; H10P14/63; H10P14/6302; H10P14/6304; H10P14/6306; H10P14/6308; H10P14/6309; H10P14/6322; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/6342; H10P14/65; H10P14/6516; H10P14/6529; H10P14/66; H10P14/668; H10P14/6681; H10P14/6682; H10P14/6684; H10P14/6686; H10P14/6928; H10P14/6929; H10P32/00; H10P32/10; H10P32/14; H10P32/1408; H10P32/141; H10P32/17; H10P32/171; Y; Y10; Y10S; Y10S148/00; Y10S148/04; Y10S148/041; Y10S148/043; Y10S148/118; Y10S438/00; Y10S438/914; Y10S438/92; Y10S438/923
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
20 words
The method of claim 1 wherein said glass layer has a thickness in the range of 1000 to 5000 A.
Claim 2
Dependent Claim
20 words
The method of claim 1 wherein said thin SiO2 has a thickness in the range of 200 to 300 A.
Claim 3
Dependent Claim
24 words
The method of claim 1 wherein said oxidizing atmosphere is a gas selected from the group consisting of oxygen, air, steam, and mixtures thereof.
Claim 4
Dependent Claim
23 words
The method of claim 4 wherein the substrate is heated in oxidizing atmosphere to a temperature in the range of 1,000* to 1200*C.
Claim 5
Dependent Claim
28 words
The method of claim 5 wherein the time of heating in the oxidizing atmosphere is of the order of 15 min. per 200 A of the glass layer.
Claim 6
Dependent Claim
26 words
The method of claim 5 wherein the substrate is heated in an inert atmosphere for a time in the range of 20 min. to 8 hrs.
Claim 7
Dependent Claim
51 words
The method of claim 4 wherein said glass layer is a paint-on layer formed by depositing a layer from a mixture of a polysiloxane, an organic arsenic compound, and a solvent, and heating the deposited layer at a temperature and for a time sufficient to decompose to an arseno silicate glass.
Claim 8
Dependent Claim
22 words
The method of claim 8 wherein said arseno silicate glass layer has a thickness in the range of 2,000 to 3,000 A.
Claim 9
Dependent Claim
27 words
The method of claim 9 wherein the arseno silicate glass layer is heated in an oxidizing atmosphere to a temperature in the range of 1,150* to 1,200*C.
Claim 10
Dependent Claim
28 words
The method of claim 10 wherein said arseno silicate glass layer is heated in the oxidizing atmosphere for a time in the range of 1/4 to 1/2 hrs.
Claim 11
Dependent Claim
36 words
The method of claim 11 wherein said substrate is heated in an inert atmosphere at a temperature in the range of 1,100* to 1, 200*C for a time in the range of 1 to 8 hrs.
Claim 12
Dependent Claim
22 words
The method of claim 12 wherein said inert atmosphere is selected from the group consisting of N2, Ar, He and mixtures thereof.
Claim 13
Independent Claim
92 words
A method for diffusing As into a silicon substrate forming diffused regions having surface impurity concentrations in excess of 1019 atoms/cc comprising, forming a diffusion masking layer on the substrate, forming diffusion windows in said masking layer, forming a thermal silicon oxide layer in the windows having a thickness in the range of 100-900A, forming an As doped layer over at least said diffusion windows, heating the substrate in an inert atmosphere to diffuse As from the doped layer through the silicon oxide layer and into the substrate to the desired depth.
Claim 14
Dependent Claim
30 words
The method of claim 14 wherein said As doped layer is a glass layer doped with As in a concentration in the range of 1020 to 5 X 1021 atoms/cc.
Claim 15
Dependent Claim
50 words
The method of claim 14 wherein said As doped layer is formed by depositing a layer of a mixture of a polysiloxane, an organic arsenic compound, and a solvent, and heating the deposited layer at a temperature and for a time sufficient to decompose it to an arseno silicate glass.
Claim 16
Dependent Claim
13 words
The method of claim 16 wherein said deposited layer is heated in O3.
Claim 17
Independent Claim
111 words
A method for diffusing As into a silicon substrate forming regions having surface impurity concentrations in excess of 1019 atoms/cc comprising, forming on a silicon substrate a composite layer of an upper As doped glassy layer; and an underlying silicate layer having a thickness in the range of 100-900A by separately forming each layer, heating the substrate in an inert gaseous atmosphere selected from the group consisting of N2, Ar, He and mixtures thereof at a temperature in the range of 1,000* to 1,200*C for a time sufficient to cause diffusion of As from the doped glassy layer through the silicate layer and into the silicon substrate to the desired depth.
Claim 18
Dependent Claim
15 words
The method of claim 18 wherein said silicate layer is an Al silicate glass layer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1977-03-18 | 1977-09-17 | 1978-03-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1981-03-18 | 1981-09-17 | 1982-03-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1985-03-18 | 1985-09-17 | 1986-03-19 | $7700.00 | Window Closed / Lapsed |