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US3793065A Expired / Lapsed US ⏱️ 0.0 years remaining

Size coated glass fibers

Assignee: Owens Corning
•
Filing: 1972-03-10
•
Granted: 1974-02-19
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Expires: 1992-03-10
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Abstract

Abstract A size for lubricating fibers, including glass fibers, which is a water dispersion of a solid unctuous material, as for example a solid wax, fat, or gelled or otherwise solidified oil, and a starch ester of a cyclic hydrocarbon, as for example a starch ester of an aryl compound, an aralkyl compound, an alkaryl compound, a cycloalkyl compound and a cycloalkenyl compound, or homologues thereof. The wax may be an animal, vegetable, mineral, or synthetic wax which is unctuous and insoluble in water. The oils can be gelled by adding any gelling agent, and preferably a thixotropic gelling agent to the oil. The starch esters are only partially cooked so that unburst starch granules are retained, and this dispersion is intimately mixed with the unctuous solid emulsified particles. Other ingredients such as cationic lubricants, coloring matter, bactericides, waxes having particular characteristics, etc. can be added to provide their separate functions. The combination of the above defined partially burst starch granules of esterified starch, and the emulsified particles of the solid unctuous material have very low migration from coated glass fibers, and when dried, provide low tensions when pulled over guide surfaces.

Inventors

  • 👤 A Morrison
  • 👤 H Haynes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 14:53
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/32; C03C25/321; C08; C08L; C08L3/00; C08L3/04; C08L3/06; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2964

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 19 words
The process of claim 1 wherein said ring compound is substituted by not more than approximately 20 carbon atoms.
Claim 2
Dependent Claim 13 words
The process of claim 1 wherein said ring compound contains a benzene ring.
Claim 3
Dependent Claim 15 words
The process of claim 1 wherein said starch granules are modified by benzoate ester groups.
Claim 4
Dependent Claim 15 words
The process of claim 1 wherein said granules are modified by phenyl acetate ester groups.
Claim 5
Dependent Claim 74 words
In the process of coating glass fibers with an aqueous dispersion of glass lubricants, wrapping the fibers into a coiled package, and drying the package, the improvement wherein the aqueous dispersion is caused to contain emulsified particles of an unctuous material from the group consisting of oils, fats and waxes, and An effective amount of swollen but unburst starch granules containing ester groups having the following formula to reduce migration of the unctuous material:
Claim 6
Dependent Claim 22 words
The process of claim 6 wherein said R group is a ring compound containing not more than 20 carbon atoms substituted thereon.
Claim 7
Dependent Claim 13 words
The process of claim 6 wherein said R group contains a benzene ring.
Claim 8
Dependent Claim 13 words
The process of claim 6 wherein said R group is a benzene ring.
Claim 9
Dependent Claim 14 words
The process of claim 6 wherein said ester is a phenyl acetate starch ester.
Claim 10
Dependent Claim 79 words
Glass fibers having an aqueous coating thereon consisting essentially of solubilized starch; unctuous material from the group consisting of vegetable waxes, animal waxes, mineral waxes, synthetic waxes, fats and gelled oils; and an effective amount of swollen but unburst starch granules esterified with materials from the group consisting of five and six membered ring compounds and five and six membered substituted ring compounds a major portion of which is hydrocarbon to prevent migration of the unctuous material during drying.
Claim 11
Dependent Claim 20 words
The glass fibers of claim 11 wherein said ring compound is not substituted by more than approximately 20 carbon atoms.
Claim 12
Dependent Claim 14 words
The glass fibers of claim 11 wherein said ring compound contains a phenyl group.
Claim 13
Dependent Claim 13 words
The glass fibers of claim 11 wherein said ester is a benzoylated starch.
Claim 14
Dependent Claim 14 words
The glass fibers of claim 11 wherein said ester is a phenyl acetate ester.
Claim 15
Dependent Claim 31 words
The glass fibers of claim 1 wherein the ring compound contains non hydrocarbon substitution from the group consisting of amine groups, nitrogen, nitro groups, ketone groups, aldehyde groups, and nitrite groups.
Claim 16
Dependent Claim 22 words
Glass fibers having an effective amount of swollen and unburst starch granules thereon that are modified by ester groups having the formula:
Claim 17
Dependent Claim 16 words
Glass fibers having a coating thereon consisting essentially of the following solids in percent by weight:

References Cited (Backward Citations)

US2946705A Cited
US3461090A Cited
US3462283A Cited
US3481771A Cited
US3472682A Cited
US3513156A Cited
US3615311A Cited
US3664855A Cited
US3720662A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-02-18 1977-08-20 1978-02-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-02-18 1981-08-20 1982-02-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-02-18 1985-08-20 1986-02-19 $7700.00 Window Closed / Lapsed

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