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US3779705A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for dyeing fibers or fabrics of aromatic polyamides

Assignee: Teijin Ltd
•
Filing: 1971-08-13
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Granted: 1973-12-18
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Expires: 1991-08-13
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Abstract

Abstract A process for dip dyeing aromatic polyamide fibers or fabrics with acid dyes with good dyeability and levelling properties, without modifying measures which may cause deterioration of the desirable properties of the aromatic polyamides, which comprises dip dyeing fibers or fabrics of an unmodified aromatic polyamide in a dye bath comprising an acid dye of the monosulfonic acid, monosulfonic acid-carboxylic acid, disulfonic acid, disulfonic acid-carboxylic acid, or carboxylic acid and at least 1 percent by weight (based on the weight of the solution) of a neutral or acidic inorganic salt, in the presence of a swelling agent having a phenolic hydroxyl group, and alkali metal salts thereof; and soaping the dyeing obtained.

Inventors

  • 👤 S Yamada
  • 👤 K Kitamura
  • 👤 F Takabayashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 06:35
CPC Classifications
D; D06; D06P; D06P1/00; D06P1/44; D06P1/673; D06P1/67333; D06P1/6735; D06P1/67366; D06P1/64; D06P1/642; D06P1/6422; D06P1/67375; D06P1/96; D06P3/00; D06P3/02; D06P3/04; D06P3/24; D06P3/241; D06P3/26; Y; Y10; Y10S; Y10S8/00; Y10S8/92; Y10S8/924

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 34 words
The process of claim 1, wherein said phenolic hydroxyl-containing compound or alkali metal salt thereof is selected from the group consisting of phenol, alpha-naphthol, beta-naphthol, cresol, o-phenyl phenol, p-phenyl phenol, nitrophenol, chlorophenol, and 4-methoxyphenol.
Claim 2
Dependent Claim 27 words
The process of claim 1, wherein the amount of said swelling agent is 0.5 to 50 percent based on the weight of said fibers or fabrics (o.w.f.).
Claim 3
Dependent Claim 26 words
The process of claim 1, wherein the amount of said inorganic salt is 1 to 40 percent based on the weight of the dye bath (o.w.s.).
Claim 4
Dependent Claim 24 words
The process of claim 1 wherein said neutral or acidic inorganic salt is an alkali metal salt or ammonium salt of an inorganic acid.
Claim 5
Dependent Claim 338 words
A process for dyeing fibers or fabrics of an aromatic polyamide having an aromatic ring in the recurring units with acid dyes, which comprises dip dyeing said fibers or fabrics of an unmodified aromatic polyamide in which the recurring unit of the molecular chain is expressed by a recurring unit selected from the group consisting of: i. - NH-Ar1-CO - , wherein Ar1 is phenyl, ii. - NH-Ar1-NHCO-Ar2-CO - , wherein Ar1 and Ar2 are the same or different, and represent phenyl or naphthyl, iii. - NH-R1-Ar1-CO - , wherein Ar1 is phenyl and R1 is an alkyl group of 1 - 4 carbon atoms, iv. - NH-R1-Ar1-R2-NHCO-Ar2-CO-, wherein Ar1 and Ar2 may be the same or different, and represent phenyl or naphthyl, and R1 and R2 may be the same of different and represent an alkyl group of 1 - 4 carbon atoms, and v. combinations of two or more of units (i) to (iv), in an aqueous dye bath comprising an acid dye of the monosulfonic acid, monosulfonic acid-carboxylic acid, disulfonic acid, disulfonic acid-carboxylic acid, or carboxyiic acid type expressed by the formula D--AM)p wherein D represents a dye molecule matrix, A represents -SO3-or -COO- residue, M represents hydrogen or an alkali metal, and p is an integer of 1 to 3, with the proviso that A is only -SO3- and when A contains both -SO3- and -COO-, the maximum number of -SO3M is 2, and at least 1 percent by weight, based on the weight of the dye bath, of a neutral or acidic inorganic salt in the presence of a swelling agent selected from compounds having a phenolic hydroxyl group expressed by the following formula HO-Ar3-R3 wherein Ar3 is a phenyl or naphthyl group, R3 is a member selected from the group consisting of hydrogen, lower alkyl groups, halogen, a nitro group, lower alkoxy groups, and a phenyl group, and when Ar3 is a naphthyl group, R3 is hydrogen or a lower alkyl group, and alkali metal salt thereof; and soaping the dyeing obtained.
Claim 6
Dependent Claim 24 words
The process of claim 6 wherein said neutral or acidic inorganic salt is an alkali metal salt or ammonium salt of an inorganic acid.

References Cited (Backward Citations)

US3104931A Cited
US3503698A Cited
US3591327A Cited
US3558267A Cited
US3506990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-12-17 1977-06-18 1977-12-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-12-17 1981-06-18 1981-12-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-12-17 1985-06-18 1985-12-18 $7700.00 Window Closed / Lapsed

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