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US3777254A Expired / Lapsed US ⏱️ 0.0 years remaining

Nuclear magnetic resonance spectrometer with jointly functioning external and internal resonance stabilization systems

Assignee: Individual
•
Filing: 1971-03-12
•
Granted: 1973-12-04
•
Expires: 1991-03-12
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Abstract

Abstract A nuclear magnetic resonance spectrometer comprising an electromagnet accommodated in a housing with coils disposed within the magnetic field between the poles of the electromagnet. The electrical axes of the coils are oriented perpendicularly to the pole faces of the electromagnet. The coils are connected to the output of an internal nuclear magnetic resonance stabilization system. An analytical nuclear magnetic resonance probe is disposed in the zone defined by the coils and connected to the input of the internal nuclear magnetic resonance stabilization system. A reference nuclear magnetic resonance probe is disposed within the magnetic field of the electromagnet and is located so as to be outside the zone defined by the coils. An external nuclear magnetic resonance stabilization system is connected to the reference nuclear magnetic resonance probe and nuclear magnetic resonance signals derived from the analytical nuclear magnetic resonance probe are recorded. The external and internal stabilization systems operate simultaneously.

Inventors

  • 👤 N Morkovin
  • 👤 V Pavlenko
  • 👤 J Kleiman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 10:16
CPC Classifications
G; G01; G01R; G01R33/00; G01R33/20; G01R33/28; G01R33/38; G01R33/387; G01R33/3875; G01R33/389; G01R33/44; G01R33/46

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 224 words
A nuclear magnetic resonance spectrometer with jointly functioning external and internal NMR stabilization systems comprising an electromagnet, said electromagnet having poles with pole faces, magnetically responsive correction coils disposed between said poles and having an axis perpendicularly orientated with respect to said pole faces, an internal nuclear magnetic resonance stabilization system having an output and an input, said correction coils being connected to said output of said internal stabilization system, an analytical nuclear magnetic resonance probe, said analytical probe being disposed within a zone defined by said coils and connected to said input of said internal stabilization system, a reference nuclear magnetic resonance probe, said reference probe being disposed within the magnetic field of said electromagnet, said reference probe being located outside said zone defined by said coils, an external nuclear magnetic resonance stabilization system, said external system being connected to said reference probe, a radio-frequency source, said radio-frequency source being connected to said analytical and said reference probes and producing a signal at a resonant frequency for irradiating samples of said probes, a pair of modulators, each of said modulators being connected to a respective one of said probes, means to record the signal produced by said analytical nuclear magnetic resonance probe, and further correction coils arranged on the poles of said electromagnet and connected to the output of the external stabilization system.
Claim 2
Dependent Claim 224 words
A nuclear magnetic resonance spectrometer with jointly functioning external and internal NMR stabilization systems comprising an electromagnet, said electromagnet having poles with pole faces, magnetically responsive correction coils disposed between said poles and having an axis perpendicularly orientated with respect to said pole faces, an internal nuclear magnetic resonance stabilization system having an output and an input, said correction coils being connected to said output of said internal stabilization system, an analytical nuclear magnetic resonance probe, said analytical probe being disposed within a zone defined by said coils and connected to said input of said internal stabilization system, a reference nuclear magnetic resonance probe, said reference probe being disposed within the magnetic field of said electromagnet, said reference probe being located outside said zone defined by said coils, an external nuclear magnetic resonance stabilization system, said external system being connected to said reference probe, a radio-frequency source, said radio-frequency source being connected to said analytical and said reference probes and producing a signal at a resonant frequency for irradiating samples of said probes, a pair of modulators, each of said modulators being connected to a respective one of said probes, means to record the signal produced by said analytical nuclear magnetic resonance probe, and further correction coils arranged on the poles of said electromagnet and connected to the output of the external stabilization system.
Claim 3
Dependent Claim 80 words
A nuclear magnetic resonance spectrometer as claimed in claim 1, wherein said external system includes an RF amplifier having an input and an output, an amplitude discriminator, an AF amplifier, a synchronous detector, and a d.c. amplifier, said reference probe being connected to said input of said RF amplifier, said output of said RF amplifier being connected to said further correction coils through a series connection of said amplitude discriminator, said AF amplifier, said synchronous detector and said d.c. amplifier.
Claim 4
Dependent Claim 59 words
A nuclear magnetic resonance spectrometer as claimed in claim 2, wherein said internal system comprises an RF amplifier, an amplitude discriminator, an AF amplifier, a synchronous detector and a d.c. amplifier, said analytical probe being connected to said magnetically responsive coil through a series connection of said RF amplifier, said AF amplifier, said synchronous detector and said d.c. amplifier.

References Cited (Backward Citations)

US3427532A Cited
US3388322A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-12-03 1977-06-04 1977-12-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-12-03 1981-06-04 1981-12-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-12-03 1985-06-04 1985-12-04 $7700.00 Window Closed / Lapsed

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