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US3775117A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for selective metallization of insulating material bodies

Assignee: Siemens AG
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Filing: 1971-07-13
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Granted: 1973-11-27
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Expires: 1991-07-13
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Abstract

Abstract Process for the production of fine-line circuit plates or the like having selected sharply defined metallized areas on an insulating base and the metallized plate so-produced. The process generally comprises applying a layer of a photoresist onto the insulating base and then applying a layer of a light and developer permeable, metallizing ink repellant material (i.e., a silicon oil in xylene) onto the photoresist layer. The coated base is then selectively exposed to light, rendering the exposed photoresist areas chemically changed in its solubility to a suitable developer. The exposed coated base is then contacted with the developer and the soluble photoresist areas are removed, along with the superimposed areas of repellant material supported thereby. The resultant base, having selected areas completely exposed and other areas covered with the non-exposed photoresist and repellant material, is then contacted with a metallizing ink (i.e., an aqueous solution of lithium polymolybdate) and the resultant areas of metallizing ink on the base are air dried. Next, the partially metallized base is annealed at temperatures sufficient to completely remove the remaining photoresist and repellant materials and burn-in the metal on the base.

Inventors

  • 👤 H Hoffman
  • 👤 E Rosshaupter
  • 👤 A Weitze

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 16:11
CPC Classifications
G; G03; G03C; G03C5/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 14 words
A method as defined in claim 1 wherein the photoresist is a positive-acting photoresist.
Claim 2
Dependent Claim 18 words
A method as defined in claim 1 wherein the hydrophobic material is applied by means of screen printing.
Claim 3
Dependent Claim 39 words
A method as defined in claim 1 wherein the hydrophobic material is selected from the group consisting of paraffins, waxes, oils, oil-solvent mixtures and plastics characterized by the properties of being permeable to light and to developers for photoresist.
Claim 4
Dependent Claim 17 words
A method as defined in claim 4 wherein the hydrophobic material is essentially a silicon oil-xylene mixture.
Claim 5
Dependent Claim 35 words
A method as defined in claim 1 wherein the aqueous solution includes lithium fluoride in an amount sufficient to substantially saturate said solution and includes a lithium-polymolybdate having a stoichiometric composition of 2LiO2 . 3MoO3.
Claim 6
Dependent Claim 23 words
A method as defined in claim 1 wherein the aqueous solution includes a lower aliphatic alcohol for adjusting the density of said solution.
Claim 7
Dependent Claim 17 words
A method as defined in claim 7 wherein the density of the aqueous solution is about 1.195.
Claim 8
Dependent Claim 17 words
A method as defined in claim 7 wherein the density of the aqueous solution is about 1.20.
Claim 9
Dependent Claim 50 words
A method as defined in claim 1 wherein the annealing conditions include passing a reducing atmosphere over the resultant base structure and subjecting said structure to temperatures in the range of about 1,350* to about 1,600* C. for a period of time ranging from about 5 to about 30 minutes.
Claim 10
Independent Claim 301 words
A method of select metallization of a surface of an insulating base consisting essentially of the steps of: coating a surface of said insulating base with a layer of a positive-acting photoresist; superimposing a layer of a hydrophobic material onto said layer of photoresist, said hydrophobic material comprising a silicon oil-solvent mixture; exposing select areas of the surface coated with superimposed layers of photoresist and hydrophobic material to light so that areas of said photoresist layer corresponding to select areas are exposed thereby producing an exposed coated base, said exposed areas of the photoresist layer undergoing a chemical change so as to become soluble in a suitable developer and allowing the photoresist layer to be developed by said developer; contacting said exposed coated base with a developer for said photoresist for removal of soluble areas of the photoresist layer and superimposed areas of the hydrophobic material so as to expose areas of said base corresponding to said select areas and thereby produce a partially coated base; coating said partially coated base with an aqueous solution of lithium-polymolybdate having a stoichiometric composition of 2LiO2 . 3MoO3 and an amount of lithium fluoride sufficient to substantially saturate said solution, so that a layer of said solution forms only on the exposed areas of said base; drying said solution on the exposed areas of said base; and substantially simultaneously passing a reducing atmosphere of a dry hydrogen gas having a dew point of less than -20* C. over the resultant base and subjecting said base to temperatures in the range of about 1,350* to about 1,600* C. for a period of time ranging from about 5 to 30 minutes so as to burn-in the metal from said solution onto the insulating base and completely remove the remaining photoresist and repellant materIal from said base.
Claim 11
Dependent Claim 20 words
A method as defined in claim 11 wherein the hydrophobic material is a 3 percent silicon oil in xylene mixture.

References Cited (Backward Citations)

US2139640A Cited
US3177085A Cited
US3398010A Cited
US3443988A Cited
US3640765A Cited
US3619285A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-11-26 1977-05-28 1977-11-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-11-26 1981-05-28 1981-11-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-11-26 1985-05-28 1985-11-27 $7700.00 Window Closed / Lapsed

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