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US3755329A
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Nitrogen-heterocyclylgold(i) compounds
Assignee: EIDP Inc
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Filing: 1970-12-22
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Granted: 1973-08-28
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Expires: 1990-12-22
Abstract
Abstract Disclosed herein are nitrogen-heterocyclylgold(I) compounds wherein the gold is bonded directly, or via a p-phenylene group, to carbon of the heterocyclic nucleus, and a process for their preparation comprising reacting a heterocyclyllithium compound with a trihydrocarbyl-phosphorus, -arsenic, or -antimony-gold halide. The compounds are useful for gold plating and for printing electrical circuits.
Inventors
- 👤 L Vaughan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 16:53
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/50; C07F9/5045; C07F1/00
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
11 words
A compound of claim 1, wherein Y is a single bond.
Claim 2
Dependent Claim
13 words
A compound of claim 1, wherein said substituents are trifluoromethyl or lower alkyl.
Claim 3
Dependent Claim
6 words
The compound of claim 1, 2-pyridylgold(I).
Claim 4
Dependent Claim
6 words
The compound of claim 1, 2-quinolylgold(I).
Claim 5
Dependent Claim
6 words
The compound of claim 1, 8-quinolylgold(I).
Claim 6
Dependent Claim
6 words
The compound of claim 1, 3-methyl-2-pyridylgold(I).
Claim 7
Dependent Claim
6 words
The compound of claim 1, 4-methyl-2-pyridylgold(I).
Claim 8
Dependent Claim
6 words
The compound of claim 1, 5-methyl-2-pyridylgold(I).
Claim 9
Dependent Claim
6 words
The compound of claim 1, 6-methyl-2-pyridylylgold(I).
Claim 10
Dependent Claim
6 words
The compound of claim 1, 4-t-butylpyridylgold(I).
Claim 11
Dependent Claim
6 words
The compound of claim 1, 6-methoxy-8-quinolylgold(I).
Claim 12
Dependent Claim
6 words
The compound of claim 1, 4-(2-quinolyl)phenylgold(I).
Claim 13
Dependent Claim
6 words
The compound of claim 1, 4,6-dimethyl-2-pyridylgold(I).
Claim 14
Dependent Claim
6 words
The compound of claim 1, 6-phenanthridinylgold(I).
Claim 15
Dependent Claim
6 words
The compound of claim 1, 5-trifluoromethyl-2-pyridylgold(I).
Claim 16
Dependent Claim
6 words
The compound of claim 1, 2-methyl-4-quinolylgold(I).
Claim 17
Dependent Claim
6 words
The compound of claim 1, 2,4-dimethyl-7-quinolylgold(I).
Claim 18
Dependent Claim
27 words
A compound of claim 1 wherein said aromatic compound has one substituent and wherein said substituent is either methoxy or alkyl having one to four carbon atoms.
Claim 19
Independent Claim
171 words
A method for making heterocyclylgold(I) compounds comprising reacting a compound having the formula Q - Y - Li wherein Q is a monovalent group derived by removal of a hydrogen ring carbon of a basic aromatic compound selected from the group consisting of pyridine, quinoline, benzoquinoline, isoquinoline, benzisoquinoline and phenanthroline, said aromatic compound having 0-3 substituents, said substituents being either trifluoromethyl or having 1 to 8 carbon atoms and being selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, alkaryl, alkaryloxy, aralkyl and aralkoxy and free of ethylenic and acetylenic unsaturation, provided that no heterocyclic ring in Q has more than one tertiary alkyl substituent; and Y is a link between Q and Li, and is a single bond or a ph-phenylene group with a compound of the formula (R1R2R3)Z-Au-X wherein: R1, R2, and R3 are hydrocarbyl groups having from one to 18 carbon atoms free of ethylenic and acetylenic unsaturation; Z is selected from the group consisting of phosphorous, arsenic, and antimony; and X is chlorine, bromine or iodine.
Claim 20
Dependent Claim
17 words
The method of claim 20, wherein the reaction is run at temperatures of between -80*C. to 50*C.
Claim 21
Dependent Claim
25 words
The method of claim 20, wherein the reaction is conducted in the presence of an inert organic solvent for the reactants free of Zerewitinoff-active hydrogen.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1976-08-27 | 1977-02-26 | 1977-08-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1980-08-27 | 1981-02-26 | 1981-08-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1984-08-27 | 1985-02-26 | 1985-08-28 | $7700.00 | Window Closed / Lapsed |