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US3755231A Expired / Lapsed US ⏱️ 0.0 years remaining

Rubbery compositions and applications thereof

Assignee: Shaw Pipe Industries Ltd
•
Filing: 1972-01-21
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Granted: 1973-08-28
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Expires: 1992-01-21
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Abstract

Abstract Liquid composition suitable for application to steel surfaces such as pipe interiors, which cure in situ to provide rubbery linings and coatings, comprise a terminally reactive diolefin polymer such as dibromopoly-butadiene, a curative for the polymer, a rubbery thermoplastic polymer such as a styrene butadiene block copolymer, and a solvent.

Inventors

  • 👤 J Muir
  • 👤 J Kavalir
  • 👤 P Dolezal

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 10:38
CPC Classifications
C; C08; C08L; C08L19/00; C08L19/006; C08L53/00; C08L53/02; C09; C09D; C09D123/00; C09D123/02; C09D123/04; C09D123/08; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L23/0846; C08L23/0853; C08L79/00; C08L79/02; C08L95/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 38 words
A composition as claimed in claim 1 in which the block copolymer is selected from the group consisting of styrene-butadiene copolymers and Alpha -methyl-styrenebutadiene block copolymers, and the reinforcing filler is a mixture of carbon black and silica.
Claim 2
Dependent Claim 23 words
A composition as claimed in claim 2 wherein the solvent is selected from the group consisting of toluene, benzene, cyclohexane and mixtures thereof.
Claim 3
Dependent Claim 66 words
A composition as claimed in claim 3 comprising 100 parts by weight of liquid butadiene polymer having teriminal allylic bromide groups, 150 to 300 parts by weight of styrene-butadiene block copolymer; 5 to 12 parts by weight pf polyethylene imine; 40 to 60 parts by weight of asphalt; 25 to 60 parts by weight of reinforcing filler and 200 to 300 parts by weight of solvent.
Claim 4
Dependent Claim 143 words
A process for protecting the interior surface of an iron tank or pipe, which comprises applying to said surface a liquid composition comprising: 100 parts by weight of a liquid polymer of butadiene, said polymer having terminal allylic halide groups; from about 150 to about 300 parts by weight of a block copolymer of the A(BA)n type where A is a monoalkenyl aromatic hydrocarbon polymer block and B is a conjugated diolefin polymer bLock; from about two to about 20 parts by weight of polyalkyleneimine curative; from zero to about 100 parts by weight of asphalt; from about 25 to about 60 parts by weight of reinforcing filler; and from about 100 to about 400 parts by weight of organic solvent; and curing said composition at ambient temperatures on said surface to a solid rubber of high abrasion resistance, adhering to said surface.
Claim 5
Dependent Claim 20 words
The process as claimed in claim 5 wherein the surface is an interior surface of an iron tank or pipe.
Claim 6
Dependent Claim 18 words
A process as claimed in claim 6, wherein the curing of the composition takes place at ambient temperatures.
Claim 7
Dependent Claim 28 words
A process as claimed in claim 7, wherein the liquid butadiene polymer and the curative therefor are contacted immediately prior to application of the composition to the surface.
Claim 8
Dependent Claim 24 words
A process as claimed in claim 8, wherein the liquid composition is applied to a pipe surface by spraying through a rotating spray head.
Claim 9
Dependent Claim 28 words
A process as claimed in claim 8 wherein the composition is applied to the pipe surface by casting from a casting head followed by centrifugally spinning the pipe.
Claim 10
Dependent Claim 38 words
A process as claimed in claim 8, which includes the steps of applying to the steel pipe surface a primer selected from the group consisting of organo-silanes and polyurethanes, prior to the application of the liquid composition thereto.
Claim 11
Dependent Claim 76 words
A process as claimed in claim 11, wherein the composition comprises 100 parts by weight of a liquid butadiene polymer having terminal allylic bromide groups, from 150 to 300 parts by weight of a styrene-butadiene or alphamethylstyrene-butadiene block copolymer, from 5 to 12 parts by weight of poly(ethylenimine), from 40 to 60 parts by weight of asphalt, from 25 to 60 parts by weight of filler and from 200 to 300 parts by weight of solvent.

References Cited (Backward Citations)

US2855376A Cited
US3265765A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-08-27 1977-02-26 1977-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-08-27 1981-02-26 1981-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-08-27 1985-02-26 1985-08-28 $7700.00 Window Closed / Lapsed

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