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US3753678A Expired / Lapsed US ⏱️ 0.0 years remaining

Substituted dioxanes as herbicides

Assignee: FMC Corp
•
Filing: 1972-02-09
•
Granted: 1973-08-21
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Expires: 1992-02-09
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Abstract

Abstract Herbicidal compositions containing compounds of the formula WHERE R2 is hydrogen, hydrocarbyl or substituted hydrocarbyl radical; R2a is hydrogen or methyl and R2 and R2a may together form a ring; R5 is hydrogen, alkyl, haloalkyl or cyanoalkyl; Rr is aryl, substituted aryl or heterocyclyl.

Inventors

  • 👤 Young S Tyler
  • 👤 K Hill

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 04:29
CPC Classifications
C; C07; C07D; C07D319/00; C07D319/04; C07D319/06

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 22 words
Method as in claim 1, in which Rr is a phenyl radical having at least one non-hydrogen substituent in an ortho position.
Claim 2
Dependent Claim 22 words
Method as in claim 1 in which R2 is a phenyl radical having at least one non-hydrogen substituent in a meta position.
Claim 3
Dependent Claim 10 words
Method as in claim 1 in which R2a is hydrogen.
Claim 4
Dependent Claim 15 words
Method as in claim 1 in which R2 is aromatic and has a fluoro substituent.
Claim 5
Dependent Claim 18 words
Method as in claim 2 in which said phenyl radical has a fluoro substituent in an ortho position.
Claim 6
Dependent Claim 18 words
Method as in claim 2 in which said phenyl radical has a chloro substituent in an ortho position.
Claim 7
Dependent Claim 18 words
Method as in claim 2 in which said phenyl radical has a methyl substituent in an ortho position.
Claim 8
Dependent Claim 36 words
The method as in claim 1 in which the compound is cis-5-benzyloxy-2-phenyl-1,3-dioxane; cis-5-(2-fluorobenzyloxy)-2-phenyl-1,3-dioxane; cis-5-(2-methylbenzyloxy)-2-phenyl-1,3-dioxane; cis-5-benzyloxy-2-(3-chlorophenyl)-1,3-dioxane; 5-benzyloxy-1,3-dioxane; cis-5-benzyloxy-2-(2-fluorophenyl)-1,3-dioxane; cis-5-(4-methylbenzyloxy)-2-phenyl-1,3-dioxane; cis-5-(2-bromobenzyloxy)-2-phenyl-1,3-dioxane; cis-5-(4-fluorobenzyloxy)-2-phenyl-1,3-dioxane; cis-5-(3-fluorobenzyloxy)-2-phenyl-1,3-dioxane; cis-5-(2,6-dichlorobenzyloxy)-2-phenyl-1,3-dioxane; cis-5-(2-chlorobenzyloxy)-2-phenyl-1,3-dioxane; cis-5-benzyloxy-2-(3-fluorophenyl)-1,3-dioxane; cis-5-(2-fluorobenzyloxy)-2-(3-fluorophenyl)-1,3-dioxane; cis-5-(2-fluorobenzyloxy)-2-(3-methylphenyl)-1,3-dioxane; cis-5-(2-fluorobenzyloxy)-2-(3-chlorophenyl)-1,3-dioxane; cis-5-benzyloxy-2-(3-benzyloxyphenyl)-1,3-dioxane; cis-5-benzyloxy-2-(3-methoxyphenyl)-1,3-dioxane; cis-2-(3-chlorophenyl)-5-(2-methylbenzyloxy)-1,3-dioxane; r-2-chloromethyl-c-5-(2-fluorobenzyloxy)-5-methyl-1,3-dioxane; r-2-ethyl-c-5-(2-fluorobenzyloxy)-5-methyl-1,3-dioxane; r-2-ethyl-c-5-(2-methylbenzyloxy)-5-methyl-1,3-dioxane; r-2-ethyl-5-methyl-c-5-(2-methylbenzyloxy)-1,3-dioxane; or cis-5-(2-fluorobenzyloxy)-2-(2-furyl)-1,3-dioxane.
Claim 9
Dependent Claim 41 words
Method of claim 1 in which R2a is hydrogen and in which each of the substituents R2, R5 and Rr has a molecular weight below 125 when it is aliphatic and a molecular weight below 190 when it contains a ring.
Claim 10
Dependent Claim 22 words
Method as in claim 1 in which the compound is applied as a preemergence treatment to the soil of a soybean field.
Claim 11
Dependent Claim 22 words
Method as in claim 1 in which the compound is applied as a preemergence treatment to the soil of a cotton field.

References Cited (Backward Citations)

US2937935A Cited
US3000904A Cited
US3060235A Cited
US3303221A Cited
US3322525A Cited
US3459771A Cited
US3427326A Cited
NL7013903A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-08-20 1977-02-19 1977-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-08-20 1981-02-19 1981-08-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-08-20 1985-02-19 1985-08-21 $7700.00 Window Closed / Lapsed

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