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Rare earth tellurites and method of producing same

Assignee: Kennecott Utah Copper LLC
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Filing: 1971-10-18
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Granted: 1973-03-27
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Expires: 1991-10-18
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Abstract

Abstract Tellurium compounds having the general formula (AxBy)Te4011 where A and B is a rare earth metal or yttrium, x is from 0 to 2, y is from 0 to 2, and x plus y is 2. Where A and B are the same metal the formula is M2Te4011. The compounds are prepared by reactions between Te02 and the rare earth oxides.

Inventors

  • 👤 M Redman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 06:52
CPC Classifications
C; C01; C01B; C01B19/00; C01B19/008; C09; C09C; C09C1/00; C01P; C01P2002/00; C01P2002/70; C01P2002/72; C01P2002/74; C01P2002/77; C01P2006/00; C01P2006/10; C01P2006/40; C01P2006/60; C01P2006/90

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 28 words
The composition of claim 1 wherein A and B are selected from the group of lanthanum, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, and yttrium.
Claim 2
Dependent Claim 18 words
A new composition of matter having the formula M2Te4O11 where M is a rare earth metal or yttrium.
Claim 3
Dependent Claim 23 words
The composition of claim 3 wherein M is selected from lanthanum, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, and yttrium.
Claim 4
Dependent Claim 14 words
The composition of claim 3 wherein M is a mixture of rare earth metals.
Claim 5
Independent Claim 89 words
The method of making the compound M2Te4O11, where M is selected from lanthanum, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, and yttrium by the solid-state reaction which comprises intimately mixing powders of M2O3 and TeO2 in a molar ratio of TeO2 to M2O3 of at least 4:1, compressing the admixture into a cohesive mass, heating in a non-reducing atmosphere at a temperature at least from about 700* C up to the temperature at which the compound begins to decompose, cooling to room temperature and recovering M2Te4O11.
Claim 6
Dependent Claim 14 words
The method of claim 6 wherein M is a mixture of rare earth metals.
Claim 7
Independent Claim 66 words
The method of making single crystals having the general formula M2Te4O11 where M is selected from lanthanum, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, and yttrium comprising intimately mixing M2O3 with an excess of TeO2, heating the mixture to its melting point, slowly cooling the melt at no more than 100* C per hour and separating the crystals of M2Te4O11 from the matrix.
Claim 8
Dependent Claim 19 words
The method of claim 8 wherein a seed crystal is introduced into the melt on which the crystal grows.
Claim 9
Dependent Claim 14 words
The method of claim 8 wherein M is a mixture of rare earth metals.

References Cited (Backward Citations)

US3053616A Cited
US3053618A Cited
US3053617A Cited
US3053619A Cited
US3309168A Cited
US3418246A Cited
US3309169A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-03-26 1976-09-25 1977-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-03-26 1980-09-25 1981-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-03-26 1984-09-25 1985-03-27 $7700.00 Window Closed / Lapsed

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