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Process of forming a carbide layer of vanadium, niobium or tantalum upon a steel surface

Assignee: Toyota Central R&D Labs Inc
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Filing: 1970-10-29
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Granted: 1973-03-06
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Expires: 1990-10-29
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Abstract

Abstract A process for the surface treatment of an iron or iron alloy stock comprising heating a mixture of boric acid or borate. A V-a group element of the periodic table consisting of vanadium, niobium and tantalum, or a substance containing the same, and carbon or a carbon containing substance to its fusing state in a bath vessel, and immersing the stock in the molten bath of said mixture, thereby forming a carbide layer of said element on the stock thus treated. The present invention can be performed without adding carbon to a mixture in the case when either said stock or said vessel includes carbon.

Inventors

  • 👤 N Komatsu
  • 👤 T Arai
  • 👤 M Mizutani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 12:33
CPC Classifications
C; C23; C23C; C23C12/00; C23C12/02; C23C10/00; C23C10/18; C23C10/20; C23C10/24

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 89 words
A process for the surface treatment of an iron or iron alloy stock, comprising the steps of heating a mixture consisting essentially of boric acid or a borate, at least one element of group V-a of the Periodic table consisting of vanadium, niobium and tantalum or a substance containing the same, and carbon or a carbon-containing substance to its fusing state in a bath vessel, and immersing the stock in the molten bath of said mixture, thereby forming a carbide layer of said elEment on the stock thus treated.
Claim 2
Dependent Claim 89 words
A process for the surface treatment of an iron or iron alloy stock, comprising the steps of heating a mixture consisting essentially of boric acid or a borate, at least one element of group V-a of the Periodic table consisting of vanadium, niobium and tantalum or a substance containing the same, and carbon or a carbon-containing substance to its fusing state in a bath vessel, and immersing the stock in the molten bath of said mixture, thereby forming a carbide layer of said elEment on the stock thus treated.
Claim 3
Dependent Claim 13 words
A process according to claim 1, wherein borax is used as said borate.
Claim 4
Dependent Claim 17 words
A process according to claim 1, wherein said substance containing V-a group element is a ferro-alloy thereof.
Claim 5
Dependent Claim 22 words
A process according to claim 1, wherein 1 to 70 percent by weight of V-a group element is included in said mixture.
Claim 6
Dependent Claim 20 words
A process according to claim 1, wherein at least 0.03 percent by weight of carbon is included in said mixture.
Claim 7
Dependent Claim 19 words
A process according to claim 1, wherein said heating step is performed within the range of 800*C to 1,100*C.
Claim 8
Dependent Claim 34 words
A process according to claim 1, wherein at least one member selected from the group consisting of a hydroxide or halide of sodium or potassium and a phosphorus oxide is added to said mixture.
Claim 9
Dependent Claim 24 words
A process according to claim 1, wherein 42 to 95 percent by weight of said boric acid or borate is included in said mixture.
Claim 10
Dependent Claim 25 words
A process according to claim 6, wherein said stock is immersed in said mixture for a period of time of from 1 to 30 hours.
Claim 11
Dependent Claim 89 words
A process for the surface treatment of an iron or iron alloy stock, comprising the steps of heating a mixture consisting essentially of boric acid or a borate and at least one element of Group V-a of the Periodic table consisting of vanadium, niobium and tantalum or a substance containing the same, to its fusing state in a vessel containing carbon as its main ingredient, and immersing the stock in the molten bath of said mixture, thereby forming a carbide layer of said element on the stock thus treated.
Claim 12
Dependent Claim 89 words
A process for the surface treatment of an iron or iron alloy stock, comprising the steps of heating a mixture consisting essentially of boric acid or a borate and at least one element of Group V-a of the Periodic table consisting of vanadium, niobium and tantalum or a substance containing the same, to its fusing state in a vessel containing carbon as its main ingredient, and immersing the stock in the molten bath of said mixture, thereby forming a carbide layer of said element on the stock thus treated.
Claim 13
Dependent Claim 13 words
A process according to claim 10, wherein said vessel is made of graphite.
Claim 14
Dependent Claim 88 words
A process for the surface treatment of an iron or iron alloy stock, comprising the steps of heating a mixture consisting essentially of boric acid or a borate, at least one element of Group V-a of the Periodic table consisting of vanadium, niobium and tantalum or a substance containing the same to its fusing state in the vessel, and immersing an iron or iron alloy stock containing carbon in the molten bath of said mixture, thereby forming a carbide layer of said element on the stock thus treated.
Claim 15
Dependent Claim 88 words
A process for the surface treatment of an iron or iron alloy stock, comprising the steps of heating a mixture consisting essentially of boric acid or a borate, at least one element of Group V-a of the Periodic table consisting of vanadium, niobium and tantalum or a substance containing the same to its fusing state in the vessel, and immersing an iron or iron alloy stock containing carbon in the molten bath of said mixture, thereby forming a carbide layer of said element on the stock thus treated.
Claim 16
Dependent Claim 26 words
A process according to claim 12, wherein said substance containing a group V-a element of the Periodic table is a ferro-alloy containing a group V-a element.
Claim 17
Dependent Claim 24 words
A process according to claim 12, wherein said stock is selected from the group consisting of high-carbon steel, high-carbon alloy steel and cast iron.
Claim 18
Dependent Claim 30 words
A process according to claim 12, wherein said stock is a low-carbon stock and is case-hardened prior to said immersing step to increase the carbon content on the surface thereof.
Claim 19
Dependent Claim 13 words
A process according to claim 12, wherein borax is used as said borate.
Claim 20
Dependent Claim 23 words
A process according to claim 12, wherein 1 to 70 percent by weight of said V-a group element is included in said mixture.
Claim 21
Dependent Claim 20 words
A process according to claim 12, wherein said heating step is performed within the range of 800*C to 1,100* C.
Claim 22
Dependent Claim 34 words
A process according to claim 12, wherein at least one member selected from the group consisting of a hydroxide or halide of sodium or potassium and a phosphorus oxide is added to said mixture.
Claim 23
Dependent Claim 24 words
A process according to claim 12, wherein 42 to 95 percent by weight of said boric acid or borate is included in said mixture.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-03-05 1976-09-04 1977-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-03-05 1980-09-04 1981-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-03-05 1984-09-04 1985-03-06 $7700.00 Window Closed / Lapsed

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