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Process for producing a cross-linked copolymer of tetrafluoroethylene and propylene using high energy ionizing radiation

Assignee: AGC Inc
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Filing: 1970-12-11
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Granted: 1973-02-27
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Expires: 1990-12-11
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Abstract

Abstract A cross-linked copolymer of tetrafluoroethylene and propylene is produced by irradiating a copolymer of tetrafluoroethylene and propylene in the absence of monomers of tetrafluoroethylene, propylene, or other copolymerizable monomer, with high energy ionizing radiation.

Inventors

  • 👤 Y Tabata
  • 👤 G Kojima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 16:23
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/28; C08J2327/00; C08J2327/02; C08J2327/12; C08J2327/18

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 24 words
The process of claim 1 in which said copolymer is irradiated in the absence of any monomer of tetrafluoroethylene, propylene, or other copolymerizable monomer.
Claim 2
Dependent Claim 20 words
The process of claim 1, in which a shaped copolymer of tetrafluoroethylene and propylene is exposed to the irradiation treatment.
Claim 3
Dependent Claim 16 words
The process of claim 1, wherein the total dose is from 105 -5 X 107 Rads.
Claim 4
Dependent Claim 12 words
The process of claim 1, wherein said copolymer is irradiated in vacuum.
Claim 5
Dependent Claim 107 words
A cross-linked copolymer of tetrafluoroethylene and propylene which is characterized by an ultimate elongation of greater than 200%, an ultimate tensile strength of greater than 80 kg/cm2, and a decomposition temperature of more than 300* C. which is produced by irradiating a copolymer of tetrafluoroethylene and propylene having an average molecular weight of more than 20,000 and an intrinsic viscosity in tetrahydrofuran at 30* C. of more than 0.25, wherein the mole ratio of tetrafluoroethylene to propylene is from 90/10 to 20/80, with high energy ionizing radiation at a total dose of 105 - 5 X 107 Rads, and a dose rate of 102 to 109 roentgens/hour.

References Cited (Backward Citations)

US3467635A Cited
US3556965A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-02-27 1976-08-28 1977-02-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-02-27 1980-08-28 1981-02-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-02-27 1984-08-28 1985-02-27 $7700.00 Window Closed / Lapsed

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