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Alkylation and dealkylation of aromatics in the presence of crystalline aluminosilicates

Assignee: Mobil Oil AS
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Filing: 1968-04-18
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Granted: 1973-02-13
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Expires: 1988-04-18
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Abstract

Abstract A process for alkylating or dealkylating a compound capable of alkylation or dealkylation by contacting it in a reaction zone maintained under conditions effective for accomplishing said alkylation or dealkylation with a catalyst comprising a crystalline zeolite characterized by a unique X-ray diffraction pattern or products of thermal treatment of the zeolite. The zeolite can be further defined by reference to the following formula expressed in terms of mole ratios of oxides: WHEREIN M is a cation, J is aluminum or gallium and Z is silicon or germanium and n is the valence of M.

Inventors

  • 👤 E Bowes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 17:45
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/54; C07C2/64; C07C2/66; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/70; B01J29/7011; C07C4/00; C07C4/08; C07C4/12; C07C4/14; C07C4/18; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42; C07C2521/00; C07C2521/02; C07C2521/04; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/70

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 69 words
A process for alkylating benzene which comprises contacting the same with ethylene at atmospheric pressure and a temperature of approximately 350* F. in the presence of a catalyst consisting essentially of a crystalline aluminosilicate zeolite characterized by the X-ray diffraction lines of Table 1 and a composition, expressed in terms of mole ratios of oxides as follows: wherein M is predominately hydrogen and n is the valence of M.
Claim 2
Dependent Claim 69 words
A process for alkylating benzene which comprises contacting the same with ethylene at atmospheric pressure and a temperature of approximately 350* F. in the presence of a catalyst consisting essentially of a crystalline aluminosilicate zeolite characterized by the X-ray diffraction lines of Table 1 and a composition, expressed in terms of mole ratios of oxides as follows: wherein M is predominately hydrogen and n is the valence of M.
Claim 3
Dependent Claim 22 words
A process according to claim 1 wherein said catalyst is HZSM-4 characterized by a silica/alumina mole ratio between about 5 and 15.
Claim 4
Dependent Claim 18 words
A process according to claim 1 wherein said catalyst is employed in combination with a support or binder.

References Cited (Backward Citations)

US3370099A Cited
US3251897A Cited
US3254023A Cited
US3377400A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-02-13 1976-08-14 1977-02-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-02-13 1980-08-14 1981-02-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-02-13 1984-08-14 1985-02-13 $7700.00 Window Closed / Lapsed

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