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Process of laminating using vinyl acetate-ethylene copolymer latex adhesive composition

Assignee: Air Products and Chemicals Inc
•
Filing: 1970-05-06
•
Granted: 1973-01-02
•
Expires: 1990-05-06
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Abstract

Abstract Aqueous latices comprising vinyl acetate-ethylene copolymers are effective to laminate a film, web or other substrate to a second surface whereby the dried polymer film deposited by the latex unites the substrate to the second surface.

Inventors

  • 👤 M Lindemann
  • 👤 J Iacoviello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 23:52
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/12; B32B27/30; B32B27/304; B32B7/00; B32B7/04; B32B7/12; C; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; C09J131/00; C09J131/02; C09J131/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31884; Y10T428/31909; Y10T428/31928; Y10T442/00; Y10T442/30; Y10T442/3854; Y10T442/387

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 15 words
The composition of claim 1 wherein the polyvinyl alcohol is acetylated up to 50 percent.
Claim 2
Dependent Claim 19 words
The composition of claim 1 wherein the ethylene content of the copOlymer is more than 15 percent by weight.
Claim 3
Dependent Claim 142 words
A process of uniting a substrate with an adjacent surface of a continuous web to form a laminate, which process comprises interposing between the substrate and web an adhesive composition consisting essentially of an aqueous vinyl acetate-ethylene copolymer emulsion having from about 5 to about 40 percent by weight ethylene, a solids content of from 45 to about 60 percent by weight and an intrinsic viscosity of from 1 to 2.5 dl/g, as measured in benzene at 30* C, the vinyl acetate and ethylene monomers copolymerized in the presence of a protective colloid in an amount from about 0.05 to about 2 percent by weight based upon the total weight of the emulsion and adhering the substrate and web to form a resulting laminate structure, said protective colloid being selected from the group consisting essentially of a polyvinyl alcohol and hydroxyethyl cellulose.
Claim 4
Dependent Claim 18 words
The process of claim 4 wherein the polyvinyl alcohol of the composition is acetylated up to 50 percent.
Claim 5
Dependent Claim 20 words
The process of claim 4 wherein the ethylene content of the copolymer emulsion is more than 15 percent by weight.
Claim 6
Dependent Claim 20 words
The process of claim 4 wherein the substrate and web of the laminate are polyvinyl chloride film and cloth, respectively.
Claim 7
Dependent Claim 120 words
A laminate comprising a substrate and an overlying continuous web bonded together by means of an adhesive composition, said composition consisting essentially of an aqueous vinyl acetate-ethylene copolymer emulsion having from about 5 to about 40 percent by weight ethylene, a solids content of from 45 to about 60 percent by weight and an intrinsic viscosity of from 1 to 2.5 dl/g, as measured in benzene at 30* C, the vinyl acetate and ethylene monomers copolymerized in the presence of a protective colloid in an amount from about 0.05 to about 2 percent by weight based upon the total weight of the emulsion, said protective colloid being selected from the group consisting essentially of a polyvinyl alcohol and hydroxyethyl cellulose.
Claim 8
Dependent Claim 19 words
The laminate of claim 8 wherein the polyvinyl alcohol of the adhesive composition is acetylated up to 50 percent.
Claim 9
Dependent Claim 20 words
The laminate of claim 8 wherein the ethylene content of the copolymer emulsion is more than 15 percent by weight.
Claim 10
Dependent Claim 20 words
The laminate of claim 8 wherein the substrate and web of the laminate are polyvinyl chloride film and cloth, respectively.

References Cited (Backward Citations)

US3197429A Cited
US3355322A Cited
US3446767A Cited
US3380851A Cited
US3440200A Cited
US3440199A Cited
US3526540A Cited
US3645952A Cited
US3301809A Cited
US3423352A Cited
US3526538A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-01-02 1976-07-03 1977-01-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-01-02 1980-07-03 1981-01-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-01-02 1984-07-03 1985-01-02 $7700.00 Window Closed / Lapsed

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