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US3697622A
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Chemically curable liquid polyene-polythiol polymer composition
Assignee: WR Grace and Co
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Filing: 1971-06-25
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Granted: 1972-10-10
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Expires: 1991-06-25
Abstract
Abstract The invention disclosed is for a new chemically curable liquid polymer composition which includes a liquid polyene component having a molecule containing at least two unsaturated carbon-tocarbon bonds disposed at terminal positions on a main chain backbone of the molecule, and a polythiol component having a molecule containing a multiplicity of pendant or terminally positioned -SH functional groups per average molecule. The chemically curable liquid polymer composition upon curing in the presence of a chemical free radical generating reagent forms odorless, solid, elastomeric products which may serve as sealants, coatings, adhesives, and molded articles.
Inventors
- 👤 Clifton L Kehr
- 👤 Walter R Wszolek
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 23:22
CPC Classifications
C; C08; C08G; C08G75/00; C08G75/02; C08G75/04; C08G75/045; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/671; C08G18/6715; C08G18/70; C08G18/81; C08G18/8108; C08G18/83; C08G18/834; C08G18/835; C08G75/12; C08L; C08L81/00; Y; Y10; Y10S; Y10S525/00; Y10S525/92; Y10S525/921; Y10S525/925
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
81 words
The composition of claim 1 wherein (A) has the formula: wherein a and b are integers greater than 1; R2 is a member of the group consisting of hydrogen and alkyl; R3 is a member of the group consisting of hydrogen, and saturated alkyl; R4 is a divalent derivative of the group consisting of phenyl, benzyl, alkyl, cycloalkyl, substituted phenyl, substituted benzyl, substituted alkyl and substituted cycloalkyl, said alkyl, cycloalkyl and substituents on members substituted being defined as in claim 1.
Claim 2
Dependent Claim
20 words
The composition of claim 1 wherein the mole ratio of ene to thiol is from about 0.5/1 to about 2/1.
Claim 3
Dependent Claim
20 words
The composition of claim 1 wherein the mole ratio of ene to thiol is from about 0.75/1 to about 1.5/1.
Claim 4
Dependent Claim
49 words
The composition of claim 1 wherein the chemical free radical generating reagent is selected from the group consisting of molecular oxygen; organic hydroperoxides and peroxides; blends of organic hydroperoxides and peroxides with transition metal salts; and blends of organic hydroperoxides and peroxides with tertiary amines and transition metal salts.
Claim 5
Dependent Claim
308 words
A process of forming essentially odorless solid polythioether which comprises I. Admixing: A. a A-unsaturated polyene component which comprises the formula: (A-(X)m wherein m is an integer of at least 2; wherein X is where f is an integer from 1 to 9; R is a radical selected from the group consisting of hydrogen, fluorine, chlorine, furyl, thienyl, pyridyl, phenyl and substituted phenyl, benzyl and substituted benzyl, alkyl and substituted alkyl, alkoxy and substituted alkoxy, cycloalkyl and substituted cycloalkyl; said substituents on said substituted members selected from the group consisting of nitro, chloro, fluoro, acetoxy, acetamide, phenyl, benzyl, alkyl, alkoxy and cycloalkyl; said alkyl and alkoxy having from one to nine carbon atoms and said cycloalkyl having from three to eight carbon atoms; wherein (A) is free of reactive carbon-to-carbon unsaturation; free of highly water-sensitive members; and is a polyvalent chemically compatible member of the group consisting of carbonate, carboxylate, carbonyl, ether, silane, silicate, phosphonate, phosphite, phosphate, alkyl and substituted alkyl, cycloalkyl and substituted cycloalkyl, aryl and substituted aryl, urethane and substituted urethane, urea and substituted urea, amine and substituted amine, amide and substituted amide, hydroxyl, heterocyclic carbon containing radical, and mixtures thereof; said substituents on said members substituted being defined above, said component having a molecular weight in the range from about 64 to 20,000; and a viscosity in the range from essentially 0 to 20 million centipoises at 70* C; and B. a polythiol component having a molecular weight in the range from about 50 to about 20,000 of the general formula: R8-(SH)n wherein R8 is a polyvalent organic moiety free from reactive carbon-to-carbon unsaturation and n is at least 2, the sum of m and n being greater than 4, with the ene/thiol mole ratio being selected so as to provide a cross-linked solid, self-supporting cured product, and C. a chemical free radical generating reagent.
Claim 6
Dependent Claim
14 words
An article comprising the composition of claim 6 as a coating on a substrate.
Claim 7
Dependent Claim
14 words
An article comprising the composition of claim 6 as an adhesive between two substrates.
Claim 8
Dependent Claim
12 words
An article comprising the composition of claim 6 as an elastomeric sEalant.
Claim 9
Dependent Claim
11 words
A shaped, molded article cast from the composition of claim 6.
Claim 10
Dependent Claim
58 words
The process of claim 6 wherein the chemical free radical generating reagent is selected from the group consisting of molecular oxygen; organic hydroperoxides and peroxides; blends of organic hydroperoxides and peroxides with tertiary amines; blends of organic hydroperoxides and peroxides with transition metal salts; and blends of organic hydroperoxides and peroxides with tertiary amines and transition metal salts.
Claim 11
Dependent Claim
11 words
The composition of claim 1 wherein the polyene has the formula:
Claim 12
Dependent Claim
20 words
The composition of claim 1 wherein the polyene has the formula: where n is an integer of 0 or greater.
Claim 13
Dependent Claim
17 words
The composition of claim 1 wherein the polyene has the structure: where n is at least 1.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1975-10-10 | 1976-04-10 | 1976-10-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1979-10-10 | 1980-04-10 | 1980-10-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1983-10-10 | 1984-04-10 | 1984-10-10 | $7700.00 | Window Closed / Lapsed |