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US3676646A Expired / Lapsed US ⏱️ 0.0 years remaining

Document with chemically developable precisely defined alphanumeric characters

Assignee: International Business Machines Corp
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Filing: 1970-08-31
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Granted: 1972-07-11
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Expires: 1990-08-31
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Abstract

Abstract A document processable in optical alphanumeric character readers has a plurality of identical constraint character patterns printed on an untreated substrate in an improved moisture-setting or lithographic ink that is visible to the human eye as a hand printing guide to the operator but not machine-recognizable until selectable portions of the pattern are developed by a developing solution applied by a pen to create a desired one of a plurality of alphanumeric characters of an intensity recognizable by such a machine. The discontinuous pattern configuration assures sharply defined distinctive machine-recognizable characters without undesirable feathered edges or ''''tics.'''' The highly reflective developer provides no machine-recognizable image when inadvertently applied to uninked areas of the substrate.

Inventors

  • 👤 Donald W Carlsen
  • 👤 John J Kotla
  • 👤 Arden A Parker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:13
CPC Classifications
G; G06; G06K; G06K19/00; G06K19/04; G06V; G06V30/00; G06V30/10; G06V30/22; G06V30/224

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 238 words
As an article of manufacture, a document comprising a substrate overprinted with a plurality of identical symbols in an ink that is visible to the eye but not recognizable by an optical character reading machine, each such symbol constituting a constraint pattern adapted to be chemically developed in selectable portions thereof by an operator-applied developing solution, that portion of the inked pattern contacted by the solution reacting chemically to create a desired one of a plurality of possible hand printable, human readable, non-smearing, machine readable characters having a precisely defined machine recognizable configuration corresponding to the sharp lines of the overprinted constraint pattern where developed by said solution, and said solution when applied to any portions of the substrate not overprinted with said ink being ineffective to provide indicia of a color and intensity readable by the machine, each of said symbols being in the form of a hollow figure divided into a plurality of hollow subfigures, said figure and subfigures being defined by discontinuous non-touching sections separated by dots which do not touch the sections or other dots, the dots being at least at each point of adjacency of one section with another, and printed in said ink with a spacing predetermined to be great enough to preclude the creation of undesired feathered edges or at intersections of a developed section with one not being developed without creating detectable discontinuities in the machine readable character as developed.
Claim 2
Dependent Claim 238 words
As an article of manufacture, a document comprising a substrate overprinted with a plurality of identical symbols in an ink that is visible to the eye but not recognizable by an optical character reading machine, each such symbol constituting a constraint pattern adapted to be chemically developed in selectable portions thereof by an operator-applied developing solution, that portion of the inked pattern contacted by the solution reacting chemically to create a desired one of a plurality of possible hand printable, human readable, non-smearing, machine readable characters having a precisely defined machine recognizable configuration corresponding to the sharp lines of the overprinted constraint pattern where developed by said solution, and said solution when applied to any portions of the substrate not overprinted with said ink being ineffective to provide indicia of a color and intensity readable by the machine, each of said symbols being in the form of a hollow figure divided into a plurality of hollow subfigures, said figure and subfigures being defined by discontinuous non-touching sections separated by dots which do not touch the sections or other dots, the dots being at least at each point of adjacency of one section with another, and printed in said ink with a spacing predetermined to be great enough to preclude the creation of undesired feathered edges or at intersections of a developed section with one not being developed without creating detectable discontinuities in the machine readable character as developed.
Claim 3
Dependent Claim 105 words
An article according to claim 1, wherein the overprinted ink is adapted to produce the machine readable character by chemical reaction with a developing solution that comprises an iron salt dissolved in a polar solvent in the presence of halide and acetate ions, and said ink comprises a phenol whose reaction product with iron salts is black, and said ink being substantially neutral to cause at least two protonic hydrogen ions to be removed from the phenol before application of the developing solution to the ink and generate highly reactive phenoxide ions with which the iron salts readily react upon application of said developing solution.
Claim 4
Dependent Claim 46 words
An article according to claim 2, wherein the machine readable character formed as the reaction product of the developing solution with said ink is adapted to be eradicated and rendered non-machine readable by application of a correction fluid comprising a solution of phosphoric acid in water.
Claim 5
Dependent Claim 67 words
An article according to claim 2, wherein said ink is a moisture-setting ink having a resin content with an acid number of the order of about 250 to 350 and containing a compound that when combined with the phenol renders the ink substantially neutral, and said compound being an amine, a 1 percent solution of which in water would give a pH value of at least 9.
Claim 6
Dependent Claim 23 words
An article according to claim 4, whereIn the ratio, by weight, of phenol to amine is within the range of 2:1 and 5:1.
Claim 7
Dependent Claim 41 words
An article according to claim 2, wherein said ink is a lithographic ink having a resin content with an acid number of the order of about 10 to 25 which does not substantially alter the essentially neutral nature of the ink.
Claim 8
Dependent Claim 50 words
An article according to claim 1, wherein said symbols when undeveloped having a reflectance ratio relative to the substrate of substantially 95 percent or more in a preselected band within the infrared wavelength range and when developed having a reflectance ratio of substantially 40 percent or less within said band.
Claim 9
Dependent Claim 43 words
An article according to claim 7, wherein portions of the substrate not overprinted with said ink provide a reflectance ratio relative to the substrate of substantially 95 percent or more within said preselected band when developing solution is inadvertently applied to such portion.
Claim 10
Dependent Claim 60 words
An article according to claim 2, wherein said overprinted ink comprises, by weight, approximately 35 percent phenol compound, 43 percent of a moisture-set vehicle, 8 percent of an amine selected from the group consisting of tetradecyl amine and stearyl amine, 3 percent thickening agent, 5 percent hygroscopic solvent, 1 percent pigment, 3 percent lubricating grease, and 2 percent wetting agent.
Claim 11
Dependent Claim 66 words
An article according to claim 2, wherein said overprinted ink comprises by weight, approximately 35 percent propyl gallate, 43 percent of a 60 percent resin in triethylene glycol, 8 percent of an amine selected from the group consisting of tetradecyl amine and stearyl amine, 3 percent alumina hydrate, 5 percent diethylene glycol, 1 percent pigment, 3 percent lubricating grease, and 2 percent sorbitan partial fatty ester.
Claim 12
Dependent Claim 25 words
An article according to claim 2, wherein said overprinted ink comprises, by weight, approximately 40 percent phenol compound, 57 percent varnish, and 3 percent pigment.
Claim 13
Dependent Claim 47 words
An article according to claim 2, wherein said overprinted ink comprises, by weight, approximately 35 to 40 percent of at least one phenolic compound selected from the group consisting of propyl gallate, trihydroxybutyrophenone, sodium salicylate in combination with 2,3 dihydroxynaphthalene-6-sulfonic acid, 2,4 dihydroxybenzophenone, sodium salt, and 8-hydroxyquinoline.
Claim 14
Dependent Claim 55 words
An article according to claim 2, wherein the overprinted ink is adapted to produce such machine readable character by chemical reaction with a developing solution that comprises, by weight, approximately 20 percent ferric chloride hexahydrate, 4 percent ammonium acetate and 76 percent solvents selected from the group consisting of 1-butanol, diethylene glycol and tetraethylene glycol.
Claim 15
Dependent Claim 67 words
An article according to claim 13, wherein the machine readable character formed as the reaction product of the developing solution with said ink is adapted to be eradicated and rendered non-machine readable by application of a correction fluid comprising, by weight, approximately 10 percent of an 85 percent solution of phosphoric acid in water, 80 percent water, 9 percent denatured alcohol, and 1 percent octylphenoxy polyethoxy ethanol.
Claim 16
Independent Claim 196 words
The method of creating an optical character recognizing machine-readable document with precisely defined hand delineated machine readable characters, comprising the steps of providing an ink that is visible to the human eye when applied to a substrate but not machine readable by an optical character reading machine, and is capable of providing a character of a color and intensity that is machine readable only where a developing solution is applied thereto, printing the substrate with said ink to provide in one printing step a plurality of identical constraint character patternS from which a language of precisely defined machine recognizable characters may be formed, said patterns being formed of discontinuous non-touching segments separated by dots which do not touch the segments or other dots, the dots being at least at each point of adjacency of one segment with another, said segments and dots being visible to the human eye and with a predetermined spacing corresponding to the maximum that will provide, when developed, a machine readable character without detectable discontinuities, and tracing over selectable portions of at least one pattern with the developing solution so as to develop such portions into a desired one of said characters.
Claim 17
Independent Claim 196 words
The method of creating an optical character recognizing machine-readable document with precisely defined hand delineated machine readable characters, comprising the steps of providing an ink that is visible to the human eye when applied to a substrate but not machine readable by an optical character reading machine, and is capable of providing a character of a color and intensity that is machine readable only where a developing solution is applied thereto, printing the substrate with said ink to provide in one printing step a plurality of identical constraint character patternS from which a language of precisely defined machine recognizable characters may be formed, said patterns being formed of discontinuous non-touching segments separated by dots which do not touch the segments or other dots, the dots being at least at each point of adjacency of one segment with another, said segments and dots being visible to the human eye and with a predetermined spacing corresponding to the maximum that will provide, when developed, a machine readable character without detectable discontinuities, and tracing over selectable portions of at least one pattern with the developing solution so as to develop such portions into a desired one of said characters.
Claim 18
Dependent Claim 72 words
The method according to claim 15, wherein the ink comprises a phenol whose reaction product with iron salts is black, said ink being rendered substantially neutral to cause, prior to the tracing step, at least two protonic hydrogen ions to be removed from the phenol and generate highly reactive phenoxide ions, and the developing solution comprises an iron salt dissolved in a polar solvent in the presence of halide and acetate ions.

References Cited (Backward Citations)

US1732223A Cited
US1884197A Cited
US2963220A Cited
US3031961A Cited
US3011905A Cited
US3088841A Cited
US3527927A Cited
US3485168A Cited
US3438927A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-07-11 1976-01-10 1976-07-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-07-11 1980-01-10 1980-07-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-07-11 1984-01-10 1984-07-11 $7700.00 Window Closed / Lapsed

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