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US3676390A
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Compositions of polymers of bicycla (2.2.1) heptene-2 and derivatives
Assignee: Charbonnages de France CDF
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Filing: 1971-01-20
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Granted: 1972-07-11
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Expires: 1991-01-20
Abstract
Abstract The invention relates to a vulcanized elastomer composition consisting essentially of a vulcanized mixture of (1) a macromolecular polymer compound selected from the group consisting of substantially amorphous polymers of bicyclo (2.2.1) heptene-2 and its substituted derivatives (2) at least one compound having a low volatility and a freezing point less than -30* C, this mixture of said polymer and said low volatility compound prior to vulcanization having a glass transition temperature lower than about -10* C, said vulcanized composition having a combination of good mechanical and physical properties.
Inventors
- 👤 Jean Vergne
- 👤 Leon Solaux
- 👤 Jean-Claude Robinet
- 👤 Philippe Lacroix
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 18:28
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/0016; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08; C08K3/00; C08K3/01; C08K3/013
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
49 words
A vulcanized elastomer composition in accordance with claim 1 wherein said compound having a low volatility and a freezing point less than -30* C. is selected from the group consisting of aromatic and naphthenic hydrocarbons and mixtures of essentially aromatic type hydrocarbons and mixtures of essentially naphthenic type hydrocarbons.
Claim 2
Dependent Claim
32 words
A vulcanized elastomer composition in accordance with claim 1, further comprising up to 400 parts by weight of a filler selected from the group consisting of carbon black, silica, kaolin, and CaCO3.
Claim 3
Dependent Claim
55 words
A method of manufacture of a composition as claimed in claim 1, comprising the polymerization of the said bicyclo (2.2.1) heptene-2 compound according to said formula in the presence of said compound having a low volatility and a freezing point lower than -30* C. and containing substantially no ethylene unsaturation and followed by the vulcanization.
Claim 4
Dependent Claim
57 words
A vulcanized composition of elastomer material in accordance with claim 1 having a breaking strength of 4 kg/sq.mm and a rebound resilience of 3 percent wherein said polymer compound consists of amorphous homo-polymer of bicyclo (2.2.1) heptene-2, and further comprising 40 parts by weight of an essentially aromatic oil and 60 parts by weight of carbon black.
Claim 5
Dependent Claim
37 words
A vulcanized elastomer composition in accordance with claim 1, wherein said polymer compound is an amorphous homo-polymer of bicyclo (2.2.1) heptene-2; and further comprising up to 400 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 6
Dependent Claim
37 words
A vulcanized elastomer composition in accordance with claim 1, wherein said polymer compound is an amorphous homo-polymer of methyl-5-bicyclo (2.2.1) heptene-2; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 7
Dependent Claim
38 words
A vulcanized elastomer composition in accordance with claim 1, wherein said polymer compound is an amorphous homo-polymer of bicyclo (2.2.1) heptene-2 oic-5; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 8
Dependent Claim
38 words
A vulcanized elastomer composition in accordAnce with claim 1, wherein said polymer compound is an amorphous homo-polymer of bicyclo (2.2.1) heptene-2 ol-5; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 9
Dependent Claim
41 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of bicyclo (2.2.1) heptene-2 and methyl-5-bicyclo (2.2.1) heptene-2; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 10
Dependent Claim
46 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of bicyclo (2.2.1) heptene-2 and acetate of bicyclo (2.2.1) heptene-2 ol 5; and further comprising up to Kaolin 200 parts by weight of carbon black, silica, daolin or CaCO3.
Claim 11
Dependent Claim
46 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of bicyclo (2.2.1) heptene-2 and methyl ester of bicyclo (2.2.1) heptene-2 oic 5; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 12
Dependent Claim
46 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of bicyclo (2.2.1) heptene-2 and dimethyl trans ester of bicyclo (2.2.1) heptene-2 dioic-5,6; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 13
Dependent Claim
47 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of bicyclo (2.2.1) heptene-2 and the exo-cis dimethyl ester of bicyclo (2.2.1) heptene-2 dioic-5,6; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 14
Dependent Claim
47 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of methyl-5 bicyclo (2.2.1) heptene-2 and the acetate of bicyclo (2.2.1) heptene-2 ol 5; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 15
Dependent Claim
46 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of methyl-5 bicyclo (2.2.1) heptene-2 and the methylester of bicyclo (2.2.1) heptene-2 oic-5; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 16
Dependent Claim
47 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of methyl-5 bicyclo (2.2.1) heptene-2 and the trans dimethyl ester of bicyclo (2.2.1)heptene-2 dioic-5,6; and further comprising up to 200 parts by weight of carbon black, silica, kaolin or CaCO3.
Claim 17
Dependent Claim
46 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer compound is an amorphous copolymer of methyl-5 bicyclo (2.2.1)heptene-2 and the exo-cis dimethyl ester of bicyclo (2.2.1)heptene-2 dioic-5,6; and further comprising up to 200 parts by weight of carbon black, silica, Kaolin or CaCO3.
Claim 18
Dependent Claim
55 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer is an amorphous poly bicyclo (2.2.1)heptene-2; and further comprising 200 parts of a mixture of mainly aromatic or naphthenic hydrocarbon oils and 200 parts of S.A.F. type carbon black and having a rebound resilience below 30 percent between -50* C. and +60* C.
Claim 19
Dependent Claim
54 words
A vulcanized elastomer composition in accordance with claim 1 wherein said polymer is an amorphous poly bicyclo (2.2.1)heptene-2; and further comprising 400 parts of a mixture of a mainly aromatic hydrocarbon oil and 400 parts of S.A.F. type carbon black and having a rebound resilience below 25 percent between -50* C. and +60* C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1975-07-11 | 1976-01-10 | 1976-07-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1979-07-11 | 1980-01-10 | 1980-07-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1983-07-11 | 1984-01-10 | 1984-07-11 | $7700.00 | Window Closed / Lapsed |