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US3674666A Expired / Lapsed US ⏱️ 0.0 years remaining

Enhancing reaction rates

Assignee: JOHN B BUTT
•
Filing: 1970-08-19
•
Granted: 1972-07-04
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Expires: 1990-08-19
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Abstract

Abstract Process and apparatus for effecting a chemical reaction in an electrically uncharged reactant to produce a product by introducing reactant into a chemical reactor having walls defining a chamber, a reaction zone within the chamber, and an inlet to admit reactant to the chamber, a first electrode and a second electrode spaced therefrom, the electrodes being opposed across the reaction zone, a supporting structure of electrically non-conductive material supported between the electrodes and in the reaction zone, the structure having channels for passage of reactant and product material, a plurality of electrically conductive particles separately supported on the structure, the particles being electrically insulated one from another and having surface portions exposed to direct contact with reactant in the channels, the surface portions having catalytic effect which is enhanced by changing the electric charge on the surface portions, and means connected to the electrodes for establishing an electrical potential difference between said electrodes. Reactant is brought into contact with said surface portions of said particles while simultaneously applying an electric potential difference across the electrodes to produce an electric field which changes the charge on said exposed surface portions of the electrically conductive particles and thereby enhances the catalytic effect of said exposed surface portions in producing the product.

Inventors

  • 👤 Richard N Foster
  • 👤 John B Butt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 06:43
CPC Classifications
B; B01; B01J; B01J37/00; B01J37/34; B01J19/00; B01J19/08; B01J19/087; B01J19/088; C; C07; C07C; C07C5/00; C07C5/32; C07C5/327; C07C5/333; C07C5/3332

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 13 words
The reactor of claim 1 including means for periodically reversing said potential difference.
Claim 2
Dependent Claim 23 words
The reactor of claim 2 including means for applying a potential difference having an rms value greater than 300 volts to said electrodes.
Claim 3
Dependent Claim 22 words
The reactor of claim 1 wherein the particles have exposed surface area in excess of 0.1 m2 per gram of support structure.
Claim 4
Dependent Claim 18 words
The reactor of claim 4 wherein said particles have points with radii of curvature less than 100 A.
Claim 5
Dependent Claim 220 words
A reactor for effecting a chemical reaction therein through the action of an electrically conductive catalytic material effective to promote said reaction to a degree dependent on the surface electric charge on said material, said reactor having a wall of generally cylindrical form defining a chamber, with an inlet at one end and an outlet at the opposed end of the chamber and a reaction zone within the chamber at a position intermediate to the inlet and the outlet, comprising: a first electrode in the form of an axial rod and passing through the reaction zone, a second electrode in the form of a cylindrical shell around the reaction zone, a rigid supporting structure of electrically non-conductive material supported between said electrodes and in the reaction zone, the structure having channels for passage of reactant and product material, a plurality of particles of said catalytic material having points with radii of curvature less than 100 A., said particles supported in spaced relation on said structure so as to be electrically insulated one from another and having surface portions aggregating more than 0.1 m2 per gram of structure exposed to direct contact with reactant in said channels, and means connected to said electrodes for inducing modification of surface charge on said particles by establishing an electric potential difference between said electrodes.
Claim 6
Dependent Claim 206 words
A process for effecting a chemical reaction in an electrically uncharged reactant to produce a product, comprising: introducing said reactant into a chemical reactor having walls defining a chamber, a reaction zone within said chamber, and an inlet to admit reactant to said chamber, a first electrode and a second electrode spaced therefrom, said electrodes being opposed across said reaction zone, a supporting structure of electrically non-conductive material supported between said electrodes and in said reaction zone, said structure having channels for passage of reactant and product material, a plurality of electrically conductive particles separately supported on said structure, said particles being electrically insulated one from another and having surface portions exposed to direct contact with reactant in said channels, said surface portions promoting said reaction to a degree dependent on the electric charge on said surface portions, and means connected to said electrodes for establishing an electrical potential difference between said electrodes, bringing said reactant into contact with said surface portions of said particles while simultaneously inducing changes in the surface charge on said exposed surface portions of said electrically conductive particles by applying an electric potential difference across said electrodes, and thereby enhancing production of said product, and withdrawing said product from said reactor.
Claim 7
Dependent Claim 20 words
The process of claim 7 wherein the exposed surface of said particles exceeds 0.1 m2 per gram of support structure.
Claim 8
Dependent Claim 18 words
The process of claim 8 wherein said particles have points with radii of curvature less than 100 A.
Claim 9
Dependent Claim 12 words
The process of claim 7 wherein the potential difference is periodically reversed.

References Cited (Backward Citations)

US3421988A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-07-04 1976-01-03 1976-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-07-04 1980-01-03 1980-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-07-04 1984-01-03 1984-07-04 $7700.00 Window Closed / Lapsed

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