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US3669859A Expired / Lapsed US ⏱️ 0.0 years remaining

Process and compositions for protecting images with resin films

Assignee: Eastman Kodak Co
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Filing: 1969-08-29
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Granted: 1972-06-13
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Expires: 1989-08-29
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Abstract

Abstract Novel process and compositions are provided for forming protective coatings. The compositions feature a graft copolymer suspension in an electrically insulating carrier vehicle. The copolymer is comprised of a linear backbone chain formed of an unsaturated polymer soluble in the carrier vehicle, having grafted thereto pendant side chains substantially all of which are insoluble in the carrier vehicle. A developed image-bearing member which is contiguous with an electrically conductive backing is placed in close proximity to an electrode and a bias potential is applied between the electrode and the conductive backing. While this potential is being applied, the copolymer suspension is applied to the image-bearing surface of the member to deposit a uniform resin layer.

Inventors

  • 👤 Stewart H Merrill

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 10:28
CPC Classifications
G; G03; G03G; G03G13/00; G03G13/20; G03G8/00

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 165 words
A process for applying protective coatings to an image-bearing member, which member has a developed image on a surface thereof which is contiguous to an electrically conductive backing, using an electrode closely spaced from said image-bearing surface, said process comprising the steps of applying an electrical bias potential between such electrode and conductive backing; applying to the image-bearing surface of said member in the presence of said electrical bias potential a resin suspension comprising an electrically insulating liquid carrier vehicle having therein charge-bearing particles of a graft copolymer to deposit said copolymer particles uniformly over said member, said copolymer having a linear backbone chain formed of a polyene which is soluble in said carrier vehicle, said backbone chain having grafted thereto pendant side chains formed from monomers selected from the group consisting of acrylic and methacrylic acids, styrene, acrylonitrile, vinyl esters, and vinyl ethers, substantially all of said side chains being insoluble in said carrier vehicle; and affixing said uniformly deposited particles to said member.
Claim 2
Dependent Claim 25 words
A process as described in claim 1 wherein the carrier vehicle is an organic liquid having a volatility at least equal to that of kerosene.
Claim 3
Dependent Claim 34 words
A process as described in claim 1 wherein the polyene forming said backbone chain is formed by polymerizing a member selected from the group consisting of isoprene, butadiene, 2,3-dimethylbutadiene, chloroprene, styrene and mixtures thereof.
Claim 4
Dependent Claim 30 words
A process as described in claim 1 wherein the graft copolymer particles have a glass transition temperature below about 65* C. and wherein the carrier vehicle is an isoparaffinic hydrocarbon.
Claim 5
Dependent Claim 28 words
A process as described in claim 1 wherein the monomers forming said pendant side chains are vinyl esters selected from the group consisting of acrylic and methacrylic esters.
Claim 6
Dependent Claim 161 words
A process for fixing developed electrographic images on an electrographic element, which element has (a) an electrically conducting backing and (b) a visible, substantially unfixed, developed image on a surface thereof, using an electrode closely spaced from said image-bearing surface, said process comprising applying an electrical bias potential between such electrode and conductive backing; applying to the image-bearing surface of such element in the presence of said electrical bias potential a resin suspension comprising a hydrocarbon liquid carrier vehicle having therein charge-bearing particles of a graft copolymer to deposit said particles uniformly over the entire surface of said element, said copolymer having a linear backbone chain formed of a polyene which is soluble in said carrIer vehicle, said backbone chain having grafted thereto pendant side chains formed from monomers selected from the group consisting of acrylic and methacrylic esters, said particles having a glass transition temperature below about 35* C.; and removing excess carrier vehicle to permanently fix the copolymer thereto.
Claim 7
Dependent Claim 164 words
A process for fixing developed electrographic images on a receiving member, which member (a) is contiguous to an electrically conducting backing and (b) has a visible, substantially unfixed, developed image on a surface thereof, using an electrode closely spaced from said image-bearing surface, said process comprising applying an electrical bias potential between such electrode and conductive backing; applying to the image-bearing surface of such member in the presence of said electrical bias potential a resin suspension comprising a hydrocarbon liquid carrier vehicle having therein charge-bearing particles of a graft copolymer to deposit said particles uniformly over the entire surface of said member, said copolymer having a linear backbone chain formed of a polyene which is soluble in said carrier vehicle, said backbone chain having grafted thereto pendant side chains formed from monomers selected from the group consisting of acrylic and methacrylic esters, said particles having a glass transition temperature below about 35* C.; and removing excess carrier vehicle to permanently fix the copolymer thereto.

References Cited (Backward Citations)

US2898279A Cited
US2990280A Cited
US3257304A Cited
US3297557A Cited
US3518081A Cited
US3384565A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-06-13 1975-12-13 1976-06-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-06-13 1979-12-13 1980-06-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-06-13 1983-12-13 1984-06-13 $7700.00 Window Closed / Lapsed

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