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Method for inhibiting the deposition of wax from a wax-containing oil

Assignee: Union Oil Company of California
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Filing: 1970-10-28
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Granted: 1972-06-13
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Expires: 1990-10-28
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Abstract

Abstract A method for inhibiting the deposition of wax from waxcontaining petroleum and other wax-containing oils in which a small amount of a wax deposition inhibitor comprised of a copolymer of ethylene and a monoethylenically unsaturated ester is added to the petroleum.

Inventors

  • 👤 Paul W Fischer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 23:51
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/18; C10L1/192; C10L1/195; C09; C09K; C09K8/00; C09K8/52; C09K8/524; E; E21; E21B; E21B43/00; E21B43/25; C10L1/196; C10L1/1963; C10L1/197; C10L1/1973; Y; Y10; Y10S; Y10S507/00; Y10S507/927; Y10S507/929; Y10S507/931

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 66 words
The method in accordance with claim 1 wherein said monoethylenically unsaturated ester is characterized by the formula: wherein (1) R is hydrogen or an alkyl group containing from about one to 25 CARBON atoms and R1 is a vinyl or allyl group, or (2) R is an Alpha , Beta -unsaturated alkylene and R1 is an alkyl group containing from about one to 25 carbon atoms.
Claim 2
Dependent Claim 21 words
The method in accordance with claim 1 wherein said inhibitor is copolymer ethylene/vinyl acetate, copolymer ethylene/ethyl acrylate or copolymer ethylene/methyl methacrylate.
Claim 3
Dependent Claim 27 words
The method in accordance with claim 1 wherein said inhibitor is incorporated into said wax-containing oil as a solution of the copolymer dissolved in an organic solvent.
Claim 4
Dependent Claim 46 words
The method defined in claim 1 wherein the inhibitor is incorporated into said wax-containing oil at an oil temperature sufficiently high to maintain the wax dissolved in the oil, and wherein said oil is thereafter cooled to a temperature below the solidification temperature of the wax.
Claim 5
Dependent Claim 33 words
The method defined in claim 1 wherein said inhibitor is incorporated into said wax-containing oil in an amount to provide therein an effective concentration of said inhibitor between about 5 and 2,000 ppm.
Claim 6
Independent Claim 86 words
A method for inhibiting the deposition and accumulation of wax in wells, tanks, pipelines and like equipment handling a wax-containing oil, which comprises incorporating into said oil a wax deposition inhibitor comprising a copolymer of (1) ethylene and (2) a lower vinyl ester or a lower alkyl acrylate or methacrylate, said inhibitor being added to said oil in an amount to provide therein a concentration of said copolymer between about 5 and 2,000 ppm effective to inhibit the deposition and accumulation of wax in said equipment.
Claim 7
Dependent Claim 32 words
The method defined in claim 7 wherein said inhibitor is added to said oil as a solution containing about 10 to 50 weight percent of said copolymer dissolved in an organic solvent.
Claim 8
Dependent Claim 41 words
The method defined in claim 7 wherein said inhibitor is a copolymer of ethylene and vinyl acetate containing from about 10 to 70 weight percent vinyl acetate and exhibiting a melt index between about 1 and 600 grams per 10 minutes.
Claim 9
Dependent Claim 46 words
The method defined in claim 7 wherein the inhibitor is incorporated into said wax-containing oil at an oil temperature sufficiently high to maintain the wax dissolved in the oil, and wherein said oil is thereafter cooled to a temperature below the solidification temperature of the wax.
Claim 10
Independent Claim 106 words
A method for inhibiting the deposition of wax from a wax-containing oil comprising admixing into said oil at an oil temperature sufficiently high to maintain the wax dissolved in the oil an amount of a solution of about 10 to 50 weight percent of a wax deposition inhibitor dissolved in an organic solvent to provide in said wax-containing oil an effective concentration of said inhibitor between about 5 and 2,000 ppm, said wax deposition inhibitor comprising a copolymer of ethylene and vinyl acetate containing about 35 to 55 weight percent vinyl acetate and exhibiting a melt index between about 1 and 600 grams per 10 minutes.
Claim 11
Dependent Claim 42 words
The method defined in claim 11 wherein said wax deposition inhibitor is a copolymer of ethylene and vinyl acetate containing about 39 to 42 weight percent vinyl acetate and exhibiting a melt index between about 1 and 600 grams per 10 minutes.
Claim 12
Dependent Claim 184 words
In a method for operating a well for the produc-tion of wax-containing petroleum from a subterranean formation wherein the petroleum flows from the formation into the well and is accumulated therein at a temperature sufficiently high to maintain the wax dissolved in the petroleum and wherein said petroleum is transported to the surface through a production tubing, said petroleum being cooled to a temperature below the solidification temperature of the wax whereupon wax participates from the petroleum and tends to deposit on the interior surface of the production tubing and on the interior surfaces of surface equipment causing them to become plugged with wax, the imProvement which comprises adding to the wax-containing petroleum in the well a wax deposition inhibitor comprising a copolymer of ethylene and a monoethylenically unsaturated ester characterized by the following formula: wherein (1) R is hydrogen or an alkyl group containing from about one to 25 carbon atoms and R is a vinyl or allyl group, or (2) R is an Alpha , Beta -unsaturated alkylene and R1 is an alkyl group containing from about one to 25 carbon atoms.
Claim 13
Dependent Claim 29 words
The method defined in claim 13 wherein said inhibitor is incorporated into said petroleum in an amount to provide therein an effective concentration between about 5 and 2,000 ppm.
Claim 14
Dependent Claim 27 words
The method defined in claim 14 wherein said wax deposition inhibitor is added to said petroleum as a solution of the copolymer dissolved in an organic solvent.
Claim 15
Dependent Claim 14 words
The method defined in claim 15 wherein said monoethylenically unsaturated ester is vinyl acetate.
Claim 16
Dependent Claim 19 words
The method defined in claim 16 wherein said copolymer contains from about 10 to 70 weight percent vinyl acetate.
Claim 17
Independent Claim 87 words
A method for removing accumulated wax deposits from surfaces contacted by a wax-containing oil which comprises periodically adding to said oil an effective concentration of a copolymer of ethylene and a monoethylenically unsaturated ester characterized by the formula: wherein (1) R is hydrogen or an alkyl group containing from about one to 25 carbon atoms and R1 is a vinyl or alkyl group, or (2) R is an Alpha , Beta -unsaturated alkylene and R1 is an alkyl group containing from about one to 25 carbon atoms.

References Cited (Backward Citations)

US2953551A Cited
US3189573A Cited
US3051653A Cited
US3244188A Cited
US3222336A Cited
US3395757A Cited
US3481870A Cited
US3531409A Cited
US3487036A Cited
US3542712A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-06-13 1975-12-13 1976-06-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-06-13 1979-12-13 1980-06-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-06-13 1983-12-13 1984-06-13 $7700.00 Window Closed / Lapsed

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