Patent US3650813A successfully refreshed from Google Patents.
US3650813A
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Acrylic-siloxane resin paint ii
Assignee: EIDP Inc
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Filing: 1969-12-24
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Granted: 1972-03-21
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Expires: 1989-12-24
Abstract
Abstract A novel acrylic-siloxane paint binder resin that is crosslinkable with vinyl monomers by exposure to an electron beam is produced in a two step reaction wherein (1) a siloxane having two or more hydroxy or alkoxy functional groups per molecule is reacted with a hydroxy functional copolymer of acrylic monomers, and (2) the siloxane-comprising reaction product of the first reaction step is reacted with a C5 - C12 monohydroxy acrylate, e.g., the monoester of a C2 - C8 diol and acrylic or methacrylic acid.
Inventors
- 👤 John D Nordstrom
- 👤 Carolyn B Zelek
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 23:10
CPC Classifications
C; C08; C08F; C08F290/00; C08F290/08; C08F290/14; C08F290/148; C08F8/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663; Y10T428/31678; Y10T428/31971; Y10T428/31989; Y10T442/00; Y10T442/20; Y10T442/2033
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
43 words
reacting by etherification the resultant resin with a C5-C12 monohydroxy ester of C2-C8 dihydric alcohol and acrylic or methacrylic acid employed in an amount sufficient to react with at least a substantial portion of the unreacted hydroxy or alkoxy groups of said siloxane.
Claim 2
Dependent Claim
17 words
An article of manufacture in accordance with claim 1 wherein said siloxane is a hydroxy functional siloxane.
Claim 3
Dependent Claim
44 words
reacting the resultant resin with a C5- - C12 monohydroxy ester of a C2-C8 dihydric alcohol and acrylic or methacrylic acid employed in an amount sufficient to react with at least a substantial portion of the unreacted hydroxy or alkoxy groups of said siloxane.
Claim 4
Dependent Claim
44 words
reacting by etherification the resultant resin with a C5-C12 monohydroxy ester of a C2-C8 dihydric alcohol and acrylic or methacrylic acid employed in an amount sufficient to react with at least a substantial portion of the unreacted hydroxy or alkoxy groups of said siloxane.
Claim 5
Dependent Claim
43 words
reacting the resultant resin with a C5- C12 monohydroxy ester of a C2-C8 dihydric alcohol and acrylic or methacrylic acid employed in an amount sufficient to react with at least a substantial portion of the untreated hydroxy or alkoxy groups of said siloxane.
Claim 6
Dependent Claim
17 words
An article of manufacture in accordance with claim 1 wherein said siloxane is a methoxy functional siloxane.
Claim 7
Dependent Claim
31 words
An article of manufacture in accordance with claim 1 wherein said siloxane has two to five functional groups per molecule, said functional groups being selected from hydroxyl groups of methoxy groups.
Claim 8
Dependent Claim
14 words
An article of manufacture in accordance with claim 1 wherein said substrate is wood.
Claim 9
Dependent Claim
16 words
An article of manufacture in accordance with claim 1 wherein said substrate is synthetic polymeric solid.
Claim 10
Dependent Claim
14 words
An article of manufacture in accordance with claim 1 wherein said substrate is glass.
Claim 11
Dependent Claim
14 words
An article of manufacture in accordance with claim 1 wherein said substrate is fabric.
Claim 12
Dependent Claim
14 words
An article of manufacture in accordance with claim 1 wherein said substrate is metal.
Claim 13
Dependent Claim
55 words
A paint comprising particulate pigment and a film-forming solution consisting essentially of 20 to 80 parts by weight vinyl monomers and 80 to 20 parts by weight of an acrylic-siloxane resin applied to said surface as a paint film and crosslinked thereon by exposing said film to ionizing radiation, said acrylic-siloxane resin being formed by:
Claim 14
Dependent Claim
19 words
A paint in accordance with claim 10 wherein said copoLymer contains one to 10 reactive hydroxyl groups per molecule.
Claim 15
Dependent Claim
25 words
A paint in accordance with claim 10 wherein said copolymer contains between about 0.5 and about 1.5 hydroxyl groups per 1, 000 units molecular weight.
Claim 16
Dependent Claim
29 words
A paint in accordance with claim 10 wherein said siloxane has two to five functional groups per molecule, said functional groups being selected from hydroxyl groups and methoxy groups.
Claim 17
Dependent Claim
25 words
A paint in accordance with claim 10 wherein said vinyl monomers consist essentially of esters of acrylic or methacrylic acid and C1 to C8 alcohol.
Claim 18
Dependent Claim
35 words
A paint in accordance with claim 10 wherein said vinyl monomers consist essentially of a mixture of C8 to C10 vinyl hydrocarbons and esters of acrylic or methacrylic acid and a C1 to C8 alcohol.
Claim 19
Dependent Claim
35 words
A paint in accordance with claim 10 wherein said film-forming solution consists essentially of 35 to 65 parts by weight of said acrylic-siloxane resin and 65 to 35 parts by weight of vinyl monomers. crosslinking
Claim 20
Independent Claim
94 words
A method for coating a substrate which comprises applying to the surface of said substrate to an average depth in the range of about 0.1 to about 4 mils of film-forming solution consisting essentially of 20 to 80 parts by weight vinyl monomers and 80 to 20 parts by weight of an alpha-beta olefinically unsaturated acrylic-siloxane resin and cross-linking said vinyl monomers and said resin upon said surface by exposing said coating to an electron beam having average energy in the range of about 100,000 to about 500,000 volts, said acrylic-siloxane resin formed by:
Claim 21
Dependent Claim
111 words
An acrylic-siloxane resin formed by (1) reacting by etherification one molar amount of a siloxane having at least two functional groups per molecule selected from hydroxyl groups and alkoxy groups with about 0.5 to about 1.5 molar amounts of a copolymer of vinyl monomers, said copolymer being characterized in that: a. at least one constituent monomer thereof is a C5-C12 monohydroxy ester of a C2-C8 dihydric alcohol and acrylic or methacrylic acid, b. at least one constituent monomer thereof is a C4-C12 alkyl ester of a C1-C8 monohydric alcohol and acrylic or methacrylic acid, and c. it contains about 0.2 to about two hydroxyl groups per 1,000 units molecular weight, and
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1975-03-21 | 1975-09-20 | 1976-03-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1979-03-21 | 1979-09-20 | 1980-03-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1983-03-21 | 1983-09-20 | 1984-03-21 | $7700.00 | Window Closed / Lapsed |