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US3644244A Expired / Lapsed US ⏱️ 0.0 years remaining

Polybutadiene-polynitrile graft copolymer dispersions stabilized with hydroxylamines

Assignee: Valspar Corp
•
Filing: 1969-12-15
•
Granted: 1972-02-22
•
Expires: 1989-12-15
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Abstract

Abstract Organosols of polybutadiene-polynitrile graft copolymers, stabilized against gelation by hydroxylamines. These compositions are useful as can coatings.

Inventors

  • 👤 Michael Fryd
  • 👤 Walter W Kaminski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:01
CPC Classifications
C; C08; C08F; C08F279/00; C08F279/02; C08K; C08K5/00; C08K5/16; C08K5/32; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31696; Y10T428/31699

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 14 words
The composition of claim 1 wherein the anti gelation agent is an N,N-dialkyl hydroxylamine.
Claim 2
Dependent Claim 36 words
The composition of claim 1 wherein the graft copolymer has a polybutadiene backbone and at least one polymethacrylonitrile graft component(s), the organic liquid carrier is an aliphatic hydrocarbon and the anti gelation agent is N,N-diethyl hydroxylamine.
Claim 3
Dependent Claim 36 words
The composition of claim 1 wherein the graft copolymer has a polybutadiene backbone and at least one polyacrylonitrile graft component(s), the organic liquid carrier is an aliphatic hydrocarbon and the anti gelation agent is N,N-diethyl hydroxylamine.
Claim 4
Dependent Claim 43 words
The composition of claim 1 wherein the graft copolymer has a polybutadiene backbone and at least one polymethacrylonitrile graft component and at least one polyvinylchloride graft component, the organic liquid carrier is an aliphatic hydrocarbon and the anti gelation agent is N,N-diethyl hydroxylamine.
Claim 5
Dependent Claim 23 words
The composition of claim 1 additionally containing from about 20 through about 10,000 parts per million of one or more variable-valence metal salts.
Claim 6
Dependent Claim 23 words
The composition of claim 2 additionally containing from about 20 through about 10,000 parts per million of one or more variable-valence metal salts.
Claim 7
Dependent Claim 23 words
The composition of claim 3 additionally containing from about 20 through about 10,000 parts per million of one or more variable-valence metal salts.
Claim 8
Dependent Claim 15 words
The composition of claim 8 wherein the metal salts are manganese octoate and cerium octoate.
Claim 9
Dependent Claim 23 words
The composition of claim 4 additionally containing from about 20 through about 10,000 parts per million of one or more variable-valence metal salts.
Claim 10
Dependent Claim 23 words
The composition of claim 5 additionally containing from about 20 through about 10,000 parts per million of one or more variable-valence metal salts.
Claim 11
Dependent Claim 13 words
The composition of claim 1 wherein the backbone component is a diene polymer.
Claim 12
Dependent Claim 20 words
The composition of claim 1 wherein the backbone component is a diene polymer and the ethylenically unsaturated nitrile is acrylonitrile.
Claim 13
Dependent Claim 18 words
The composition of claim 1 wherein the backbone component is a diene polymer and the nitrile is methacrylonitrile.
Claim 14
Dependent Claim 14 words
The composition of claim 13 wherein the anti gelation agent is an N,N-dialkyl hydroxylamine.
Claim 15
Dependent Claim 14 words
The composition of claim 14 wherein the anti gelation agent is an N,N-dialkyl hydroxylamine.
Claim 16
Dependent Claim 23 words
The composition of claim 12 additionally containing from about 20 to about 10,000 parts per million of one or more variable-valence metal salts.
Claim 17
Dependent Claim 23 words
The composition of claim 13 additionally containing from about 20 to about 10,000 parts per million of one or mOre variable-valence metal salts.
Claim 18
Dependent Claim 23 words
The composition of claim 14 additionally containing from about 20 to about 10,000 parts per million of one or more variable-valence metal salts.
Claim 19
Dependent Claim 23 words
The composition of claim 15 additionally containing from about 20 to about 10,000 parts per million of one or more variable-valence metal salts.
Claim 20
Dependent Claim 23 words
The composition of claim 16 additionally containing from about 20 to about 10,000 parts per million of one or more variable-valence metal salts.
Claim 21
Dependent Claim 15 words
A substrate coated with the composition of claim 1, heated to form a continuous film.
Claim 22
Dependent Claim 15 words
The substrate coated with the composition of claim 6, heated to form a continuous film.
Claim 23
Dependent Claim 15 words
A substrate coated with the composition of claim 12, heated to form a continuous film.
Claim 24
Dependent Claim 15 words
A substrate coated with the composition of claim 13, heated to form a continuous film.
Claim 25
Dependent Claim 15 words
A substrate coated with the composition of claim 14, heated to form a continuous film.
Claim 26
Dependent Claim 16 words
A substrate coated with a composition according to claim 15, heated to form a continuous film.
Claim 27
Dependent Claim 15 words
A substrate coated with a composition of claim 16, heated to form a continuous film.

References Cited (Backward Citations)

US2013319A Cited
US3095388A Cited
DE1222249B Cited
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US3449471A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-02-21 1975-08-23 1976-02-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-02-21 1979-08-23 1980-02-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-02-21 1983-08-23 1984-02-22 $7700.00 Window Closed / Lapsed

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