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Electroless metal deposition

Assignee: Kollmorgen Corp
•
Filing: 1969-08-04
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Granted: 1972-01-18
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Expires: 1989-08-04
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Abstract

Abstract An improved method for enhancing the ductility of electroless metal deposits is provided in which an electroless metal bath contains an extraneous ion which has a preferential capacity for being coulombically adsorbed at the outer layer of an electric double layer present on an interface in contact with such bath on which said metal is electrolessly depositing, such ion being present in an amount sufficient to reduce the inclusion of hydrogen in the electrolessly deposited metal.

Inventors

  • 👤 Frederick W Schneble Jr
  • 👤 John F Mccormack
  • 👤 Rudolph J Zeblisky

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 20:05
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/31; C23C18/38; C23C18/40

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 27 words
The method of claim 1, wherein said extraneous ion not electrostatically adsorbed at the outer layer is chemisorbed at the inner layer of the electric double layer.
Claim 2
Dependent Claim 14 words
The method of claim 1, wherein the extraneous ion is a phosphorus containing ion.
Claim 3
Dependent Claim 29 words
The method of claim 1, wherein the electroless metal deposition solution comprises as a stabilizing agent a member selected from the group consisting of divalent sulfur compounds and sulfites.
Claim 4
Dependent Claim 38 words
The method of claim 1, wherein the electroless metal deposition solution comprises as an agent for increasing the rate of deposition of the electroless metal a member selected from the group consisting of hexacyanoferrate (II) and hexacyanoferrate (III).
Claim 5
Dependent Claim 29 words
The method of claim 5, wherein the electroless metal deposition solution comprises as a stabilizing agent a member selected from the group consisting of divalent sulfur compounds and sulfites.
Claim 6
Dependent Claim 26 words
The method of claim 1, wherein the surface contacted with the electroless metal deposition solution is selectively sensitized in designated areas, thereby forming a printed circuit.
Claim 7
Dependent Claim 37 words
The method of claim 1, wherein the electroless metal deposition solution comprises less than 25 parts per million of an ion having an oxidation potential greater than the oxidation potential of the particular ion being electrolessly deposited.
Claim 8
Dependent Claim 23 words
The method of claim 1, wherein the extraneous ion is present in an amount of from about 0.02 to 0.08 mole per liter.

References Cited (Backward Citations)

US3119709A Cited
US3257215A Cited
US3361580A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-01-17 1975-07-19 1976-01-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-01-17 1979-07-19 1980-01-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-01-17 1983-07-19 1984-01-18 $7700.00 Window Closed / Lapsed

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