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US3626041A Expired / Lapsed US ⏱️ 0.0 years remaining

Apparatus and process for making continuous filament

Assignee: Monsanto Co
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Filing: 1968-11-13
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Granted: 1971-12-07
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Expires: 1988-11-13
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Abstract

Abstract A process for making a continuous filament from discrete particulate matter including particles and fibers and mixtures thereof which may be initially packed and oriented in any random fashion. The particulate matter is added to a reaction vessel having a pair of electrodes therein. A strong electrokinetic field is established in this vessel and this electrokinetic field will untangle and properly orient the various random fibers and particulate matter through its influence. This action will cause close packing of the particulate matter in a desired pattern. Furthermore, the orientation is made to take place in a polymeric composition or resin matrix system so that the particulate matter is not only oriented, but held in the oriented position without the aid of the electrokinetic field. During the process of alignment and polymerization or partial polymerization, the continuous filament is formed and simultaneously removed outwardly from the vessel and then fully cured.

Inventors

  • 👤 Joseph E Fields
  • 👤 Edward H Mottus

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 12:18
CPC Classifications
B; B29; B29C; B29C70/00; B29C70/04; B29C70/28; B29C70/40; B29C70/06; B29C70/10; B29C70/12; B29C70/14; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2964; Y10T428/2967

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 17 words
The process of claim 1 wherein substantially all of said fibers have their major axis substantially aligned.
Claim 2
Dependent Claim 10 words
The process of claim 1 wherein said fibers are rod-shaped.
Claim 3
Dependent Claim 214 words
A process for producing a continuous strand of filament, said process comprising introducing discrete fibers having an aspect ratio of at least 5.0 into (a) an electrically nonconductive liquid matrix and where the fibers have a dielectric constant at least 1.5 times greater than the dielectric constant of the liquid matrix, applying an electric field through said matrix under conditions giving rise to electrokinetic effects which are primarily dominated by electrophoretic effects enabling movement of the fibers with respect to the liquid matrix and electroosmotic effects enabling movement of the liquid matrix with respect to the fiber, said field being of such magnitude so that the electrokinetic effects dominate other forces acting on individual fibers and at a strength at least sufficient to cause untangling of the Fibers, dispersion of the fibers, orientation of the fibers, and close packing of the fibers in the desired orientation where substantially all of said fibers have their major axis substantially aligned, to form a continuous strand of filament, partially solidifying the liquid matrix surrounding the fibers to maintain a cohesive force between the fibers and partially solidified liquid matrix and thereby maintain the fibers in close packed alignment in the matrix surrounding said fibers and continually removing the continuous strand of filament from the unsolidified liquid matrix.
Claim 4
Dependent Claim 54 words
The process of claim 4 further characterized in that the liquid matrix contains a nonconductive prepolymer system which prepolymer system is capable of being actuated by an electric field, and that at least sufficient polymerization occurs in the liquid matrix to independently hold the fiber in an oriented position before releasing the electric field.
Claim 5
Dependent Claim 33 words
The process of claim 4 further characterized in that said electric field comprises an electrical potential difference where an electrical potential provides a significant contribution to the total force of the electric field.
Claim 6
Independent Claim 208 words
A system for producing a continuous strand of filaments, said system comprising a reactor vessel, means for introducing discrete fibers having an aspect ratio of at least 5.0 into (a) an electrically nonconductive liquid matrix and where the fibers have a dielectric constant at least 1.5 times greater than the dielectric constant of the liquid matrix, means associated with said reactor vessel for applying an electric field through said matrix under conditions giving rise to electrokinetic effects which are primarily dominated by electrophoretic effects enabling movement of the fibers with respect to the liquid matrix and electroosmotic effects enabling movement of the liquid matrix with respect to the fiber, said field being of such magnitude so that the electrokinetic effects dominate other forces acting on individual fibers and at a strength at least sufficient to cause proper orientation and close packing of the fibers in the liquid matrix to form a continuous strand of filaments, partially solidifying the liquid matrix surrounding the fibers to maintain a cohesive force between the fibers and partially solidified liquid matrix and thereby maintain the fibers in close packed alignment in the matrix surrounding said fibers and means for removing said strand of filaments from the unsolidified liquid matrix as it is formed.
Claim 7
Dependent Claim 286 words
A process for producing a continuous strand of filament, said process comprising introducing discrete fibers having an aspect ratio of at least 5.0 into a (a) an electrically nonconductive liquid matrix and where the fibers have a dielectric constant at least 1.5 times greater than the dielectric constant of the liquid matrix, said filaments being selected from the class consisting of fibers of silica, silica sol, fume silica, silica gel, glass fibers cristobalite, wollastonite, spodumene, mica mullite, sillimanite, chrysolite crocidolite, forsterite, hercynite, kaolinite, dickite, nacrite, beidellite, bentonite, hectorite, montmorillonite, montronite, saponite, attapulgite, iron, cobalt, nickel, aluminum, tin, lead, magnesium, calcium, strontium, barium, titanium, zirconium, vanadium, chromium, manganese, copper, zinc, the corresponding oxides of the above said metals, and heavy metal phosphates, sulfides, and sulfates, said matrix being selected from the class consisting of polyesters, polyimides, phenol-formaldehydes, epoxies, vinyl polymers and copolymers polycarbonates, polyolefins, polyvinyl chloride, and polyurethanes, applying an electric field through said matrix under conditions giving rise to electrokinetic effects which are primarily dominated by electrophoretic effects enabling movement of the fibers with respect to the liquid matrix and electroosmotic effects enabling movement of the liquid matrix with respect to the fiber, said field being of Such magnitude so that the electrokinetic effects dominate other forces acting on individual fibers and at a strength at least sufficient to cause proper orientation and close packing of the fibers in the liquid matrix to form a continuous filament, partially solidifying the liquid matrix surrounding the fibers to maintain a cohesive force between the fibers and partially solidified liquid matrix and thereby maintain the fibers in close packed alignment in the matrix surrounding said fibers and removing said filament from the liquid matrix as it is thus formed.
Claim 8
Dependent Claim 17 words
The process of claim 8 wherein substantially all of said fibers have their major axis substantially aligned.
Claim 9
Dependent Claim 309 words
A process for producing a continuous strand of filament, said process comprising introducing discrete fibers having an aspect ratio of at least 5.0 into (a) an electrically nonconductive liquid matrix and where the fibers have a dielectric constant at least 1.5 times greater than the dielectric constant of the liquid matrix, said filaments being selected from the class consisting of fibers of silica, silica sol, fume silica, silica gel, glass fibers, cristobalite, wollastonite, spodumene, mica, mullite, sillimanite, chrysolite crocidolite, forsterite, hercynite, kaolinite, dickite, nacrite, beidellite, bentonite, hectorite, montmorillonite, nontronite, saponite, attapulgite, iron, cobalt, nickel, aluminum, tin, lead magnesium, calcium, strontium, barium, titanium, zirconium, vanadium, chromium, manganese, copper, zinc, the corresponding oxides of the above said metals, and heavy metal phosphates, sulfides, and sulfates, said matrix being selected from the class consisting of polyesters, polyimides, phenol-formaldehydes, epoxies, vinyl polymers and copolymers, polycarbonates, polyolefins, polyvinyl chloride, and polyurethanes, applying an electric field through said matrix under conditions giving rise to electrokinetic effects which are primarily dominated by electrophoretic effects enabling movement of the fibers with respect to the liquid matrix and electroosmotic effects enabling movement of the liquid matrix with respect to the fiber, said field being of such magnitude so that the electrokinetic effects dominate other forces acting on individual fibers and at a strength at least sufficient to cause untangling of the fibers, dispersion of the fibers, orientation of the fibers, and close packing of the fibers in the desired orientation where substantially all of said fibers have their major axis substantially aligned, to form a continuous strand of filament, partially solidifying the liquid matrix surrounding the fibers to maintain a cohesive force between the fibers and partially solidified liquid matrix and thereby maintain the fibers in close packed alignment in the matrix surrounding said fibers and continually removing the continuous strand of filament from the unsolidified liquid matrix.
Claim 10
Independent Claim 301 words
A system for producing a continuous strand of filaments, said system comprising a reactor vessel, means for introducing discrete fibers having an aspect ratio of at least 5.0 into a nonconductive liquid matrix and where the fibers have a dielectric constant at least 1.5 times greater than the dielectric constant of the liquid matrix, said filaments being selected from the class consisting of fibers of silica, silica sol, fume silica, silica gel, glass fibers, cristobalite, wollastonite, spodumene, mica, mullite, sillimanite, chrysoltile, crocidolite, forsterite, hercynite, kaolinite, dickite, nacrite, beidellite, bentonite, hectorite, montmorillonite, nontronite, saponite, attapulgite, iron, cobalt, nickel, aluminum, tin, lead, magnesium, calcium, strontium, barium, titanium, zirconium, vanadium, chromium, manganese, copper, zinc, the corresponding oxides of the above said metals, and heavy metal phosphates, sulfides, and sulfates, said matrix being selected from the class consisting of polyesters, polyimides, phenol-formaldehydes, epoxies, vinyl polymers and copolymers, polycarBonates, polyolefins, polyvinyl chloride, and polyurethanes, means associated with said reactor vessel for applying an electric field through said matrix under conditions giving rise to electrokinetic effects which are primarily dominated by electrophoretic effects enabling movement of the fibers with respect to the liquid matrix and electroosmotic effects enabling movement of the liquid matrix with respect to the fiber, said field being of such magnitude so that the electrokinetic effects dominate other forces acting on individual fibers and at a strength at least sufficient to cause proper orientation and close packing of the fibers in the liquid matrix to form a continuous strand of filaments, partially solidifying the liquid matrix surrounding the fibers to maintain a cohesive force between the fibers and partially solidified liquid matrix and thereby maintain the fibers in close packed alignment in the matrix surrounding said fibers and means for removing said strand of filaments from the unsolidified liquid matrix as it is formed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-12-06 1975-06-07 1975-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-12-06 1979-06-07 1979-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-12-06 1983-06-07 1983-12-07 $7700.00 Window Closed / Lapsed

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