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Well-cementing method using a spacer composition

Assignee: Atlantic Richfield Co
•
Filing: 1970-06-01
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Granted: 1971-12-07
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Expires: 1990-06-01
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Abstract

Abstract A spacer composition for use while cementing a well that contains an oil-base drilling fluid, the spacer containing a water-in-oil emulsion and at least one of an inorganic and organic material such as halides, hydroxides, borates, sulfates, phosphates, organic acids, and the like. A method for emplacing a cementing composition in a well bore containing an oil-base drilling fluid wherein the spacer is the composition of this invention, is employed between the drilling fluid in the well bore and the cementing composition, and is maintained there while the cementing composition is emplaced and hardened in the desired position in the well bore.

Inventors

  • 👤 Patrick N Parker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 17:18
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/42; C09K8/424

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 270 words
A method according to claim 1 wherein said material is selected from (1) halides, hydroxides, borates, and sulfates of alkali metals; (2) hydroxides, phosphates, phosphites, and borates of alkaline earth metals; (3) metaphosphoric acid or boric acid; (4) lignosulfonates of alkali metals, alkaline earth metals, Cr, Fe, Mn, Co, Ni, Mo, and W; (5) acids of the formula where R2 is (1)- OM and M is hydrogen, R, alkali metal, alkaline earth metal, Zn, Sn, and Pb or (2) hydrogen; R is (1) alkyl having from one to 20, inclusive, carbon atoms per molecule, (2) cycloalkyl having from three to 20, inclusive, carbon atoms per molecule, (3) aryl having from six to 20, inclusive, carbon atoms per molecule, (4) hydrogen, or (5) where n varies from zero to 20, inclusive, Y is (a)- COOM (where M is as defined above), (b)- OH, (c) hydrogen, or (d) the Y''s being the same or different in any given molecule; R1 is selected from the same radicals as R and is the same or different from R in any given molecule; (6) acids of the formula where M is as defined above, R4 is alkyl, cycloalkyl, or aryl as defined for R above, or hydrogen, or and Y is as defined for R above; and R5 is selected from the same radicals as R4 and can be the same or different from R4 in any given molecule; (7) carbohydrates; (8) acids of group 5 having from one to 10, inclusive, hydroxy substituents; (9) anhydrides of the acids of groups 5, 6, and 8; and (10) oxides, halides, and carbonates of Zn or Pb.
Claim 2
Dependent Claim 132 words
A method according to claim 1 wherein said material is selected from (1) halides, hydroxides, borates, and sulfates of alkali metals; (2) hydroxides, phosphates, phosphites, and borates of alkaline earth metals; (3) metaphosphoric acid or boric acid; (4) lignosulfonates of alkali metals, alkaline earth metals, Cr, Fe, Mn, Co, Ni, Mo, and W; (5) carboxymethylcellulose; (6) carboxymethylhydroxyethylcellulose; (7) succinic acid; (8) glutaric acid; (9) sorbitol; (10) phthalic acid; (11) maleic acid; (12) tartaric acid; (13) gluconic acid; (14) oxalic acid; (15) citric acid; (16) glucoheptanoic acid; (17) malonic acid; (18) adipic acid; (19) pimelic acid; (20) suberic acid; (21) azeloic acid; (22) sebacic acid; (23) ZnCl2; (24) ZnO; (25) ZnCO3; and (26) PbO, and said spacer contains no more than about 100,000 p.p.m. CaCl2 based on the water phase of said emulsion.
Claim 3
Dependent Claim 36 words
A method according to claim 1 wherein the amount of said material present is from about 1,000 p.p.m. based on the water phase in said emulsion up to about the saturation point of the water phase.
Claim 4
Dependent Claim 70 words
A method according to claim 1 wherein said material is one of a borate of groups 1 and 2 or a halide of group 1, and said borate or halide is present in an amount of from about 1,000 to about 500,000 p.p.m. based on the water phase in said emulsion, and said spacer contains no more than about 100,000 p.p.m. CaCl2 based on the water phase in said emulsion.
Claim 5
Dependent Claim 17 words
A method according to claim 1 wherein said spacer contains no more than about 1,000 p.p.m. CaCl2.

References Cited (Backward Citations)

US2206389A Cited
US2582909A Cited
US2590814A Cited
US2848051A Cited
US3291211A Cited
US3299952A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-12-06 1975-06-07 1975-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-12-06 1979-06-07 1979-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-12-06 1983-06-07 1983-12-07 $7700.00 Window Closed / Lapsed

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