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US3622535A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing mineral reinforced polylactam compositions

Assignee: Monsanto Co
•
Filing: 1969-01-27
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Granted: 1971-11-23
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Expires: 1989-01-27
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Abstract

Abstract Improved lactam slurries containing a major amount of a mineral reinforcing agent suitable for conversion to a reinforced polylactam composition by the initiated, anionic polymerization process and essentially containing an effective amount of from about 0.1 to about 1.0 weight percent, based on the mineral, of an adduct prepared by the reaction of (1) a higher alkylbenzenesulfonic acid, wherein the alkyl group contains from nine to 15 carbon atoms, with (2) an omega aminoalkylenetrialkoxysilane, wherein the alkylene group contains from two to 10 carbon atoms and each of the alkoxy groups contain from one to three carbon atoms. The presence of said adduct acts as a fluidifying agent to provide a lower viscosity slurry at a given mineral concentration enabling better filling of molds in the cast-polymerization process and/or permitting the use of slurry compositions with higher mineral concentrations with processing equipment operating near the upper limit of prior art mineral concentration for any particular mineral-lactam composition.

Inventors

  • 👤 Robert Z Greenley
  • 👤 Jerry M Sugerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:58
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/08; C08G69/14; C08G69/16; C08G69/18; C08K; C08K9/00; C08K9/04; C08K9/06

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 20 words
The process of claim 1, wherein the lactam monomers contain from 6 to 12 carbon atoms in the lactam ring
Claim 2
Dependent Claim 18 words
The process of claim 2, wherein at least 50 mol percent of the lactam monomers is epsilon -caprolactam.
Claim 3
Dependent Claim 30 words
The process of claim 1, wherein the inorganic filler material is a particulate mineral having a water solubility of less than 0.15 gram per liter, and passes a 60-mesh screen.
Claim 4
Dependent Claim 12 words
The process of claim 4, wherein the mineral is a siliceous material.
Claim 5
Dependent Claim 10 words
The process of claim 5, wherein the mineral is silica.
Claim 6
Dependent Claim 10 words
The process of claim 5, wherein the mineral is wollastonite.
Claim 7
Dependent Claim 10 words
The process of claim 5, wherein the mineral is feldspar.
Claim 8
Dependent Claim 21 words
The process of claim 2, wherein the adduct is prepared by the essentially equimolecular reaction of dodecylbenzenesulfonic acid with gamma -aminopropyltriethoxysilane.
Claim 9
Dependent Claim 30 words
The process of claim 9, wherein the inorganic filler material is a particulate mineral having a water solubility of less than 0.15 gram per liter, and passes a 60-mesh screen.
Claim 10
Dependent Claim 18 words
The process of claim 10, wherein at least 50 mol percent of the lactam monomers is epsilon -caprolactam.
Claim 11
Dependent Claim 12 words
The process of claim 10, wherein the lactam monomer is epsilon -caprolactam.
Claim 12
Dependent Claim 11 words
The process of claim 12, wherein the inorganic filler is silica.
Claim 13
Dependent Claim 11 words
The process of claim 12, wherein the inorganic filler is wollastonite.
Claim 14
Dependent Claim 11 words
The process of claim 12, wherein the inorganic filler is feldspar.

References Cited (Backward Citations)

US3419517A Cited
US3410831A Cited
US3418268A Cited
US3498872A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-11-22 1975-05-24 1975-11-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-11-22 1979-05-24 1979-11-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-11-22 1983-05-24 1983-11-23 $7700.00 Window Closed / Lapsed

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