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Process for preparing colored photoresists

Assignee: GAF Corp
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Filing: 1968-02-12
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Granted: 1971-11-09
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Expires: 1988-02-12
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Abstract

Abstract Photopolymerizable compositions containing a polymerizable ethylenically unsaturated compound, a ferric salt, a peroxy compound and an alpha-hydroxycarboxylic acid, and their use in preparing photoresists.

Inventors

  • 👤 Edward Cerwonka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 11:45
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/30; G03F7/32; C; C08; C08F; C08F2/00; C08F2/46; G03F7/004; G03F7/027; G03F7/028; G03F7/029

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 18 words
A photopolymerizable composition according to claim 1 wherein a water-soluble colloidal carrier is added to said photopolymerizable composition.
Claim 2
Dependent Claim 13 words
A photopolymerizable composition according to claim 2 wherein said colloidal carrier is gelatin.
Claim 3
Dependent Claim 20 words
A photopolymerizable composition according to claim 3 consisting essentially of gelatin, metahydroxy mandelic acid, acrylamide, N,N''-methylene-bisacrylamide and ferric ammonium citrate.
Claim 4
Dependent Claim 20 words
A photopolymerizable composition according to claim 3 consisting essentially of gelatin, hydroxy-carboxy-methyl-substituted malachite green, acrylamide, N,N''-methylene-bisacrylamide and ferric ammonium citrate.
Claim 5
Dependent Claim 90 words
In the process for preparing photoresists wherein a photopolymerizable composition comprising a water-soluble colloidal carrier, at least one ethylenically unsaturated monomer and a light-sensitive ferric salt is coated on a suitable support, dried, imagewise exposed to light, and then developed by washing in the presence of a peroxy compound, the improvement which comprises adding an alpha-hydroxy carboxylic acid selected from the group consisting of color couplers which yield a coloration with the oxidation products of a primary aromatic amine developer and alpha-hydroxy-carboxy-substituted dyestuffs to said photopolymerizable composition prior to exposure.
Claim 6
Dependent Claim 13 words
The process of claim 6 wherein the alpha-hydroxy carboxylic acid is a dye.
Claim 7
Dependent Claim 14 words
The process of claim 6 wherein the alpha-hydroxy carboxylic acid is a color coupler.
Claim 8
Dependent Claim 11 words
A photopolymerizable composition according to claim 1 containing a peroxy compound.
Claim 9
Dependent Claim 96 words
The process of preparing a colored photoresist which comprises image-wise exposing to light, a photopolymerizable layer on a support, said layer consisting essentially of a water-soluble colloidal carrier, at least one ethylenically unsaturated monomer, a light-sensitive ferric salt and an alpha-hydroxycarboxylic acid which is a color coupler yielding a coloration with the oxidation products of a primary aromatic amine developer, treating said layer with a peroxy compound, developing it with a primary aromatic amino developer solution, and treating it with the solution of an oxidizing agent selected from the group consisting of water-soluble ferricyanides and dichromates.
Claim 10
Dependent Claim 43 words
The process of preparing a colored photoresist according to claim 10 wherein said layer consists essentially of meta-hydroxy mandelic acid, gelatin, acrylamide, N,N''-methylenebisacrylamide and ferric ammonium citrate, said peroxy compound is hydrogen peroxide and said primary aromatic amino developer is N-ethyl-N-hydroxyethyl- para-phenylene diamine.
Claim 11
Dependent Claim 55 words
The process of preparing a colored photoresist which comprises image-wise exposing to light, a photopolymerizable layer on a support, said layer consisting essentially of a water-soluble colloidal carrier, at least one ethylenically unsaturated monomer, a light-sensitive ferric salt and an alpha-hydroxy-carboxy-substituted dyestuff, treating said layer with a peroxy compound and developing by washing with water.
Claim 12
Dependent Claim 39 words
The process of preparing a colored photoresist according to claim 12 wherein said layer consists essentially of gelatin, acrylamide, N,N''-methylenebisacrylamide, ferric ammonium citrate and hydroxy-carboxy-substituted malachite green, treating said layer with hydrogen peroxide, and developing by washing with water.

References Cited (Backward Citations)

US3101270A Cited
US3183094A Cited
US3352675A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-11-08 1975-05-10 1975-11-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-11-08 1979-05-10 1979-11-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-11-08 1983-05-10 1983-11-09 $7700.00 Window Closed / Lapsed

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