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US3617501A Expired / Lapsed US ⏱️ 0.0 years remaining

Integrated process for refining whole crude oil

Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1968-09-06
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Granted: 1971-11-02
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Expires: 1988-09-06
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Abstract

Abstract The disclosure relates to a process for the refining of whole crude oil to produce a maximum quantity of gasoline and distillate products and a minimum quantity of industrial fuel oil. The process features hydrotreating of whole crude oil as the first major processing step.

Inventors

  • 👤 Jackson Eng
  • 👤 John L Tiedje

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:28
CPC Classifications
C; C10; C10G; C10G69/00; C10G47/00

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 237 words
An integrated process for producing light naphtha, heavy naphtha and a fuel oil fraction from whole petroleum crude oil comprising the steps of: a. passing said whole petroleum crude oil containing sulfur, nitrogen and metal impurities directly to a hydrofining zone; b. hydrofining said crude oil in the presence of a hydrofining catalyst and hydrogen; c. passing hydrofined crude oil to an atmospheric distillation zone; d. distilling an admixture of said hydrofined crude oil with hydrocracked products as hereinafter identified; e. recovering a light naphtha fraction from said distillation zone, said fraction being essentially free of mercaptans; f. recovering a low sulfur, heavy naphtha reformer feed stock fraction from said distillation zone; g. passing a low sulfur, low nitrogen atmospheric distillation bottoms from said distillation zone to a vacuum distillation zone; h. recovering a low sulfur fuel oil and cracking feed fraction from said vacuum distillation zone; i. passing said cracking feed fraction to a hydrocracking zone; j. hydrocracking said fraction at a temperature in the range of 650* to 750* F. and a pressure in the range of 1,000 to 3,000 p.s.i.g. in the presence of 5,000 to 10,000 s.c.f./B of hydrogen and a catalyst comprising a metal hydrogenation component and a crystalline aluminosilicate zeolite; k. recovering hydrocracked products comprising a major amount of naphtha, and l. passing said hydrocracked products to the atmospheric distillation zone of step (c) to provide said admixture of step (d).
Claim 2
Dependent Claim 15 words
Process according to claim 11, in which the hydrofining catalyst is cobalt molybdate on alumina.
Claim 3
Dependent Claim 24 words
Process according to claim 1, in which said cracking feed fraction of step (i) boils in the range of about 650* to 950* F.
Claim 4
Dependent Claim 23 words
Process according to claim 1, in which the catalyst of step (j) comprises a nickel-tungsten hydrogenation component on a support comprising zeolite Y.
Claim 5
Dependent Claim 227 words
An integrated process for producing light naphtha and heavy naphtha from whole petroleum crude oil comprising the steps of: a. passing said whole petroleum crude oil containing sulfur, nitrogen and metal impurities directly to a hydrofining zone; b. hydrofining said crude oil in the presence of a hydrofining catalyst and hydrogen; c. passing hydrofined crude oil to an atmospheric distillation zone; d. distilling an admixture of said hydrofined crude oil with cracked products as hereinafter identified; e. recovering a light naphtha fraction from said distillation zone, said fraction being essentially free of mercaptans; f. recovering a low sulfur, heavy naphtha reformer feed stock fraction from said distillation zone; g. passing a low sulfur, low nitrogen cracking feed fraction from said distillation zone to a cracking zone; h. catalytically cracking said fraction at a temperature in the range of 900* to 950* F. and a pressure in the range of 5 to 25 p.s.i.g. in the presence of a cracking catalyst comprising a crystalline aluminosilicate zeolite component composited with an amorphous silica alumina component; i. recovering catalytically cracked products; j. passing a major proportion of said cracked products to the hydrofining zone of step (b) for saturation of olefins in the cracked products, and k. passing a minor proportion of said cracked products to the atmospheric distillation zone of step (c) to provide said admixture of step (d).
Claim 6
Dependent Claim 28 words
Process according to claim 6 in which the hydrofining catalyst of step (b) is nickel molybdate on a support comprising alumina and 1 and 10 weight percent silica.
Claim 7
Dependent Claim 191 words
An integrated process for producing light naphtha, hEavy naphtha and fuel oil from whole petroleum crude oil comprising the steps of: a. passing said whole petroleum crude oil containing sulfur, nitrogen and metal impurities directly to a hydrofining zone; b. hydrofining said crude oil in the presence of a hydrofining catalyst and hydrogen; c, passing hydrofined crude oil to an atmospheric distillation zone; d. distilling an admixture of said hydrofined crude oil with cracked products as hereinafter identified; e. recovering a light naphtha fraction from said distillation zone, and fraction being essentially free of mercaptans; f. recovering a low sulfur, heavy naphtha reformer feed stock fraction from said distillation zone; g. passing a low sulfur, low nitrogen atmospheric distillation bottoms from said distillation zone to a vacuum distillation zone; h. recovering a low sulfur fuel oil and a cracking feed fraction from said vacuum distillation zone; i. cracking the cracking feed fraction of step (h) in a cracking zone in the presence of a cracking catalyst; j. passing at least a part of the cracked products to the atmospheric distillation zone of step (c) to provide said admixture of step (d).

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-11-01 1975-05-03 1975-11-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-11-01 1979-05-03 1979-11-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-11-01 1983-05-03 1983-11-02 $7700.00 Window Closed / Lapsed

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