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Electroless plating of plastics

Assignee: Dow Chemical Co
•
Filing: 1967-12-05
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Granted: 1971-09-21
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Expires: 1987-12-05
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Abstract

Abstract An organic plastic substrate is metal plated by the following essential steps (1) sulfonation with SO3 in a chlorinated hydrocarbon solvent, (2) neutralization of the sulfonated plastic in a dilute alkaline aqueous solution of an alkali compound, (3) immersing the neutralized, sulfonated plastic in a basic solution of silver nitrate and (4) coating a thin coat of copper or nickel on the activated, sulfonated plastic by means of a conventional electroless plating bath.

Inventors

  • 👤 Richard J Rathsack

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:02
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/2006; C23C18/2046; C23C18/2073; C23C18/2086; C23C18/22

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 25 words
The method of claim 1 in which the concentration of sulfur trioxide in the chlorinated solvent is about 0.1 to about 10 percent by weight.
Claim 2
Dependent Claim 26 words
The method of claim 2 in which the chlorinated hydrocarbon solvent is selected from the group consisting of carbon tetrachloride, tetrachloroethylene, methylene chloride and mixtures thereof.
Claim 3
Dependent Claim 30 words
The method of claim 1 in which the chlorinated hydrocarbon solvent is methylene chloride and the concentration of sulfur trioxide in said solvent is 2.5 to 4.0 percent by weight.
Claim 4
Dependent Claim 31 words
The method of claim 1 in which the dilute alkaline aqueous solution of an alkali compound has a concentration of about 0.1 to about 20 weight percent of the alkali compound.
Claim 5
Dependent Claim 19 words
The method of claim 5 in which the alkali compound is an alkali metal salt of a weak acid.
Claim 6
Dependent Claim 14 words
The method of claim 5 in which the alkali compound is a strong base.
Claim 7
Dependent Claim 13 words
The method of claim 5 in which the alkali compound is sodium bicarbonate.
Claim 8
Dependent Claim 37 words
The method of claim 1 in which the basic aqueous solution of silver nitrate contains about 0.2 to about 10 percent by weight of silver nitrate and about 1.0 to 4.0 percent by weight of ammonium hydroxide.

References Cited (Backward Citations)

US2783137A Cited
US2728831A Cited
US2836578A Cited
US2821522A Cited
US3035944A Cited
US3222218A Cited
US3326866A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-09-20 1975-03-22 1975-09-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-09-20 1979-03-22 1979-09-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-09-20 1983-03-22 1983-09-21 $7700.00 Window Closed / Lapsed

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