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US3592043A Expired / Lapsed US ⏱️ 0.0 years remaining

Micro-adsorption detector and method of using same

Assignee: Varian Medical Systems Inc
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Filing: 1969-01-27
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Granted: 1971-07-13
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Expires: 1989-01-27
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Abstract

Abstract A microadsorption detector is disclosed having at least three adsorption-heat-detection cells serially disposed in close proximity to each other along the flow path for a fluid stream in which constituents are to detected. The third adsorption-heatdetection cell permits the electrical outputs of the cells to be combined in at least two pairs to form at least two separate composite output signals. The composite signals each comprise a combination of the outputs of at least two cells. Use of different adsorptive fill materials in the pairs of cells yields qualitative information concerning the constituents to be detected in the fluid stream. At least one of the cells would normally be filled with a relatively inert, nonadsorptive material and serve as a reference cell to compensate for extaneous temperature changes common to all the cells. Four or more cells can be arranged to compensate for flow sensitivity. The signal from one pair of cells, both members of which are filled with the same type of adsorptive material, will compensate that part of the signal from other pairs of cells which is due to change in flow rate.

Inventors

  • 👤 Miner Nelson Munk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 12:51
CPC Classifications
G; G01; G01N; G01N30/00; G01N30/02; G01N30/62; G01N30/78

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 139 words
In a microadsorption detector, means forming a plurality of adsorption detector cells serially disposed in close proximity to each other along the flowpath for a fluid stream to be detected, each of said cells including a thermally responsive sensing element for deriving an output determinative of the adsorption in the respective cell of certain constituents of the fluid stream, THE IMPROVEMENT WHEREIN, at least one of said cells including active adsorptive packing material and the remainder of said cells having relatively inactive packing material, there are at least three of said serially disposed adsorption detection cells, means combining the individual outputs of each of said cells in pairs to form at least two separate composite output signals, such composite signals each comprising a combination of the outputs of at least two cells and means comparing the composite output signals.
Claim 2
Dependent Claim 139 words
In a microadsorption detector, means forming a plurality of adsorption detector cells serially disposed in close proximity to each other along the flowpath for a fluid stream to be detected, each of said cells including a thermally responsive sensing element for deriving an output determinative of the adsorption in the respective cell of certain constituents of the fluid stream, THE IMPROVEMENT WHEREIN, at least one of said cells including active adsorptive packing material and the remainder of said cells having relatively inactive packing material, there are at least three of said serially disposed adsorption detection cells, means combining the individual outputs of each of said cells in pairs to form at least two separate composite output signals, such composite signals each comprising a combination of the outputs of at least two cells and means comparing the composite output signals.
Claim 3
Dependent Claim 21 words
The apparatus of claim 1 wherein said plurality of serially disposed adsorption cells comprises at least four of said adsorption cells.
Claim 4
Dependent Claim 42 words
The apparatus of claim 1 wherein at least two of said cells includes a relative active adsorptive packing material for a constituent of the fluid stream as compared to the adsorptive characteristics of the packing material, if any, of said third cell.
Claim 5
Dependent Claim 20 words
The apparatus of claim 1 wherein said comparing means includes a recorder for recording the separate composite signals for comparison.
Claim 6
Dependent Claim 32 words
The apparatus of claim 1 wherein said combining means includes a pair of wheatstone bridge networks, and wherein said comparing means compares the separate outputs of said pair of wheatstone bridge networks.
Claim 7
Dependent Claim 77 words
The apparatus of claim 2 wherein at least three of said detection cells each includes a relatively inert adsorptive fill material, if any, as compared to a relatively active fill material disposed within said fourth cell, means for combining the outputs of two pair of said cells to produce a pair of composite outputs, and means for comparing the composite outputs to derive an output which is relatively independent of the rate of flow of said stream.
Claim 8
Dependent Claim 32 words
The apparatus of claim 1 including a liquid chromatographic column disposed upstream of said detector cells such that said detector cells are disposed to detect the effluent liquid stream of said column.

References Cited (Backward Citations)

US2596992A Cited
US2633737A Cited
US2868011A Cited
US3263488A Cited
US3408854A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-07-12 1975-01-11 1975-07-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-07-12 1979-01-11 1979-07-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-07-12 1983-01-11 1983-07-13 $7700.00 Window Closed / Lapsed

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